• Title/Summary/Keyword: polymeric dielectric

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Laminating Rule for Predicting the Dielectric Properties of the E-glass/Epoxy Laminate Composite (유리섬유/에폭시 복합재료 적층판의 유전성질 예측을 위한 적층판 법칙)

  • Chin, Woo-Seok;Lee, Dai-Gil
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.04a
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    • pp.141-145
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    • 2005
  • Since the electromagnetic properties of fiber reinforced polymeric laminate composite can be tailored effectively by adjusting its composition and regulating the stacking sequence, it is plausible material for fabricating the radar absorbing structures (RAS) of desired performance. In order to design the effective electromagnetic wave (EM) absorber with the fiber reinforced polymeric laminate composite, its electromagnetic characteristics should be available and could be regulated easily in the target frequency bands. In this study, dielectric characteristics of the E-glass/epoxy laminate composites were measured by the free space method in the X-band frequency range ($8.2\;{\sim}\;12.4\;GHz$). In order to describe the dielectric behavior of laminate composites of arbitrary stacking sequences, the equivalent circuit model and the laminating equations for estimating dielectric properties were proposed, and experimentally verified. From the comparison of the predicted and measured data, the proposed method predicted well the experimentally measured data.

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Binary Mixture Rule for Predicting the Dielectric Properties of Unidirectional E-glass/Epoxy Composite Materials (일방향 유리섬유/에폭시 복합재료의 유전성질 예측을 위한 혼합법칙)

  • Chin Woo Seok;Lee Dai Gil
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.175-179
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    • 2004
  • Since the electromagnetic properties of fiber reinforced polymeric composites can be tailored effectively by adding small amount of electromagnetic powders to the matrix of composites, they are plausible materials for fabricating the radar absorbing structures (RAS) of desired performance. In order to design the effective electromagnetic wave (EM) absorber with the fiber reinforced polymeric composites, the electromagnetic characteristics with respect to the constituents of the composite should be available in the target frequency band. In order to describe the dielectric behavior of low loss unidirectional fiber reinforced composite, theoretical models and mixture equations for estimating its dielectric constant were proposed with respect to the fiber, matrix volume fractions and fiber orientations, and verified by the experiments. From the investigation, it was found that the suggested binary mixture rules agreed well with the experimental results.

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Novel Smart Polymeric Composites for Thermistors and Electromagnetic Wave Shielding Effectiveness from TiC Loaded Styrene-Butadiene Rubber

  • Sung, Yong-Kiel;Farid EI-Tantawy
    • Macromolecular Research
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    • v.10 no.6
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    • pp.345-358
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    • 2002
  • The electrical conductivity during vulcanization process was measured as a function of time for the system of TiC loaded styrene-butadiene rubber (SBR) composites. The phenomenon of negative and positive temperature coefficients of conductivity and its conduction mechanism were also studied for the SBR polymeric composites. The current-voltage characteristics of the polymeric composites were non-linear in high voltage and showed a switching effect. The effects of temperature on the thermal conductivity and effective dielectric constant were measured. The measured parameters were found to be dependent on TiC concentration. The electromagnetic wave shielding (EMS) of the SBR-TiC polymeric composite was also examined. The SBR filled with TiC could be expected to be promising novel smart polymeric composites for self-electrical heating, temperature sensor, time delay switching, and electro-magnetic wave shielding effectiveness.

Electrical Treeing Deterioration and Dielectric Breakdown Phenomena in Polymeric Insulator (고분자 절연재료에서 전기트리 열화 및 절연파괴 현상)

  • Cho, Yeong-Sin;Kim, Sang-Uk
    • Korean Journal of Materials Research
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    • v.9 no.4
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    • pp.398-403
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    • 1999
  • Studies on the electrical treeing deterioration and dielectric breakdown phenomena in the polymeric insulator of polyethylene and epoxy resin were carried out. Block type samples with needle-plane electrode geometry were electrically stressed and the tree pattern from the needle tip was observed. In LDPE the density of electrical tree was very high and its pattern was bush type. For the case of XLPE, branched tree was observed. As temperature and SN content increased, the dielectric breakdown voltage decreased and the treeing phenomena became more complicated. Fan type cracks were observed around the conducting tree path in the brittle DGEBA/MDA system.

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Fabrication of Thin Film Dielectric by Hybrid Sol (Hybrid Sol을 이용한 박막 유전체 제작)

  • Kim, Yong-Suk;Yoo, Won-Hee;Chang, Byeung-Gyu;Oh, Yong-Soo
    • Korean Journal of Materials Research
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    • v.17 no.4
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    • pp.185-191
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    • 2007
  • The purpose of this study is to evaluate the thin fihn dielectric made of hybrid sol, which consist of barium titanate powder, polymeric sol and other polymers. This sol will be used dielectric applied to small, thin electric passive components such as MLCC(Multi Layer Ceramic Condenser), resister, inductor. This sol is composed of mixed fine barium titanate powder and polymeric sol including Ba, Ti-precursor, solvent, chelating agent, chemical reaction catalyst, the additive sols to improve fired densification and temperature reliability. First at all, we mixed hybrid sol to be dispersed and be stabilized by ball milling for 24hrs. By spin coating method, we makes thin film dielectric on the convectional green sheet for MLCC. After heat treatments, we analyzes the structure morphology, physical, electrical properties and X5R Temperature properties.

Characterization and experimental investigation for gamma-ray shielding competence of basalt-doped polyethylene nanocomposites

  • I.A. El-Mesady;F.I. El-Agawany;H. El-Samman;Y.S. Rammah;A. Hussein;R.A. Elsad
    • Nuclear Engineering and Technology
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    • v.56 no.2
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    • pp.477-484
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    • 2024
  • Experimental investigations on gamma - rays attenuation parameters and dielectric spectroscopic properties were done on a polymeric mixture with chemical composition (100-x) polyethylene + x basalt, where x = 0, 1, 3, 5, 10, and 20 wt%. Using the melting blending technique,six nanocomposite polymeric samples were prepared. The linear attenuation coefficient µ of each prepared set of samples was measured using a gamma-ray spectrometer including High Purity Germanium detector (HPGe) at energies 662.5, 1173.24, and 1332.51 keV. Based on the measured values of (µ) and sample density, the other effective shielding parameters were calculated. The values of µ showed an increase with increasing the dopant ratios from 0.0 up to 20.0 wt%. In addition, the µ values decreased with the photon's energy. The µ values were found 0.0847 up to 0.1175 cm-1, 0.0571 up to 0.0855 cm-1, and 0.0543 up to 0.075 cm-1 at 662.5, 1173.24, and 1332.51 keV. for B0 up to B20, respectively. The ATR spectroscopy was done on the prepared samples, and a good evidence of adding the filler to the pure polyethylene (HDPE) was obtained. Besides, an enhancement in dielectric constant by insertion of basalt NPs also recorded and can be attributed to the large dielectric constant of basalt compared to pure HDPE.

ZnO Thin Film Transistor Prepared from ALD with an Organic Gate Dielectric

  • Choi, Woon-Seop
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.543-545
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    • 2009
  • With injection-type source delivery system of atomic layer deposition (ALD), bottom-contact and bottom-gate thin-film transistors (TFTs) were fabricated with a poly-4-vinyphenol polymeric dielectric for the first time. The properties of the ZnO TFT were greatly influenced by the device structure and the process conditions. The zinc oxide TFTs exhibited a channel mobility of 0.43 $cm^2$/Vs, a threshold voltage of 0.85 V, a subthreshold slope of 3.30 V/dec, and an on-to-off current ratio of above $10^6$ with solid saturation.

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New Polytriazoleimides with High Thermal and Chemical Stabilities

  • E, Yanpeng;Wan, Liqiang;Li, Yujing;Huang, Farong;Du, Lei
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2193-2199
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    • 2012
  • A series of novel polytriazoleimides were prepared from various aromatic dianhydrides and a new kind of 1,2,3-triazole-containing aromatic diamine synthesized by the Cu (I)-catalyzed 1,3-dipolar cycloaddition reaction in DMAc, and characterized by FT-IR, $^1H$-NMR, XRD, DSC and TGA techniques. The results show the polytriazoleimides are soluble in most of strong polar solvents and have inherent viscosity values of 0.51-0.62 dL/g(DMAc). The polytriazoleimide films exhibit a tensile strength of 62.3-104.5 MPa and an elongation at breakage of 4.0-8.1%, a glass transition temperature ($T_g$) of $257-275^{\circ}C$, a decomposition temperature (at 5% weight loss) of $350-401^{\circ}C$ in $N_2$ atmosphere, and a dielectric constant of 2.47-3.01 at 10 MHz, which depend on the structure of the polymers. The polytriazoleimides perform good resistance to acid and alkali solution.

Measurement of Material Property of Thin Film and Prediction of Residual Stress using Laser Scanning Method (레이저 주사법을 이용한 박막 물성 측정 및 잔류응력 예측)

  • Lee, Sang-Soon
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.4 s.33
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    • pp.49-53
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    • 2004
  • Polymeric materials are widely used in the electronic industry as a common dielectric material or adhesive. The polymeric layer coated on Si substrate can be subjected to thermal stresses due to difference in thermal expansion coefficients. The mismatch in thermal properties between the polymeric layer and the substrate results in significant residual stresses. In this study, the thermal deformation is measured by a curvature measurement method using laser scanning, and the elastic modulus is calculated by an analytic model.

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Novel Approaches of Modified Poly (4-vinylphenol) for Low Hysteresis Organic Thin Film Transistors

  • Kim, Hyoung-Jin;Kim, Doo-Hyun;Kim, Byung-Uk;Kim, We-Yong;Kim, Ho-Jin;Hong, Mun-Pyo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1305-1307
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    • 2009
  • We have investigated the new modification of poly (vinyl phenol) (PVP) for low hysteresis organic thin film transistors (OTFTs). In order to suppression of hysteresis phenomenon, synthesized various backbone structure polymeric gate dielectric. The modified polymeric dielectric was synthesized by inducing ringshape phenol backbone structure instead of conventional chain. We could be observed that relieved hysteresis and excellent air stability from ring-shape phenol backbone structure.

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