• Polymer(Korea)
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• v.35 no.5
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• pp.488-492
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• 2011

Three isocyanatopropyldimethoxysilylpolydimethylsiloxanes(IDMSi-PDMS) were synthesised from the reaction of isocyanatopropyltrimethoxysilane with monohydroxyl group termainated PDMS having different molecular weight($M_n$=5000, 10000, and 20000). Then PDMS modified polyurethane hybrid elastomer(PSMPH) were prepared from the reaction of IDMSi-PDMS with ${\alpha}$, ${\omega}$-hydroxyl group terminated polyurethane. PSMPH sealant was prepared by compounding PSMPH elastomer with additives such as plasticizer, adhesion promoter, crosslinking agent, vicosity increasing agent, inorganic filler, and catalyst at room temperature under nitrogen atmosphere. The methoxy group in the PSMPH sealant should be crosslinked with the hydroxyl group in the building stone or moisture by typical sol-gel reaction. The adhesive strength of the sealant having PDMS of $M_n$=5000 showed 40.28 kg of maxium load and 20.14 kg of break load. The shrinkage rate of the sealant having PDMS of $M_n$=20000 was 5.7% as the best result. Also, their skin over time, slump, oil content after 8 days under oil soaked paper and alkaline resistance characteristics show good results.

• Fire Science and Engineering
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• v.17 no.4
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• pp.117-123
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• 2003

In this study; the ignition and heat release rate characteristics of rigid polyurethane foam were investigated in accordance with setchkin ignition tester and cone calorimeter which is using oxygen consumption principle. In the ignition temperature study; flash-ignition temperature was $383^{\circ}C$-$390^{\circ}C$, self-ignition temperature was$ 493^{\circ}C$∼495$^{\circ}C$. The self-ignition temperature of rigid polyurethane foam was about $100^{\circ}C$ higher than the flash-ignition temperature. In the cone calorimeter study, the time to ignition of rigid polyurethane foam was faster as the external heat flux increase. In the same heat flux level, the time to ignition was faster as the density of rigid polyurethane foam decrease. Also the heat release rate was the largest value at the heat flux of /$50 ㎾\m^2$ and had a tendency of increase as the heat flux level and density increase. In the standpoint of time to ignition and heat release rate, the fire performance of rigid polyurethane foam was influenced by the applied heat flux level and density and the flashover propensity classified by Petrella's proposal was high.

• Korean Chemical Engineering Research
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• v.50 no.3
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• pp.410-416
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• 2012

Waterborne polyurethane dispersions (PUD) were synthesized from isophorone diisocyanate (IPDI), polycarbonate diol (PCD) and dimethylol propionic acid (DMPA) as starting materials. Subsequently, polyurethane-acrylic hybrid solutions were prepared by reacting the PUD with different types of acrylate monomers, such as HEMA (2-hydroxyethyl methacrylate):MMA (methyl methacrylate), HEMA:BA (butylacrylate), HEMA:BMA (butyl methacrylate), HEMA:HEA (2-hydroxyethyl acrylate), HEMA:PETA (pentaerytritol triacrylate) mixture. Also, the effects of acrylate types on the chemical resistance and the abrasion resistance of polyurethane-acrylic hybrid solutions were investigated. The test results showed that the HEMA:MMA mixture had the strongest chemical resistance, while the HEMA:PETA mixture had the strongest abrasion resistance among several types of acrylate mixtures.

• Journal of the Korea Institute of Construction Safety
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• v.1 no.1
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• pp.7-15
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• 2018

The purpose of this study is to analyze the limits of current measures to prevent fire accidents especially in the existence of polyurethane. Suffering numerous fire accidents, preventive measures are strengthened accordingly. However, in the existence of polyurethane, current measures are insufficient since it is still impossible to completely separate inflammables form ignition sources in case of polyurethane used as insulation. In order to identify blind spots of current fire prevention measures, this study conducted analysis on the previous fire accidents and the coverage of current legislative preventive measures. In conclusion, in order to perfectly prevent polyurethane fire accidents, not only controling of working condition but also substitution of noncombustible material for polyurethane is indispensible.

• Applied Chemistry for Engineering
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• v.31 no.6
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• pp.630-634
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• 2020

We developed a processing recipe to synthesize flexible polyurethane foam with a pore size of 335 ± 107 ㎛. The gelling reaction time was varied from 0 to 30 minutes and the physical properties of the foam were evaluated. The gelling reaction where the polypropylene glycol and tolylene 2,4-diisocyanate (TDI) were reacted to form urethane prepolymer, proceeded until a chemical blowing agent, deionized water, was introduced. Fourier transform infrared (FT-IR) spectra showed that the composition of the foam did not change but the foam height reached a peak value when the gelling reaction time was 10 minutes. We found that increasing the gelling time lessened the coalescence and helped the formation of cells. Lastly, the repeatability of polyurethane foam was confirmed by one-way analysis of variance (ANOVA) by synthesizing ten identical polyurethane foams under the same experimental conditions, including the gelling reaction time. Overall, the new time parameter in-between the gelling and blowing reactions will give extra stability in manufacturing identical polyurethane foams and can be applied to various polyurethane foam processes.

• Korean Chemical Engineering Research
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• v.50 no.5
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• pp.783-788
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• 2012

Stern tube bearing is a shaft device playing important roles to reduce the friction of axial rotation and to support the weight of shaft. However, because there is no domestic producer of stern tube bering, imported stern tube bearings have many practical problems including prices, delivery and after services. This is why stern tube bearing should be localization. For the purpose of development of polyurethane resin for stern tube bearings, the effect of additives on the hardness, tensile strength and elongation of the polyurethane resin were systematically investigated. For the preliminary researches, depending on the type of curing agent, MOCA type and non-MOCA type polyurethanes were synthesized. Preliminary researches concluded that MOCA type polyurethane resin has more excellent mechanical properties than non-MPCA type for stern tube bearings that Tensile strength and Hardness of non-MOCA type investigated 23 D, 4.3 Mpa. Therefore, MOCA type polyurethane was adapted as base resin of this research. Silica, calcium carbonate and graphite were selected as additives for the enhancement of mechanical properties of polyurethane resin. Effect of the type and the dosage of these additives on the hardness, tensile strength, elongation of the polyurethane resin were experimentally examined. However, addition of calcium carbonate and graphite showed only minor effect on the hardness of the resin. Polyurethane resin with silica showed relatively excellent hardness, tensile strength and improved elongation.

• Archives of Plastic Surgery
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• v.36 no.4
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• pp.380-384
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• 2009

Purpose: Autologous vessels remain the gold standard for vascular grafts in microanastomoses. However, they are sometimes unavailable and have a limited long - term patency. Synthetic vessels have high success rates in large - diameter reconstructions but failed when used as small - diameter grafts due to graft occlusion. It has been proved that endothelial cell seeding improves prosthesis performance and long - term patency. Among polyurethane, PET and ePTFE, polyurethane has the best affinity to endothelial cells and mechanical properties closest to human vessels. We examined the ability of endothelial cells to attach to a polyurethane graft manufactured by the electrospinning method. Methods: Endothelial cells, which were cultured from porcine internal jugular veins, were attached to polyurethane grafts with an internal diameter of 3 mm. The same cells were attached to allogeneic decellularized porcine internal carotid artery grafts as controls. Both of the 10 mm - long grafts were exposed to endothelial cells in a well for 1 hour. Each well contained $2{\times}10^5$ endothelial cells. The graft materials were rotated through 90 degrees every 15 minutes in order to minimize the effect of gravity. The extent of cell attachment was examined with the MTT assay. Results: The MTT assay showed good incorporation of endothelial cells into both grafts. For the evaluation of affinity, the number of attached cells was counted at 10 fields of microscopic examination with ${\times}40$ magnification. Endothelial cells adhered more to polyurethane grafts (mean, $127.4{\pm}6.2cells$) compared to porcine artery grafts (mean $45.8{\pm}5.1cells$)(p<0.05,Mann - Whitney test). Conclusion: In this study, we attached porcine endothelial cells to polyurethane grafts, manufactured by electrospinning. The grafts exhibited a better affinity to endothelial cells than allogeneic decellularized porcine internal carotid artery grafts. It is suggested that the time required for endothelial cells to attach to decellulized artery grafts may be longer than that which is required for attachment to polyurethane grafts.

• Fibers and Polymers
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• v.2 no.3
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• pp.141-147
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• 2001

The effect of compositions of isophorone diisocyanate (IPDl)/4.4'-diphenylmethane diisocyalate (MDI) and polypropylene oxide diol (PPG, $M_w$: 3000)/1,4-butane diol (BD) on the properties of UV-cured polyurethane acrylate films based on 2-hydroxyethyl acrylate (HEA) was examined. UV-curable polyurethane acrylates were formulated from the prepolymer. trimethylol propane triacrylate (TMPTA) as a reactive diluent, and 1-hydroxycyclohexyl ketone (Irgacure 184) as a photoinitiator. Dynamic mechanical thermal properties and elastic properties of UV-cured polyurethane acrylates was fecund to depend on the chemical composition of IPDl/MDl and PPG/BD. As the BD content increased, the tensile storage modulus of all series samples increased significantly. The storage modulus increased in the order of samples A (IPDI based samples)> samples B (IPDI/MDl (7/3 molar ratio) based samples) > samples C (IPDI/MDl (5/5 molar ratio) based samples at the same composition. Two distinct louts modulus peaks for all samples are observed owing to the softs segment glass transition temperature ($T_gh$) and hard segment glass transition temperature ($T_gh$). The difference between $T_gh$, and $T_gh$, (Δ$T_g$) increases in the order of A > B > C at the same composition. In cycle test, the initial onset strain (%) was found to decrease with increasing BD content in PPG/BD and with increasing MDI content in IPDI/MDl.

• Korean Journal of Human Ecology
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• v.12 no.3
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• pp.363-376
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• 2003

The purpose of this research was to investigate the property of sensibility of silk fabrics by the linen-like finishing-used polyurethane resin. Subjective evaluations of preference and related sensory descriptors were estimated. Also, related physical and psychological variables were measured. And their correlations were investigated. The value of EM, WT, WC, MIU, and qmax of silk fabrics treated with polyurethane resin decreased and LT, B, 2HB, G, 2HG, 2HG5, and SMD increased. Physical variables which affected on the preference of summer fabrics are B, 2HB, G, 2HG5, qmax, MIU and LT. It was confirmed that silk fabrics treated with polyurethane resin were preferred as a summer fabric. Individual sensibilities that had effects on the preference of summer fabrics were softness including rough and cold. The intensities of weight value on sensory descriptors, which were related with the preference in summer environments, were in following orders: cold, rough, slippery, flexible, stiff and damp. There was no relationship between the subjective evaluation of preference and related sensory descriptors on the fabric and comfort sensation of fabric was derived from psychological variables

• Journal of Adhesion and Interface
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• v.13 no.3
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• pp.116-120
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• 2012

In this study, waterborne polyurethane was prepared from polyester polyol, $H_{12}MDI$, DMPA and sulfopropylated polypropyleneglycol-${\alpha}$,${\omega}$-diamine (SP). The $T_g$ of waterborne polyurethane was increased as the SP content increased, while it was decreased at the NCO/OH ratio of 1.8. Also the hydrolysis-resistance and tensile strength were increased as the SP content increased. The tensile strength decrement of WPU-SP was 2~5% with the exception of WPU-SP-1.