• 한국세라믹학회지
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• 제54권6호
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• pp.470-477
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• 2017

Ceramic processing to fabricate 3D complex ceramic structures is crucial for structural, energy, environmental, and biomedical applications. A unique process is ceramic stereolithography, which builds ceramic green objects from CAD files from many thin liquid layers of powder in monomer, which are solidified by polymerization with a UV laser, thereby "writing" the design for each slice. This approach directly writes layers in liquid ceramic suspension and allows one to fabricate ceramic parts and products having more accurate, complex geometries and smooth surfaces. In this paper, both UV curable materials and processes are presented. We focus on the basic material principles associated with free radical polymerization and rheological behavior, cure depth and broadening of cured lines, scattering at ceramic interface and their corresponding simulation. The immediate potentials for ceramic AM to change industry fabrication are also highlighted.

• Macromolecular Research
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• 제12권2호
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• pp.240-245
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• 2004

Monodisperse PMMA micro spheres are prepared by means of a simple soap-free emulsion polymerization in methanol-enriched aqueous medium in a single step process. The size and uniformity of the microspheres are dependent on the polymerization temperature. In a stable system, the uniformity is improved with the polymerization time. The most uniform and stable micro spheres are obtained under mild agitation speed of 100 rpm at 70$^{\circ}C$. The monodisperse PMMA microspheres in the size range of 1.4-2.0 $\mu\textrm{m}$ having less than 5% size variation are successfully achieved with varying concentrations of monomer and initiator. As the monomer and initiator concentrations increase, the larger micro spheres with enhanced uniformity are obtained. However, the decreased amount of water induces the polydisperse PMMA particles due to the generation of secondary particles.

• Elastomers and Composites
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• 제31권3호
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• pp.175-182
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• 1996

Polymer latices, prepared from the emulsion polymerization of vinyl monomer compounds, are widely used for many industrial applications. Included among these are uses in paints, adhesives, flocculants, and heavy-duty plastics as well as their original use in synthetic rubber compounds. The emulsion polymerization process with chemical initiator has chemical disadvantage such as removal of initiator which was left after polymerization. In this study, polystyrene latex was prepared by using ultrasonic irradiation which generate the free radical, and then it was analyzed by GPC. Reaction temperature hardly have an effect on average molecular weight. Average molecular weight is increased by increasing amount of surfactant, i.e. SDS, but polydispersity is decreased. After 90 minutes of reaction time, increase and decrease of average molecular weight Is repeated. It is proposed that monodisperse polymer is obtained by controlling ultrasonic irradiation time and surfactant concentration.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.623-624
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• 2009

Here we report a photo polymerization-induced hybrid alignment of a nematic liquid crystal cell which can be applied for a roll to roll fabrication process. Predominant polymerization in the vicinity of UV incident front induced a diffusion of monomers toward front slide and anisotropic polymer network was formed parallel to the polarization direction of the UV light. This induced planar alignment of liquid crystals at the front slide. Simultaneously, homeotropic alignment was induced at the bottom slide as the polymers are phase-separated from a bottom slide.

• 반도체디스플레이기술학회지
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• 제18권3호
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• pp.36-41
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• 2019

Hybrid-type transparent electrodes were fabricated by depositing carbon nanotubes (CNTs) via spray coating on polyethylene terephthalate (PET) substrates and then coating the CNTs with [poly(3,4-ethylenedioxythiophene)] (PEDOT) films via electro-polymerization. For all of the fabricated electrodes, their surface morphologies, electric sheet resistances, visible transmittances, and color properties (e.g., yellowness) were characterized as functions of the applied voltages and process times used in electro-polymerization. The sheet resistance of the CNTs was significantly reduced by the coating of PEDOT, while their visible transmittances slightly decreased. The yellowness values of the PEDOT-coated CNTs were observed to have substantially decreased via electro-polymerization. The experimental results confirmed that the fabricated hybrid electrodes had desirable properties for the application of transparent electrode in terms of the electrical resistance, optical transmittance, and chromaticity.

• Macromolecular Research
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• 제14권3호
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• pp.338-342
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• 2006

The kinetic features of polymerization with an active site comprising cobalt dihalides ($CoX_2$, where X=Cl, Br, I) activated by methylaluminoxane (MAO) were investigated in 1,3-butadiene polymerization. The catalytic system exhibited the characteristic features of living polymerization. The initiation ($k_i$) and propagation ($k_p$) rate coefficients were estimated using the kinetic model for slow initiation previously reported by Shiono et al. The energy of activation fur the propagation reaction was calculated to be 27-30 $kJmol^{-1}$. The marked changes in reaction rate observed with different halides could be adequately described in terms of variations in the initiation process, with the same Arrhenius curve fitting propagation rate coeffcients estimated from all three halides, suggesting that the halide does not participate in the growing chain end.

• 한국응용과학기술학회지
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• 제6권1호
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• pp.1-7
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• 1989

To developed new process for obtaining maximum molecular weight of anionic acrylamide and acrylic acid copolymer by inverse emulsion polymerization. Concentration of initiator, reducing agent, surfactant and mole ratio of acrylamide-acrylic acid were studied for the process. Semi-batch processes with method of redox, control of reaction temperature, feeding method of monomer and reaction time, was suitable for maximum molecular weight of P(AMAC) from this process obtained $3.09\;{\time}\;10^6({\bar{M}}n.)$ and $4.41\;{\time}\;10^6({\bar{M}}w.)$ in molecular weight measured by the intrinsic viscosity method. inverse emulsion polymerization mechanism of P(AMAC) does not followed the Smith-Ewart and Medvedev theory, but selected for concentration of initiator, reducing agent, surfactant, water solubility of monomer.

• 한국정밀공학회지
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• 제21권3호
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• pp.180-187
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• 2004

The miniaturization technologies are perceived as potential key technologies of the future. They will bring about completely different ways in which people and machines interact with the physical world. However, at the present time, the primary technologies used fur miniaturization are dependent on the microelectronic fabrication techniques. The principal shortcomings associated with such techniques are related to the inability of to produce arbitrary three-dimensional features not only in electronics but also in a wide range of metallic materials. In this paper, a ultramicro-stereolithography system assisted with a femto-second laser was developed to fabricate the arbitrary three-dimensional nano/micro-scaled features. In the developed process, a femto-second laser is projected according to CAD data on a photosensitive monomer resin, it induces polymerization of the liquid resin. After the polymerization, a droplet of ethanol is dropped to remove the liquid resin and then the polymerized nano-scaled features only remain. By a newly developed process, miniature devices for an extremely wide range of applications would become a technologically feasible reality. Some of nano/micro-scaled features as examples were fabricated to prove the usefulness of this study at the fundamental stage.

• 대한가정학회지
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• 제19권2호
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• pp.213-221
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• 1981

This theiss deals with the effects of addition of silicone oil to the polymerization and oxidation of frying oil in the practical deep fat frying process. The measurement of frying oil stability was carried out under various silicone oil content and compared with controlled frying process. In controlled frying process A.V., C.O.V., TBA, and contents of petroleumether insoluble fatty acids were increased as time was increased. It means thermal oxidized polymerization and hydrolysis of frying oil was occurred. When silicone oil was added to frying oil, it's thermal stability was better than that of the controlled oil and the degree of thermal stability was changed according to the contents of silicone oil. We obtained the highest degree of thermal stability when silicone oil was added 1ppm.

• 폴리머
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• 제34권2호
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• pp.144-149
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• 2010

Ag/polystyrene(PS) 나노복합체를 110 $^{\circ}C$의 가열법에 의하여 silver 2-ethylhexylcarbamate(Ag-CB) 복합체의 환원과 동시에 라디칼 중합을 진행하여 제조하였다. 또한, 이러한 전통적인 가열법과는 대조적으로 마이크로파를 조사하여 스티렌 단량체의 중합이 진행됨이 없이 은 나노입자가 잘 분산된 콜로이드 스티렌 용액을 제조할 수 있었다. 이렇게 단지 마이크로파를 조사하여 은 나노입자를 제조하는 방법은 반응기 내의 전체 용액 속에서 균일하고 빠르게 진행되어 매우 입자가 작고 균일한 은 나노콜로이드 용액을 제조할 수 있었다. 또한, 연속적으로 얻어진 은 나노입자를 포함하는 단량체 용액을 라디칼 중합시킴으로써 PS 고분자 매트릭스에 은 나노입자가 잘 분산된 Ag/PS 나노복합체를 얻을 수 있었다. Ag/PS(0.1/100) 나노복합체는 Ag/PS(4.0/100)를 마스터배치로 사용하여 용융-혼합 방법에 의하여 성공적으로 제조할 수 있었으며 그러한 나노복합체를 UV-VIS spectroscopy, TEM, 그리고 XRD를 이용하여 확인하였다.