• Journal of Adhesion and Interface
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• v.5 no.3
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• pp.10-17
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• 2004

We investigated the effect of stabilization processing parameters on the thermal shrinkage, thermal stability and microstructure of rayon fabrics stabilized under various conditions such as heating rate, stabilization temperature, atmosphere gas, and chemical treatment. The presence and absence of phosphoric acid treatment and the heating rate have most importantly influenced the thermal shrinkage and the weight change of rayon fabrics. Especially, the phosphoric acid treatment decreases the reduction of thickness, length, and weight of the fabrics by about 80%, 20%, and 26%, respectively, in comparison with the untreated counterparts, showing the protective effectiveness of the thermal shrinkage involved. The thermal stability of stabilized rayon fabrics is also affected by all the processing conditions used: stabilization temperature, phosphoric acid treatment, atmosphere gas, and heating rate. In addition, the surface and diameter of the stabilized fiber significantly depend on the treatment of phosphoric acid prior to stabilization process.

• Journal of Adhesion and Interface
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• v.3 no.3
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• pp.15-21
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• 2002

The modified polyethylene(m-PE) films were prepared from aqueous dispersions which were synthesized by reacting poly(ethylene-co-methylacrylate) with aqueous KOH and ammonia solution to attach -COOK, $CONH_2$, and COOH as pendent groups in the polyethylene backbones. Thermal, tensile and heat-seal properties were measured to investigate the effect of the pendent groups. Endothermic peaks on DSC curves were affected by the thermal history of the samples and a melting peak was observed at around $86^{\circ}C$ on the second heating curve while three melting peaks were shown on the first heating curve. A minimum value of tensile strength was shown at 70 mole% of COOK based on pendent groups. Tensile modulus increased with increasing the amide content in pendent groups. The m-PE films were heat-sealed at lower temperature than LDPE films and showed a minimum heat seal strength at around 70 mole% COOK content in pendent groups.

• Journal of Adhesion and Interface
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• v.3 no.3
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• pp.7-14
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• 2002

Modified polyethylenes with polar side groups of -COOK, $-CONH_2$, and -COOH were prepared at a dispersion state in water by reacting poly(ethylene-co-methylacrylate) (PEMA) with aqueous solution of KOH and ammonia. Types and their contents of side groups were investigated by infrared spectroscopy, elemental analysis and atomic absorption analysis. Solution viscosity and surface tension were also measured as a function of solid contents. Stability and transparency of the dispersions were greatly affected by the content of COOK in the side groups. The stable dispersion could be prepared at a composition of COOK of 20 mole% at least. The transparency was increased with increasing the COOK contents, but decreased with increasing the amide content at a constant composition of COOK. Solution viscosities increased abruptly at a lower solid content when the COOK contents were increased, implying higher entanglement between the chains in dispersions with higher content of hydrophilic COOK group. The dispersions of higher COOK content revealed lower surface tension values.

• Journal of Adhesion and Interface
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• v.16 no.1
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• pp.22-28
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• 2015

In this study, Waterborne polyurethanes (WPU) using Epoxy group were synthesized with polyester polyol, epoxy resin, 4,4-dicyclohexylmethane diisocyanate ($H_{12}MDI$), dimethylol propionic acid (DMPA) to improve the hydrolysis resistance and adhesion. In addition, the properties of the synthesized waterborne polyurethane was evaluated through DSC, UTM, adhesion strength. Tg of the synthesized waterborne polyurethane is shown in the vicinity of $-50^{\circ}C$. Tg were increased with as epoxy resin contents increased. The tensile strength was increased as the content of epoxy resin increases, elongation was decreased. Optimum adhesion and hydrolysis-resistance strength were obtained when polyol : epoxy ratio was 99 : 1.

• Journal of Adhesion and Interface
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• v.16 no.2
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• pp.76-82
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• 2015

W/O emulsions were prepared from the aqueous solution containing NIPAAm, MBA, and APS in the continuous phase of toluene and mineral oil mixture with HMP and Span80 by using SPG membrane emulsification, and followed by the formation of PNIPAAm hydrogel microspheres through UV photopolymerization. As the ratio of mineral oil to toluene increased in the continuous phase, both particle size of the hydrogel increased and density of PNIPAAm polymer in the hydrogel particle increased, and which significantly affected swelling/deswelling ratio ($V/V_o$) with temperature change around VPTT. When the polymerization temperature was below LCST ($20^{\circ}C$), PNIPAAm hydrogel showed filled particle morphology; however, it was turned out to hollow particle morphology with thick shell layer with $40^{\circ}C$. Both density of PNIPAAm and gel content of the hydrogel increased with the increase in MBA concentration.

• Journal of Adhesion and Interface
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• v.14 no.2
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• pp.95-100
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• 2013

In this study, a series of hot-melt pressure sensitive adhesives (HMPSAs) based on metallocene polyolefin (me-PO) were prepared to investigate their possibility of replacing the HMPSAs based on styrenic block copolymers (SBCs). In addition, to optimize the performance of HMPSAs based on me-PO, several tackifiers having different softening point and molecular weight were evaluated. To achieve the HMPSAs which can satisfy the Dahlquist Criterion, hot melts required over 10% of process oil. To obtain the HMPSAs having low viscosity which can be applied by a spraying type applicator, secondary polymer having relatively low crystallinity was required. And, tackifier having high molecular weight attributed to increasing the cohesive strength of me-PO based HMPSAs.

• Journal of Adhesion and Interface
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• v.14 no.1
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• pp.21-27
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• 2013

Cellulose-based rayon fibers or fabrics can be thermally decomposed very fast within a narrow temperature window during stabilization process. Therefore the stabilization stage is critically important for producing rayon-based carbon fibers. Consequently, in the present study the effects of isothermal stabilization and ultrasonic cleaning on the weight loss, chemical composition, microstructure, and fabric texture of cellulose-based rayon fabrics were explored. The temperature of the isothermal stabilization process performed in the range of $200{\sim}240^{\circ}C$ influenced the processing time, carbon and oxygen contents, cellulose structural change, and fabric texture. The ultrasonic cleaning, which was conducted prior to the stabilization process, played a role in shortening the stabilization time, increasing the carbon contents, decreasing the oxygen contents, and changing the XRD pattern. Also, it was considered that the ultrasonic cleaning contributed to retarding the weight loss, to reducing the thermal shrinkage, and further to reducing the fast physical change of rayon fabrics.

• Journal of Adhesion and Interface
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• v.14 no.1
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• pp.13-20
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• 2013

Palladium plays a pivotal role in the production of dental and medicinal devices, medicinal substances, jewellery, automobile and high-performance adhesives. Despite the frequent and fruitful use of such reactions, one major setback is the high level of palladium in the resultant compounds which can harm the human body. Among the palladium species, $PdCl_2$ is the most toxic. As a consequence it is desirable to detect the $Pd^{2+}$ cations by fluorescence spectra because it can provide an operationally simple and cost-effective detection method together with high sensitivity and selectivity. Herein, an ${\alpha}$-carbonyl substituted pyrene derivative, ${\gamma}$-oxo-1-pyrenebutyric acid (OPBA), was demonstrated to be a highly sensitive and selective fluorescent probe for $Pd^{2+}$ among the metal cations examined in aqueous solutions.

• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.3
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• pp.99-108
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• 2012

In this paper, to intend anticorrosive effect and weight reduction of conventional reinforced concrete slab, lightweight concrete slab reinforced with glass fiber reinforced polymer(GFRP) bar was considered and some basic behaviour of the slab were investigated. Measurement of splitting tensile strength and fracture energy of the concrete, a number of flexural experiment of the slab, numerical analysis using nonlinear finite element analysis, and comparison of the experimental results to the numerical analysis, were conducted. As a result, even the weight of the lightweight concrete slab could be reduced by about 28% than the normal concrete slab, failure load of the lightweight concrete slab was 36% smaller than the normal concrete slab. Such a thing can be attributed to the lower axial stiffness and lower bond strength of GFRP bar. In the numerical analysis, to consider decreasing property of bond strength of the lightweight concrete, interface element was used between the concrete and the GFRP bar elements and this method was shown to be a better way for the numerical analysis to approach the experimental results.

• Journal of Adhesion and Interface
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• v.5 no.2
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• pp.14-26
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• 2004

For reliable determination of mechanical characteristics of adhesively bonded joints used e.g. as input data for computer-aided design of complex components, the thick-adherend tensile-shear test according to ISO 11003-2 is the most important material testing method. Although the total displacement of the joint is measured across the polymer layer directly in the overlap zone in order to minimize the influence of the stepped adherends, the substrate deformation must be taken into account within the framework of the evaluation of the shear modulus and the maximum shear strain, at least when high-strength adhesives are applied. In the standard ISO 11003-2 version of 1993, it was prescribed to perform the substrate deformation correction by means of testing a one-piece reference specimen. The authors, however, pointed to the excessive demands on the measuring accuracy of the extensometers connected with this technique in industrial practice and alternatively proposed a numerical deformation analysis of a dummy specimen. This idea of a mathematical correction was included in the revised ISO 11003-2 version of 2001 but in the simplified form of an analytical method based on Hooke's law of elasticity for small strains. In the present work, it is shown that both calculation techniques yield considerably discordant results. As experimental assessment would require high-precision distance determination (e.g. laser extensometer), finite element analyses of the deformation behavior of the bonded joint are performed in order to estimate the accuracy of the obtained substrate deformation corrections. These simulations reveal that the numerical correction technique based on the finite element deformation modeling of the reference specimen leads to considerably more realistic results.