• Polymer(Korea)
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• v.37 no.2
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• pp.218-224
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• 2013

Graphene oxide (GO) was prepared by the Hummers and Offeman method from graphite. Two different types of functionalized graphene sheets (FGSs) were synthesized by using GO. Hexamethylamine (HDA) substituted vertically to the graphene sheet (Ver-HDA-GS) was synthesized from HDA and epoxy group in GSs. Whereas, horizontally substituted hexadecanol (HDO) to the GS(Hor-HDO-GS) was synthesized from HDO and alcohol groups via reduced GO (RGO), respectively. The structures of the GO, RGO, Ver-HDA-GS, and Hor-HDO-GS were identified by Fourier transform infrared (FTIR). In addition, we examined the thermal stability and morphology. Atomic force microscope (AFM) disclosed that Ver-HDA-GS consisted of one- or two-layer graphene regions. However, the Ver-HDA-GS layers showed average thickness of 1.76 nm. The thermal stabilities of the FGSs were better than those of the GO and RGO. The Ver- HDA-GS was well dispersed in common solvents such as dimethyl sulfoxide (DMSO), toluene, chloroform, and decalin.

• Elastomers and Composites
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• v.46 no.3
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• pp.231-236
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• 2011

The polyacrylate/multi-walled carbon nanotube (MWNT) composites were prepared and investigated for the application as a counter electrode in solar cell. The electrical conductivity of the composites was increased with increasing MWNT content and with the thickness of the sheet. The surface resistivity value of the composite at 50 wt% loading of MWNT was 0.36 ${\Omega}$/sq. The thermal decomposition temperature of the composites was also increased with the MWNT contents, and the increase of $15^{\circ}C$ was observed at the composite of polyacrylate/MWNT (50/50, w/w). The increase of storage modulus of the composites was observed, especially at the higher temperature compared to polyacrylate. The dimensional change of polyacrylate decreased over $20^{\circ}C$, but that of the composite increased linearly with the temperature. The morphology of the composites stands for the good dispersion of MWNT into the polyacrylate matrix.

• Analytical Science and Technology
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• v.21 no.2
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• pp.117-122
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• 2008

Dual scintillator for simultaneous alpha- and beta-ray counting used by detection materials of a surface contamination monitor was developed. In this study, preparation method was not a heat melting method but a solvent method, by which the counting material was manufactured by dissolving the polymer materials with solvent. It was simplified the preparation process. Plastic scintillator for beta-ray counting was prepared by solidifying the casting solution mixed with organic scintillator, polymer, and solvent. ZnS(Ag) scintillator layer was prepared by screen printing the paste solution mixed with ZnS(Ag), paste, and solvent onto the plastic layer. The good counting ability for alpha- and beta-ray using the ZnS(Ag)/plastic dual scintillator prepared and possibility for the counting material of surface contamination monitor was confirmed.

• Journal of Biomedical Engineering Research
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• v.27 no.6
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• pp.418-426
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• 2006

In the artificial heart application, productivity and hemodynamic properties of artificial heart valves are crucial in successiful application to long term in vivo trials. This paper is about manufacture and assessment of trileaflet polymer heart valves using vacuum forming process(VFP). The VFP has many advantages such as reduced fabrication time, reproducibility due to relatively easy and simple process for manufacturing. Prior to VFP of trileaflet polymer heart valves, polyurethane(Pellethane 2363 80AE, Dow Chemical) sheet was prepared by extrusion. The sheets were heated and formed to mold shape by vacuum pressure. The vacuum formed trileaflet polymer heart valves fabrication is composed of two step method, first, leaflet forming and second, conduit forming. This two-step forming process made the leaflet-conduit bonding stable with any organic solvents. Hydrodynamic properties and hemocompatibility of the vacuum formed trileaflet polymer heart valves was compared with sorin bicarbon bileaflet heart valve. The percent effective orifice area of vacuum formed trileaflet polymer heart valves was inferior to bileaflet heart valve, but the increase of plasma free hemoglobin level which reflect blood damage was superior in vacuum formed trileaflet polymer heart valves Vacuum formed trileaflet polymer heart valves has high productivity, and superior hemodynamic property than bileaflet heart valves. Low manufacturing cost and blood compatible trileaflet polymer heart valves shows the advantages of vacuum forming process, and these results give feasibility in in vivo animal trials in near future, and the clinical artificial heart development program.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.116.1-116.1
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• 2011

Materials with a combination of high electrical conductivity and optical transparency are important components of many electronic and optoelectronic devices such as liquid crystal displays, solar cells, and light emitting diodes. In this study, to fabricate a low-resistance and high optical transparent electrode film for organic photovoltaic, the following steps were performed: the design and manufacture of an electroforming stamp mold, the fabrication of thermal roll imprinted (TRI) poly-carbonate (PC) patterned films, the manufacture of high-conductivity and low-resistance Ag paste which was filled into patterned PC film using a doctor blade process and then coated with a thin film layer of conductive polymer by a spin coating process. As a result of these imprinting processes the PC films obtained a line width of $10{\pm}0.5{\mu}m$, a channel length of $500{\pm}2{\mu}m$, and a pattern depth of $7.34{\pm}0.5{\mu}m$. After the Ag paste was used to fill part of the patterned film with conductive polymer coating, the following parameters were obtained: a sheet resistance of $9.65{\Omega}$/sq, optical transparency values were 83.69 % at a wavelength of 550 nm.

• Journal of the Korea Concrete Institute
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• v.14 no.6
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• pp.922-933
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• 2002

Since the deterioration of concrete bridge decks affect durability, safety, and function, structural rehabilitation of damaged concrete deck that was strengthened with Fiber Reinforced Polymer(FRP) is increasing the latest. But recent studies on the strengthened structures are focused on the static behavior, however only a few studies on the fatigue behavior are performed. In this study, static and fatigue behavior of strengthened deck were peformed on 11 deck specimens strengthened with sheet typed Glass Fiber Reinforced Polymer(GFRP) that were reinforced by two different strengthening methods for the static test. A amount of strengthening material in the each direction such as transverse and longitudinal was adopted experimental variables for the static test and also the stress level of the static maximum load are adopted for the fatigue test. By the results of the experimental study, with respect to the strengthened decks, the resistance effect of crack propagation and effect of stress distribution are improved. In addition, the rate of variation of compliance decreased.

• Journal of Hydrogen and New Energy
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• v.23 no.1
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• pp.34-42
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• 2012

Gas diffusion layers (GDLs) of carbon composite type in polymer electrolyte fuel cells were prepared by simple and cheap manufacturing process. To obtain the carbon composite GDLs, carbon black with polymer binder was mixed in solvent, rolled to make sheet, and finally heat-treated at $340^{\circ}C$. The performance of fuel cell using composite GDLs was changed by PTFE content. The physical properties of composite GDLs for pore, conductivity and air permeability were analyzed to compare with the variation of fuel cell performance. The conductivity of composite GDLs was very similar to carbon paper as commercial GDL but pore properties and air flux were considerably different. The porosity, PTFE content and conductivity for composite GDLs did not have an influence on the cell performance much. The increase of pore diameter and air flux led to enhance cell performance.

• Composites Research
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• v.23 no.2
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• pp.17-23
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• 2010

The stealth technology can increase the survivability of aircrafts or warships and enhance the capability of mission completion in hostile territory. The purpose of this paper is to present the low observable structure with curved surfaces made by fiber-reinforced composites and to show the possibility of developing omnidirectional stealth platforms for military applications. In this study, we developed a radar absorbing structures(RAS) based on a circuit analog absorber to reduce the radar cross section(RCS) of an object with curved surfaces. Firstly, the RAS with a periodic square patterned conducting polymer layer was designed and simulated using a commercial 3-D electromagnetic field analysis program. Secondly, the designed semi-cylindrical structure with low RCS was fabricated using fiber-reinforced composites and conducting polymer. To make the periodic pattern layer, acts as resistive sheet, the intrinsic conducting polymer paste containing PEDOT with a polyurethane binder was used. Finally, the radar cross section was measured to evaluate the radar absorbing performances of the fabricated RAS by the compact range facility in POSTECH.

• Journal of the Korean Ceramic Society
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• v.40 no.12
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• pp.1183-1188
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• 2003

LCP (Liquid Crystal Polymer)/BT(BaTiO$_3$) composite was prepared by mixing LCP varnish and BT slurry. And the effect of the composition of LCP/BT composites and the size of BT powder on dielectric properties of LCP/BT composite were investigated. The dispersion properties of BT slurries were also studied as a function of volume fraction of dispersant, GLYMO (3-glycidyloxypropyltrimethoxysilane) added to various sized BT powders. The quantity of optimum dispersant in BT slurry decreased with an increase of BT powder size because of the decrease of specific surface area of BT powder. LCP/BT composite sheet was prepared by tape-casting method with mixing BT slurry and LCP varnish. The dielectric constant of the composites increased from 34.3 to 44.1 and their dielectric loss increased from 0.05 to 0.063 as the size of BT powder increased from 100 nm to 500 nm.

• Journal of the Korea Concrete Institute
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• v.16 no.6 s.84
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• pp.867-873
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• 2004

It has been known that debonding failures between CFS(Carbon Fiber Sheet) and concrete in the strengthened RC beams are initiated by the peeling of the sheets in the region of combined large moment and shear forces, being accompanied by the large shear deformation after flexural cracks. These shear deformation effects are seldom occurred in small-scale model tests, but debondings due to the large shear deformation effects are often observed in a full-scale model tests. The premature debonding failure of CFS, therefore, must be avoided to confirm the design strength of full-scale RC beam in strengthening designs. The reinforcing details, so- called 'U-Shape fiber wrap at mid-span' which wrapped the RC flexural members around the webs and tension face at critical section with CFS additionally, were proposed in this study to prevent the debonding of CFS. Other reinforcing detail, so called 'U-Shape fiber wrap at beam end' were included in this tests and comparisons were made between them.