• Title/Summary/Keyword: polymer loading

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Melt Rheology and Property of Short Aramid Fiber Reinforced Polyethylene Composites (아라미드단섬유강화 폴리에틸렌복합재료의 용융특성 및 물성)

  • Choi, Chi Hoon;Ok, Young Sook;Kim, Byung Kyu;Ha, Chang Sik;Cho, Wong Jei;Shin, Young Jo
    • Applied Chemistry for Engineering
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    • v.3 no.1
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    • pp.81-87
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    • 1992
  • Polyethylenes were reinforced with short aramid fibers on an open roll. Fiber orientation and the anisotropy of physical property were studied using scanning electron microscopy and tensile tester, together with the melt properties from an RDS rheometer. It was found that fiber orientation was obtained in roll operation, and the anisotropy of property became greater with the increase of fiber loading. Melt viscosity measurements indicated that the viscosity increases with fiber loading, with the effect much more pronounced at low loading and low frequency.

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Tension Creep Model of Recycled PET Polymer Concrete with Flexural Loading (휨 하중을 받는 재생 PET 폴리머 콘크리트의 인장크리프 모델)

  • Chae, Young-Suk;Tae, Ghi-Ho
    • Journal of the Korean Society of Safety
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    • v.27 no.5
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    • pp.117-125
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    • 2012
  • In recent years, polymer concrete based on polyester resin have been widely generalized and the research of polymer concrete have been actively pursued by the technical innovations. Polymer concrete is a composite consisting of aggregates and an organic resin binder that hardens by polymerization. Polymer concrete are stronger by a factor of three or more in compression, a factor of four to six in tension and flexural and a factor of two in impact when compared with portland cement concrete. In view of the growing use of polymer concrete, it is important to study the physical characteristics of the material, emphasizing the short term properties as well as long term mechanical behavior. If polymer concrete is to be used in flexural load-bearing application such as in beam, it is imperative to understand the deformation of the material under sustained loading conditions. This study is proposed to empirical and mechanical model of polymer concrete tension creep using long-term experimental results and mathematical development. The test results showed that proposed model has been used successfully to predict creep deformations at a stress level that was 20 percent of the ultimate strength and viscoelastic behavior of recycled-PET polymer concrete is linear of stress level up to 30 percent. It is expected that the present model allows more realistic evaluation of varying stresses in polymer concrete structures with a constant loading.

Axial impact behavior of confined concrete filled square steel tubes using fiber reinforced polymer

  • Zhang, Yitian;Shan, Bo;Kang, Thomas H.K.;Xiao, Yan
    • Steel and Composite Structures
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    • v.38 no.2
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    • pp.165-176
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    • 2021
  • Existing research on confined concrete filled steel tubular (CCFT) columns has been mainly focused on static or cyclic loading. In this paper, square section CCFT and CFT columns were tested under both static and impact loading, using a 10,000 kN capacity compression test machine and a drop weight testing equipment. Research parameters included bonded and unbonded fiber reinforced polymer (FRP) wraps, with carbon, basalt and glass FRPs (or CFRP, BFRP, and GFRP), respectively. Time history curves for impact force and steel strain observed are discussed in detail. Experimental results show that the failure modes of specimens under impact testing were characterized by local buckling of the steel tube and cracking at the corners, for both CCFT and CFT columns, similar to those under static loading. For both static and impact loading, the FRP wraps could improve the behavior and increase the loading capacity. To analyze the dynamic behavior of the composite columns, a finite element, FE, model was established in LS-DYNA. A simplified method that is compared favorably with test results is also proposed to predict the impact load capacity of square CCFT columns.

A Study on the Controlled Release of Naproxen from Hydrophilic Polymer Matrix (친수성고분자 매트릭스의 Naproxen 제어방출에 관한 연구)

  • 김종국;조은실
    • YAKHAK HOEJI
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    • v.31 no.1
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    • pp.25-32
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    • 1987
  • The effect of loading dose, plasticiser and PVA molecular weight on naproxen release from hydrophilic polymer matrix was examined. Hydrophilic polymer matrix was prepared with PVA and PVP by adding glycerine as plasticiser. The release of naproxen from polymer matrix was determined in phosphate buffer medium. The release rate of naproxen from the polymer matrix increased as drug loading dose and plasticiser percentage increased. Raproxen released from the polymer matrix showed the time square root kinetics. Without changing the release-pattern, the release rate of naproxen could not be changed by varying molecular weight of PVA. Linearly released time range increased as drug loading dose increased, whereas decreased as plasticiser percentage increased up to 30%.

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Clonazepam Release from Poly(DL-lactide-co-glycolide) Nanoparticles Prepared by Dialysis Method

  • Nah, Jae-Woon;Paek, Yun-Woong;Jeong, Young-Il;Kim, Dong-Woon;Cho, Chong-Su;Kim, Sung-Ho;Kim, Myung-Yul
    • Archives of Pharmacal Research
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    • v.21 no.4
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    • pp.418-422
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    • 1998
  • Aim of this work is to prepare poly(DL-lactide-co-glycolide) (PLGA) nanoparticles by dialysis method without surfactant and to investigate drug loading capacity and drug release. The size of PLGA nanoparticles was 269.9 $\pm$118.7 nm in intensity average and the morphology of PLGA nanoparticies was spherical shape from the observation of SEM and TEM. In the effect of drug loading contents on the particle size distribution, PLGA nanoparticles were monomodal pattern with narrow size distribution in the empty and lower drug loading nanoparticles whereas bi- or trimodal pattern was showed in the higher drug loading ones. Release of clonazepam from PLGA nanoparticles with higher drug loading contents was slower than that with lower loading contents.

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Sensing and Interfacial Evaluation of Ni Nanowire Strands/Polymer Composites using Electro-micromechanical Technique (Electro-Micromechanical 시험법을 이용한 Ni Nanowire Strands 강화 고분자 복합재료의 Sensing과 계면 물성 평가)

  • Kim, Sung-Ju;Jung, Jin-Gyu;Park, Joung-Man
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.141-144
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    • 2005
  • Sensing and interfacial evaluation of Ni nanowire strands/polymer composites were investigated using Electro-micromechanical technique. Electro-micromechanical techniques can be used as sensing method for micro damage, loading, temperature of interfacial properties. Using Ni nanowire strands/silicone composites with different content, load sensing response of electrical contact resistivity was investigated under tensile and compression condition. The mechanical properties of Ni nanowire strands with different type/epoxy composites were measured using uniformed cyclic loading and tensile test. Ni nanowire strands/epoxy composites showed humidity and temperature sensing within limited ranges, 20 vol% reinforcement. Some new information on temperature and humidity sensing plus loading sensing of Ni nanowire strands/polymer composites could be obtained from the electrical resistance measurement as a new concept of the nondestructive interfacial evaluation.

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Viscosity of polymer melts reduced jointly by filler addition and LCP fibrillation

  • He, Jiasong
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.132-132
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    • 2006
  • Filler loading (fiber or particulate) usually increases the melt viscosity of polymers. In contrast, the addition of these fillers and fibrillation of thermotropic liquid crystalline polymer (LCP) jointly decreased the viscosity of polymer melts to lower than those of pure component polymers, filler-loaded or LCP-blended ones; and even decreased the viscosity with increasing filler loading. Termed as rheological hybrid effect, this phenomenon correlated well with the LCP fibrillation in these ternary systems. Research taking fillers of various shapes and sizes showed that the filler addition promoted the LCP fibrillation, depending upon thermodynamic and dynamic factors involved.

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Performance Evaluation of Platinum Dispersed Self-humidifying Polymer Electrolyte Membrane Prepared by Using RF Magnetron Sputter

  • Kwak, Sang-Hee;Yang, Tae-Hyun;Kim, Chang-Soo;Yoon, Ki-Hyun
    • Journal of the Korean Ceramic Society
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    • v.40 no.2
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    • pp.118-122
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    • 2003
  • The performance evaluation on Pt loading in the self-humidifying polymer electrolyte membrane for Polymer Electrolyte Mem-Brane Fuel Cell(PEMFC) was investigated by using single cell test and measurement of membrane resistance. The self-humidifying membrane comprised two membranes made of perfluorosulfonylfluroride copolymer resin and fine Pt particles tying between them, coated by sputtering. From the results of performance characteristics of self-humidifying membrane cell with different Pt loading, a single cell using self-humidifying membrane with 0.15 mg/$\textrm{cm}^2$ Pt loading showed better performance than that with the others over entire current density. Also, a single cell with 0.15 mg/$\textrm{cm}^2$ Pt loading had a lower resistance value than the other cells under externally nonhumidifying condition. It is indicated that the water produced in the membrane cell with 0.15 mg/$\textrm{cm}^2$ Pt loading showed a higher provision to maintain ionic conductivity of the membrane than the other cells. The optimum amount of Pt particles embedded in the membrane for self-humidifying PEMFC was determined to be about 0.15 mg/$\textrm{cm}^2$.

Effect of Carbon-based Nanofillers on the Toughening Behavior of Epoxy Resin

  • Lee, Gi-Bbeum;Kim, Haeran;Shin, Wonjae;Jeon, Jinseok;Park, In-Seok;Nah, Changwoon
    • Elastomers and Composites
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    • v.56 no.3
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    • pp.179-186
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    • 2021
  • Carbon-based nanofillers, including nanodiamond (ND) and carbon nanotubes (CNTs), have been employed in epoxy matrixes for improving the toughness, using the tow prepreg method, of epoxy compounds for high pressure tanks. The reinforcing performance was compared with those of commercially available toughening fillers, including carboxyl-terminated butadiene acrylonitrile (CTBN) and block copolymers, such as poly(methyl methacrylate)-b-poly(butyl acrylate)-b-poly(methyl methacrylate) (BA-b-MMA). CTNB improved the mechanical performance at a relatively high filler loading of ~5 phr. Nanosized BA-b-MMA showed improved performance at a lower filler loading of ~2 phr. However, the mechanical properties deteriorated at a higher loading of ~5 phr because of the formation of larger aggregates. ND showed no significant improvement in mechanical properties because of aggregate formation. In contrast, surface-treated ND with epoxidized hydroxyl-terminated polybutadiene considerably improved the mechanical properties, notably the impact strength, because of more uniform dispersion of particles in the epoxy matrix. CNTs noticeably improved the flexural strength and impact strength at a filler loading of 0.5 phr. However, the improvements were lost with further addition of fillers because of CNT aggregation.

Behavior of Polymer-Impregnated Concrete Beams (폴리머 침투콘크리트 보의 거동)

  • 변근주;이상민;유동우;이용진
    • Proceedings of the Korea Concrete Institute Conference
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    • 1992.04a
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    • pp.67-73
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    • 1992
  • Polymer-Impregnated Concrete(PIC) is a new polymer-concrete composite material which consist of basic cement concrete and polymer. The mechanical properties and behavior of PIC depend on the type of polymers and the impregnation techniques. In general, the polymer impregnation can improve the strength, durability and ductility of normal concrete. The objective of this study is to develop the analytical procedure for analyzing the structural responces of polymer-impregnated concrete beams with different polymer loading by using finite element method on the basis of experimental results.

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