• Proceedings of the IEEK Conference
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• 1999.06a
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• pp.315-318
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• 1999

As low-cost optical waveguides of optical interconnects, we fabricate multimode optical waveguides using a molding process The core size of a optical waveguide is 47 ${\mu}{\textrm}{m}$ $\times$ 41 ${\mu}{\textrm}{m}$. We use the photoresist AZ9260 as a master, polydimethyl-siloxane (PDMS) as a mold. In transferring process to polymeric material, we employ a modified micro-transfer molding process. All processes are simple and low-cost.

• Macromolecular Research
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• v.10 no.1
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• pp.49-52
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• 2002

Rod-coil amphiphilic block copolymers, PALG-PEOs, poly(alkyl $\alpha$, L-glutamate-co-ethylene oxide)s, were successfully synthesized in three steps: 1) esterification of L-glutamic acid, 2) synthesis of ${\gamma}$-alkyl L-gultamate N-carboxyanhydride, and 3) polymerization of NCA monomers. These molecules form polymeric micelles with the hydrophobic core and hydrophilic corona in aqueous solution, which were characterized by light scattering and static fluorescence measurement.

• Proceedings of the PSK Conference
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• 2002.10a
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• pp.409.1-409.1
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• 2002

For the development of a biocompatible nano-scale drug carrier. hydrophilic polysaccharide pullulan was hydrophobized by the conjugation with fatty acid. The synthesized polymers were characterized by the measurements of fourier transform infrared (FT -IR) spectroscopy and 1H -nuclear magnetic resonance (NMR) spectroscopy. In aqueous solution. hydrophobically modified puliulan was self-assembled and structured into the core-shell type nanoparticles. (omitted)

• Korean Journal of Optics and Photonics
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• v.16 no.1
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• pp.79-84
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• 2005

To increase the tolerance for passive fiber alignment, a single mode polymer waveguide with a large core structure is demonstrated. The large core waveguide is designed to have a mode profile comparable to that of a thermally expanded core (TEC) fiber, and it can be connected to a high-contrast waveguide through an adiabatic transition taper structure. From a waveguide with a rectangular core of 25 ${\times}$ 25 ${\mu}{\textrm}{m}$$^2$, a single mode propagation is observed when the index contrast is as low as 0.0005. A UV-cured injection molding method is used to fabricate the thick core structure. Due to the large mode size, the insertion loss of the device is below 0.5 dB until the lateral displacement of the TEC fiber is 4.5 ${\mu}{\textrm}{m}$. The low insertion loss is important for reproducible passive alignment.

• Journal of the Optical Society of Korea
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• v.13 no.2
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• pp.294-298
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• 2009

In this paper we proposed a new Bragg grating waveguide in order to improve reflectivity and to achieve compactness. Bragg gratings with various thicknesses were engraved in the middle of the core layer with a length of 3 mm. For the sake of cost-effectiveness, the $3^{rd}$ order Bragg grating waveguides were fabricated via conventional photolithography. The maximum reflectivities for the fixed width waveguide of $6{\mu}m$ with the 0.1 and $0.3{\mu}m$-thick Bragg gratings were, -13.14 and -6.25 dB, respectively, and the Bragg wavelengths were 1562.28, 1564.10 nm, respectively. A slight increase in the Bragg grating thickness can result in a remarkable reduction in the length of the Bragg grating waveguide with a fixed reflectivity.

• Steel and Composite Structures
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• v.46 no.2
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• pp.203-210
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• 2023

In the present research, dynamic deflections of a sandwich beam having functionally graded (FG) porous core have been investigated assuming that the sandwich beam is exposed to a pulse load of blast type. The two layers of sandwich beam have been made of a polymeric matrix reinforced by graphene oxide powder (GOP). The micromechanical formulation of the layers has been done via Halpin-Tsai model. The solution method is chosen to be Ritz method which is an efficient method to solve the system of equations of beams modeled based on a higher-order theory. To derive the time history of sandwich beam under pulse load, Laplace method has been used. The porosity content of the core, the GOP content of the layers, thickness of the layer and also duration of the applied load have great influences of the responses of sandwich beam.

• Bulletin of the Korean Chemical Society
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• v.22 no.5
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• pp.467-475
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• 2001

A triblock copolymer based on $poly(\varepsilon-caprolactone)$ (PCL) as the hydrophobic part and poly(ethylene glycol) (PEG) as the hydrophilic portion was synthesized by a ring-opening mechanism of ${\varepsilon}-caprolactone$ with PEG containing a hydroxyl group at bot h ends as an initiator. The synthesized block copolymers of PCL/PEG/PCL (CEC) were confirmed and characterized using various analysis equipment such as 1H NMR, DSC, FT-IR, and WAXD. Core-shell type nanoparticles of CEC triblock copolymers were prepared using a dialysis technique to estimate their potential as a colloidal drug carrier using a hydrophobic drug. From the results of particle size analysis and transmission electron microscopy, the particle size of CEC core-shell type nanoparticles was determined to be about 20-60 nm with a spherical shape. Since CEC block copolymer nanoparticles have a core-shell type micellar structure and small particle size similar to polymeric micelles, CEC block copolymer can self-associate at certain concentrations and the critical association concentration (CAC) was able to be determined by fluorescence probe techniques. The CAC values of the CEC block copolymers were dependent on the PCL block length. In addition, drug loading contents were dependent on the PCL block length: the larger the PCL block length, the higher the drug loading content. Drug release from CEC core-shell type nanoparticles showed an initial burst release for the first 12 hrs followed by pseudo-zero order release kinetics for 2 or 3 days. CEC-2 block copolymer core-shell type nanoparticles were degraded very slowly, suggesting that the drug release kinetics were governed by a diffusion mechanism rather than a degradation mechanism irrelevant to the CEC block copolymer composition.

• Polymer(Korea)
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• v.30 no.5
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• pp.437-444
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• 2006

Reactive hydroxypropyl methylcellulose phthalate (reactive HPMCP) was synthesized by using a stepwise urethane reaction with isophorone diisocyanate (IPDI) and 2-hydroxyethyl moth acrylate (HEMA). Molecular weight, acid number, and critical micelle concentration (CMC) of the synthesized reactive HPMCP and pristine HPMCP were measured and used as a polymeric surfactant in the emulsion polymerizations of styrene. In the preparation of HPMCP-hybrid poly styrene nanoparticles, 6, 9, 12, 18, and 24 wt% of HPMCPs were introduced, and the maximum rate of polymerization ($R_{p,max}$), the average number of radicals per particle (n), particle size distribution were investigated. In addition, core - shell morphology of the nanoparticles were observed by using TEM and their thermal stabilities were measured by using TGA. Reactive HPMCP showed higher $R_{p,max}$, smaller particle size, larger values of n and gel contents as compared with pristine HPMCP, due to the vinyl groups from HEMA, which can be reacted with styrene oligomers, in the reactive HPMCP.

• Bulletin of the Korean Chemical Society
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• v.29 no.8
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• pp.1539-1544
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• 2008

A polymeric micelle, based on the poly(benzyl-L-histidine)-b-poly(ethylene glycol) (polyBz-His-b-PEG) diblock copolymer, was designed as a tumor-specific targeting carrier. The micelles (particle size: 67-80 nm, critical micelle concentration (CMC); 2-3 $\mu$g/mL) were formed from the diafilteration method at pH 7.4, as a result of self-assembly of the polyBz-His block at the core and PEG block on the shell. Removing benzyl (Bz) group from polyBz-His block provided pH-sensitivity of the micellar core; the micelles were physically destabilized in the pH range of pH 7.4-5.5, depending on the content of the His group free from Bz group. The ionization of His group at a slightly acidic pH promoted the deformation of the interior core. These pHdependent physical changes of the micelles provide the mechanism for pH-triggering anticancer drug (e.g., doxorubicin: DOX) release from the micelle in response to the tumor’s extracellular pH range (pH 7.2-6.5).

• Journal of the Korean Institute of Telematics and Electronics D
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• v.35D no.11
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• pp.85-90
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• 1998

A 1 4 polymeric optical power divider based on the multimode interference effect is designed and fabricated. The two dimensional finite difference beam propagation method has been utilized in designing the device. Polymers used for the core layer and the cladding layer are Cyclotene-3022 and UV-15, respectively. The device is fabricated by the reactive ion etching method. The splitting ratio of the fabricated device is 0.93 : 1.00 : 0.93 : 0.90 for TE mode and 0.84 : 0.94 : 1.00 : 0.83 for TM mode. The advantages of this device are small size and low polarization-dependence.