• Title/Summary/Keyword: polymeric liquid

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Poly (vinyl acetate)-Ionic Liquids Membranes for $CO_2$ Capture (이산화탄소 포집용 폴리비닐아세테이트-이온성액체 막)

  • Lee, Sang-Jin;Choe, Su-Hyeon;Baek, Il-Hyeon
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2010.04a
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    • pp.199-199
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    • 2010
  • Polymeric membranes have been widely used to separate gas mixtures, such as $O_2/N_2,\;CO_2/CH_4,\;CO_2/N_2$, and olefin/paraffin. The permeation selectivity is the ratio between composition ratio at the permeate side and composition ratio at the feed side. In addition, the permeation selectivity is a product of solubility selectivity and diffusivity selectivity. We present a novel idea and describe its experimental result, which was achieved by preparing polymer gel films that included a room temperature ionic liquid (RTIL) in a polymer matrix. It is known that $CO_2$ can dissolve easily in imidazolium-based RTILs. We prepared polymer-ionic liquid gel films using an ionic liquid, 1-ethyl-3-methylimidazolium acetate ([emim] acetate, C-tri) and a host polymer, poly (vinyl acetate) (PVAc, Aldrich).

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Modified Poly(3,4-ethylenedioxythiophene) with Poly(ionic liquid)s as a new hole injecting materials in organic light emitting diodes (OLEDs)

  • Kim, Earl;Kim, Tae-Young;Suh, Kwang-Seok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.132-132
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    • 2010
  • In a previous report, we demonstrated that poly (3,4-ethylenedioxythiophene) derived from poly (ionic liquid) (PEDOT:PIL) constitutes a polymeric hole-injecting material capable of improving device lifetime in organic light-emitting diodes (OLEDs).was attributed to aprotection characteristic of PEDOT:PIL for the indium extraction from ITO electrodes, which frequently occurrs in the OLED device with the conventional PEDOT materials. In this study, we report the OLED device lifetime as well asvice efficiencycan be further improved with the modified PEDOT:PIL in whichorganic compounds are incorporated. The deviced performance will be presented in terms of device lifetime and efficiencies.

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Soft-lithography for Preparing Patterned Liquid Crystal Orientations

  • Kim, Hak-Rim;Jung, Jong-Wook;Shin, Min-Soo;Kim, Myung-Eun;Lee, You-Jin;Kim, Jae-Hoon
    • Journal of Information Display
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    • v.8 no.2
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    • pp.5-9
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    • 2007
  • We demonstrate novel soft-lithographic techniques for preparing patterned liquid crystal (LC) orientations at an alignment layer. By controlling patterning conditions such as wetting property and operating temperature depending on polymeric materials, multi-directional or modified LC alignment conditions can be simply achieved.

Effect of Biofilm Formation on Soil Sorbed Naphthalene Degradation (Biofilm 생성이 토양흡착 나프탈렌 분해에 미치는 영향)

  • Li, Guang-Chun;Chung, Seon-Yong;Park, Jeong-Hun
    • Journal of Soil and Groundwater Environment
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    • v.14 no.6
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    • pp.45-52
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    • 2009
  • Naphthalene-degrading bacteria Pseudomonas aeruginosa CZ6 isolated from contaminated soil can adhere to crystal naphthalene and produce extracellular polymeric substance. LB, YM and MSM medium were used as culture mediums to investigate the formation of biofilm. Biofilm was developed the most in LB medium by Pseudomonas aeruginosa CZ6. In the culture, strain CZ6 growth was rarely affected by naphthalene concentration. Optimal culture condition was $30^{\circ}C$ and pH 7 at 0.10% substrate and 150 rpm shaking. The effect of culture medium on naphthalene degradation in the two soil slurry system was evaluated. The initial degradation rate of naphthalene was highest in the MSM medium of soil slurry. However, the sorbed naphthalene was rapidly degraded at the LB medium when naphthalene availability in liquid was limited. The results of this study suggest that biofilm formation and extracellular polymeric substance production increased bioavailability of soil sorbed naphthalene.

Development of a Simulation Program to Predict the Performance of the Multi-grade Lubricant before Blending Base Oil with Additives (기유와 첨가제 혼합 전 다등급 윤활유의 성능 예측 시뮬레이션 프로그램 개발)

  • Chun, Sang-Myung
    • Tribology and Lubricants
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    • v.28 no.2
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    • pp.47-55
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    • 2012
  • Generally, to product multi-grade oil like engine oil, a sort of mineral base oil is mixed with a fundamental additive package liquid and a polymer liquid as viscosity index improver in order to improve the lubricating property of base oil. That is, engine oil is the mixture of more than two fluids. Specially, a polymeric type liquid cannot be seen as the linear viscosity like Newtonian fluids. In this research, by using the governing equation describing non-Newtonian hydrodynamic lubrication related with the mixture of incompressible fluids based on the principle of continuum mechanics, it will be compared the bearing performance between the mixture of each liquid to be blended and multi-grade engine oil as a single fluid in a high speed hydrodynamic journal bearing. Further, it is to be found the way estimating the performance of the blended multi-grade engine lubricant in a journal bearing in advance before blending by using the physical properties of mineral base oil, fundamental additive liquid and polymer liquid of viscosity index improver. So, it can be reduced the number of trial and error to get the wanted lubricant by selecting the proper volume fraction of each liquid to satisfy the expected performance and estimating in advance the performance of various multi-grade oils before blending. Therefore, it can be shorten the developing time and saved the developing cost.

Liquid Crystalline Polymer for the Alignment of Ferroelectric Liquid Crystal Display (강유전정 액정 디스플레이의 배향을 위한 액정성 고분자)

  • Jin, Sung-Ho;Jeon, Young-Jae;Lee, Jong-Chun;Kim, Gang
    • Korean Journal of Materials Research
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    • v.10 no.5
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    • pp.350-353
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    • 2000
  • Thermotropic liquid crystalline polymer(LCP) has been used for the alignment of ferroelectric liquid crystal (FLC) molecules and the surface morphology of the resulting polymeric thin film has been observed by atomic forced microscope. The uniform alignment of FLC molecules on the surface of thermotropic LCP thin film was obtained even though microgroove structures were not formed. The contrast ratio of sample cell was about 23:1 including two polarizers and a good memory capability due to the bistability of FLC was obtained. After AC field stabilization at 20V, the typical stripe-shaped patterns appeared.

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Isolation and Characterization of White Rot Fungi for Decolorization of Several Synthetic Dyes (염료의 색도 제거능력이 우수한 백색부후균 분리 및 특성연구)

  • 오광근;김현수;조무환;채영규;전영중
    • Microbiology and Biotechnology Letters
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    • v.27 no.6
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    • pp.500-508
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    • 1999
  • Several white-rot fungi collected from the mountains of Korea were evaluated for their ability to decolorize azo, polymeric, and reactive dyes. Strains CJ-105, CJ-212 and CJ-315, identified as Trametes sp., Pleurotus sp. and Fomes sp., respectively, showed higher potential for decolorization of those dyes in either solid or liquid media. For Trametes sp. CJ-105, 100ppm of Remazol Brilliant blue R and 500ppm of Acid Red 264 were completely decolorized after 2 days under liquid culture. The dominating ligninolytic enzyme existing in the culture broth was laccase (E.C. 1.10.3.2). Also, Pleurotus sp. CJ-212 and Fomes sp. CJ-315 showed similar patterns in decolorization of Remazol Brilliant Blue R and Acid Red 264. The extent of decolorization of the dyes in liquid culture was found to be proportional to the activities of the ligninolytic of decolorization of the dyes in liquid culture was found to be proportional to the activities of the ligninolytic enzymes produced by each strain. In addition to that Trametes sp. CJ-105 was highly effective in degradation of polycyclic aromatic hydrocarbons and pentachlorophenol by the activity of the ligninolytic enzymes produced. In this study, we found that white-rot fungi, Trametes sp. CJ-105(KFCC 10941), Pleurotus sp. CJ-212(KFCC 10943) and Fomes sp. CJ-315(KFCC 10942), were effective in decolorizing a wide range of structurally different synthetic dyes, as well as some chemical compounds which are known to be hardly degradable.

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Holographic Polymer-Dispersed Liquid Crystals and Polymeric Photonic Crystals Formed by Holographic Photolithography

  • Kyu Thein;Meng Scott;Duran Hatice;Nanjundiah Kumar;Yandek Gregory R.
    • Macromolecular Research
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    • v.14 no.2
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    • pp.155-165
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    • 2006
  • The present article describes the experimental and theoretical observations on the formation of holographic, polymer-dispersed, liquid crystals and electrically switchable, photonic crystals. A phase diagram of the starting mixture of nematic liquid crystal and photo-reactive triacrylate monomer was established by means of differential scanning calorimetry (DSC) and cloud point measurement. Photolithographic patterns were imprinted on the starting mixture of LC/triacrylate via multi-beam interference. A similar study was extended to a dendrimer/photocurative mixture as well as to a single component system (tetra-acrylate). Theoretical modeling and numerical simulation were carried out based on the combination of Flory-Huggins free energy of mixing and Maier-Saupe free energy of nematic ordering. The combined free energy densities were incorporated into the time-dependent Ginzburg-Landau (Model C) equations coupled with the photopolymerization rate equation to elucidate the spatio-temporal structure growth. The 2-D photonic structures thus simulated were consistent with the experimental observations. Furthermore, 3-D simulation was performed to guide the fabrication of assorted photonic crystals under various beam-geometries. Electro-optical performance such as diffraction efficiency was evaluated during the pattern photopolymerization process and also as a function of driving voltage.

Cycling Performance and Surface Chemistry of Si-Cu Anode in Ionic Liquid Battery Electrolyte Diluted with Dimethyl Carbonate

  • Nguyen, Cao Cuong;Kim, Dong-Won;Song, Seung-Wan
    • Journal of Electrochemical Science and Technology
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    • v.2 no.1
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    • pp.8-13
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    • 2011
  • Interfacial compatibility between the Si-Cu electrode and diluted ionic liquid electrolyte containing 50 vol.% of 1M lithium bis(trifluoromethanesulfonyl)imide (LiTFSI)/1-methyl-1-propylpyrrolidinium bis(trifluoromethylsulfonyl)imide (MPP-TFSI) and 50 vol.% dimethyl carbonate (DMC) in a lithium cell and dilution effect on surface chemistry are examined. ex-situ ATR FTIR analysis results reveal that the surface of the Si-Cu electrode cycled in the diluted ionic liquid electrolyte is effectively passivated with the SEI layer mainly composed of carboxylate salts-containing polymeric compounds produced by the decomposition of DMC. Surface species by the decomposition of TFSI anion and MPP cation are found to be relatively in a very low concentration level. Passivation of electrode surface with the SEI species contributes to protect from further interfacial reactions and to preserve the electrode structure over 200 cycles, delivering discharge capacity of > 1670 $mAhg^{-1}$ and capacity retention of 88% of maximum discharge capacity.

Sythesis and Properties of Liquid Crystalline Polyurethane Elastomers

  • Lee, Tae-Jung;Lee, Dong-Jin;Kim, Han-Do
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.98-101
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    • 1998
  • Segmented polyurethane elastomers are an important class of polymeric materials consisting of thermodynamically incompatible hard and soft segments. Due to the chemical structural difference between the hard and soft segments, a microphase separation occurs, consisting of crystalline hard domains and amorphous soft domains. (omitted)

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