• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제54권3호
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• pp.114-119
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• 2005

We investigated compatibilizing effects of electrical properties such as charge distributions and electrical breakdown in blends of low density polyethylene (LDPE) / polystyrene (PS) with poly [styrene-b-(ethylene-co-butylene)-b-styrene] (SEBS), the triblock copolymer. The blends with $70\;wt\%$ of LDPE and $30\;wt\%$ of PS were prepared through a melt blending in a batch type kneader at a temperature of $220^{\circ}C$ when the SEBS content increased up to $10\;wt\%$. Scanning electron microscopy (SEM) was investigated for observation of morphology of LDPE / PS blends increasing SEBS contents. The morphological observation showed that addition of SEBS results in the domain size reduction of the dispersed PS phase and a better interfacial adhesion between LDPE and PS phases. Measurements of space charge distributions for blends was carried out with pulsed electroacoustic (PEA) method. It was possible to observe that the amount of charge storage in the LDPE / PS blends decreased wiか increasing of SEBS content. The location of SEBS at a domain interface enables charges to move from one phase to the other via domain interface and results in a indicative decrease in the amount of space charge for the LDPE / PS blends with SEBS. Electrical breakdown strength of these blends was observed. It was found that the maximum breakdown strength of the blend was 51.55 kV/mm. These results were better than 38.38 kV/mm of LDPE used electrical insulator for cables and were caused by crystalinity of blends. Because the crystalinity of blends were lower than LDPE, electrical breakdown strength of LDPE / PS blends is higher than that of LDPE. We evaluated the possibility of these blends for insulating material substituted LDPE.

• Korean Chemical Engineering Research
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• 제53권5호
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• pp.614-619
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• 2015

미세입자의 플라즈마 표면 개질을 감압상태하의 순환유동층 반응기에서 수행하였다. 플라즈마에 의해 처리된 폴리스타이렌 입자는 폴리에틸렌글리콜로 표면에 그래프팅하였다. 표면 개질 전 입자와 플라즈마 처리된 입자 그리고 그래프팅된 입자의 특성은 각각 DPPH 방법, FTIR, SEM 그리고 접촉각 측정으로 분석하였다. 플라즈마 처리된 폴리스타이렌 입자의 표면에 과산화물이 잘 형성되었다. 또한, 폴리에틸렌글리콜의 그래프팅 중합에 의해 플라즈마 처리된 입자 표면에 그래프팅이 잘 분산되었다. 따라서 감압상태의 순환 유동층 반응기에서 플라즈마 처리에 의한 PEG-g-PS 입자를 성공적으로 형성할 수 있었다.

• 폴리머
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• 제30권1호
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• pp.50-55
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• 2006

분산중합으로 제조된 폴리스티렌(PS) 시드 고분자 미립자에 가교단량체인 HDDA(1,6-hexanedioldiacrylate)를 one-step으로 흡수시키고 이를 중합하여 단분산 가교고분자 미립자를 제조할 시 1) 시드 고분자의 분자량, 2) 흡수된 가교단량체와 시드의 중량비, 3) 중합반응속도 등의 변화에 따른 가교고분자 입자의 표면 모폴로지 변화 등을 관찰하였다. 이번 연구를 통해 PS/HDDA계에서는 시드 고분자의 분자량 및 가교단량체 흡수비에 관계없이 가교고분자 입자표면에 분화구 형태의 모폴로지가 관찰되었으며, 이와 같은 표면 모폴로지는 중합반응속도를 조절함으로써 조절이 가능함을 알 수 있었다.

• 한국재료학회지
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• 제20권10호
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• pp.550-554
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• 2010

This work presents a fabrication procedure to make large-area, size-tunable, periodically different shape metal arrays using nanosphere lithography (NSL) combined with ashing and annealing. A polystyrene (PS, 580 ${\mu}m$) monolayer, which was used as a mask, was obtained with a mixed solution of PS in methanol by multi-step spin coating. The mask morphology was changed by oxygen RIE (Reactive Ion Etching) ashing and temperature processing by microwave heating. The Au or Pt deposition resulted in size tunable nano patterns with different morphologies such as hole and dots. These processes allow outstanding control of the size and morphology of the particles. Various sizes of hole patterns were obtained by reducing the size of the PS sphere through the ashing process, and by increasing the size of the PS sphere through annealing treatment, which resulted in tcontrolling the size of the metallic nanoparticles from 30 nm to 230 nm.

• Macromolecular Research
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• 제16권7호
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• pp.637-643
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• 2008

A combination of magnetic and temperature-responsive properties in the same polymer composites is expected to increase their potential applications in the biomedical field. Accordingly, micron-sized magnetite/polystyrene/poly(2-dimethylaminoethyl methacrylate-ethyleneglycol dimethacrylate), which are abbreviated as $Fe_3O_4$/PS/P (DM-EGDM) composite polymer particles, were prepared by the seeded copolymerization of DM and EGDM in the presence of magnetite/polystyrene ($Fe_3O_4$/PS) particles. $Fe_3O_4$/PS/P(DM-EGDM) composite particles with magnetic properties showed a temperature-sensitive phase transition at approximately $31^{\circ}C$. The adsorption behavior of the low molecular weight emulsifiers and trypsin (TR) as biomolecules were examined on $Fe_3O_4$/PS/P(DM-EGDM) composite polymer particles at different temperatures. The native conformation of TR was followed by measuring the specific activity under various adsorption conditions. The activity of the adsorbed TR on composite polymer particles was higher than those of the tree TR and TR adsorbed on $Fe_3O_4$/PS particles.

• 한국산학기술학회논문지
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• 제4권3호
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• pp.172-176
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• 2003

본 논문은 금형의 온도 변화가 사출성형품의 미시구조에 미치는 영향에 관해 연구했다. 웰드라인의 폭과 길이는 금형온도가 증가함에 따라 모두 감소되었다 그리고 금형의 온도에 따른 결정성수지인 PP(Polypropylene)와 비결정성수지인 PS(Polystyrene)의 치수안정성에 관해 연구했다. PS성형품은 금형온도가 높을수록 수축률이 줄어들고, 두께 편차가 적어졌고, PP성형품의 경우에는 결정의 생성으로 인해 상반된 경향이 나타났다. 캐비티의 충전성과 전사성은 금형온도가 높을수록 향상되었다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 C
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• pp.1600-1602
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• 1996

We have investigated the anisotropic dispersion force effects for surfaces alignment of liquid crystals (LCs) on rubbed polystyrene (PS) surfaces by unidirection. In microphotographs an of the textures, we obtained the nematic (N) LCs are shown to align in both direction parallel and perpendicular to the rubbing for region up to medium rubbing, however to align in the direction perpendicular to the rubbing for strong rubbing region. We suggest that the anisotropic dispersion force is very important rather than macro-surface groove effect to uniform alignment of LCs. We also measured the temperature dependence of extrapolation length of 5CB on rubbed PS surfaces for strong rubbing. It is shown that the polar anchoring strength of 5CB is very weak on rubbed PS surface compared to the rubbed polyimide (PI) surface.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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• pp.105-108
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• 1996

We have studied the anisotropic dispersion force effects for surfaces alignment of liquid crystals (LCs) on rubbed polystyrene (PS) surfaces by unidirection. In microphotographs of the textures, we obtained the nematic (N) LCs are shown to align in both direction parallel and Perpendicular to the rubbing for region up to medium rubbing, however to align in the direction perpendicular to the rubbing for strong rubbing legion. We suggest that the anisotropic dispersion force is very important rather than macro-surface groove effect to uniform alignment of LCs. We also measured the temperature dependence of extrapolation length of 5CB on rubbed PS surfaces for strong rubbing. It is shown that the polar anchoring strength of 5CB is very weak on rubbed PS surface compared to the rubbed polyimide (Pl) surface.

• 센서학회지
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• 제32권5호
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• pp.280-284
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• 2023

In this study, a prototype micro-scale photomask and microfluidic channel mold were fabricated using the thermal shrinkage of the polymer. A polystyrene (PS) sheet was used as the heat-shrink polymer, and the patterns of the photomask and microchannel are interdigitated electrodes. Patterns were formed on the PS sheets using a commercial laser printer. The contraction ratio of the PS sheet was approximately 60% at a temperature of 150 ℃, and the transmittance was reduced by approximately 0% at a wavelength of 365 nm. The microfluidic channel had a round shape. The proposed technique is simple, facile, and inexpensive for fabricating a micro-scale photomask and microfluidic channel mold and does not involve the use of any harmful materials. Thus, this technique is well-suited for fabricating diverse micro-scale patterns and channels for prototype devices, including sensors.

• 한국식품조리과학회지
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• 제12권4호
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• pp.499-505
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• 1996

김치의 맛을 더욱 좋게 유지하면서 상품적인 가치를 높이는 한 가지 방법으로 김치 포장 용기를 개발하고자 본 연구에 착수하였다. 기존으로 사용되고 있는 PP(Polypropylene), PS(Polystyrene), PPC(Polypropylene+ceramic)와 본 연구에서 개발하고자 하는 용기인 3층으로 laminate 된 PPP(PETG+PS+PETG) 용기에 김치를 담고 6일간 발효시키면서 총젖산균수, pH, 산도, 색상, 포장내 기체조성과 자유용적, 그리고 관능적인 성질을 측정하여 비교한 결과는 다음과 같았다. 총젖산균수는 PP, PS, PPP 공기내의 김치는 발효 6시간 후부터 급증한 데 반하여 PPC는 24시간 후에 급증하였고 PPP의 것은 120시간까지도 높은 수가 유 지된 것으로 나타났다. pH는 발효 72시간에 모든 시료가 pH 4로 떨어졌으룩 PPP의 것은 발효 144시간까지 pH 4를 유지하여 다른 것보다 pH 저하가 다소 둔하였다. 색도에 있어서도 PP, PS, PPC 용기의 것이 발효48시간에 L b/a 값이 45.6-49로 떨어진 데 비하여 PPP는 53.21로 붉은색이 더 좋았고 5일 후에도 같은경향을 보였다. 또한 $CO_2$와 $O_2$의 존재량과 자유용적을 비교한 결과 PPP와 PPC가 $CO_2$량이 비교적 적고 내부자유용적의 팽창도가 높은 것으로 나타나 기체 투관성이 다른 용기에 비해 낮은 것을 알 수 있었다. 그리고 색, 풍미, 텍스쳐, 종합적인 기호도 등에 대한관능검사 결과에서도 PPP내의 김치가 발효 48시간까지 좋은 결과를 보였다. 또한 PPP 용기를 김치 포장용기로 사용하면 투명하므로 내용물의 종류와 상태를 용이하게 확인하여 선택을 확실하게 할 수 있게 하며 PP나 PS 용기보다 견고하여 내용물의 발효에 의한 팽 창시 파열되지 않아 유통기간 중 안전하며 김치의 품질도 좀 더 좋은 것으로 나타나 김치 포장용기로 적절하게 사용될 수 있을 것으로 사료된다.