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http://dx.doi.org/10.17702/jai.2013.14.1.013

Highly Sensitive and Selective Fluorescent Chemosensors Specific for Pd2+ Detection  

Wang, Jing (School of Chemistry and Chemical Engineering, Guangxi University)
Ha, Chang-Sik (Department of Polymer Science and Engineering, Pusan National University)
Publication Information
Journal of Adhesion and Interface / v.14, no.1, 2013 , pp. 13-20 More about this Journal
Abstract
Palladium plays a pivotal role in the production of dental and medicinal devices, medicinal substances, jewellery, automobile and high-performance adhesives. Despite the frequent and fruitful use of such reactions, one major setback is the high level of palladium in the resultant compounds which can harm the human body. Among the palladium species, $PdCl_2$ is the most toxic. As a consequence it is desirable to detect the $Pd^{2+}$ cations by fluorescence spectra because it can provide an operationally simple and cost-effective detection method together with high sensitivity and selectivity. Herein, an ${\alpha}$-carbonyl substituted pyrene derivative, ${\gamma}$-oxo-1-pyrenebutyric acid (OPBA), was demonstrated to be a highly sensitive and selective fluorescent probe for $Pd^{2+}$ among the metal cations examined in aqueous solutions.
Keywords
$Pd^{2+}$ cations; ${\gamma}$-oxo-1-pyrenebutyric acid (OPBA); chemosensor;
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