• Title/Summary/Keyword: polymer fibers

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Microfluidic Fabrication of Conjugated Polymer Sensor Fibers (미세유동을 이용한 공액 고분자 센서 섬유 제작)

  • Yoo, Imsung;Song, Simon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.10
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    • pp.853-858
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    • 2014
  • We propose a fabrication method for polydiacetylene (PDA)-embedded hydrogel microfibers on a microfluidic chip. These fibers can be applied to the detection of cyclodextrines (CDs), which are a family of sugar and aluminum ions. PDA, a family of conjugated polymers, has unique characteristics when used for a sensor, because it undergoes a blue-to-red color transition and nonfluorescence-to-fluorescence transition in response to environmental stimulation. PDAs have different sensing characteristics depending on the head group of PCDA. By taking advantage of ionic crosslinking-induced hydrogel formation and the 3D hydrodynamic focusing effect on a microfluidic chip, PCDA-EDEA-derived diacetylene (DA) monomer-embedded microfibers were successfully fabricated. UV irradiation of the fibers afforded blue-colored PDA, and the resulting blue PDA fibers underwent a phase transition to red and emitted red fluorescence upon exposure to CDs and aluminum ions. Their fluorescence intensity varied depending on the CDs and aluminum ion concentrations. This phase transition was also observed when the fibers were dried.

Interfacial Evaluation of Single Ramie and Kenaf Fibers/Epoxy Composites Using Micromechanical Technique (Micromechanical 시험법을 이용한 Kenaf 및 Ramie 섬유 강화 에폭시 복합재료의 계면물성 평가)

  • Park, Joung-Man;Tran, Quang Son;Jung, Jin-Gyu;Kim, Sung-Ju;Hwang, Byung-Sun
    • Journal of Adhesion and Interface
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    • v.6 no.2
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    • pp.13-20
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    • 2005
  • Interfacial shear strength (IFSS) of environmentally friendly natural fiber reinforced polymer composites plays a very important role in controlling the overall mechanical performance. The IFSS of various Ramie and Kenaf fibers/epoxy composites was evaluated using the combination of micromechanical test and nondestructive acoustic emission (AE) to find out optimal conditions for desirable final performance. Dynamic contact angle was measured for Ramie and Kenaf fibers and correlated the wettability properties with interfacial adhesion. Mechanical properties of Ramie and Kenaf fibers were investigated using single-fiber tensile test and analyzed statistically by both uni-and bimodal Weibull distributions. An influence of clamping effect on a real elongation for both Ramie and Kenaf fibers were evaluated as well. Two different microfailure modes, axial debonding and fibril fracture coming from fiber bundles and single fiber composites (SFC) were observed under tension and compression.

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Flexural properties, interlaminar shear strength and morphology of phenolic matrix composites reinforced with xGnP-coated carbon fibers

  • Park, Jong Kyoo;Lee, Jae Yeol;Drzal, Lawrence T.;Cho, Donghwan
    • Carbon letters
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    • v.17 no.1
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    • pp.33-38
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    • 2016
  • In the present study, exfoliated graphite nanoplatelets (xGnP) with different particle sizes were coated onto polyacrylonitrile-based carbon fibers by a direct coating method. The flexural properties, interlaminar shear strength, and the morphology of the xGnP-coated carbon fiber/phenolic matrix composites were investigated in terms of their longitudinal flexural strength and modulus, interlaminar shear strength, and by optical and scanning electron microscopic observations. The results were compared with a phenolic matrix composite counterpart prepared without xGnP. The flexural properties and interlaminar shear strength of the xGnP-coated carbon fiber/phenolic matrix composites were found to be higher than those of the uncoated composite. The flexural and interlaminar shear strengths were affected by the particle size of the xGnP, while the particle size had no significant effect on the flexural modulus. It seems that the interfacial contacts between the xGnP-coated carbon fibers and the phenolic matrix play a role in enhancing the flexural strength as well as the interlaminar shear strength of the composites.

COMPUTATIONAL ANALYSIS ON THE COOLING PERFORMANCE OF GLASS FIBER COOLING UNIT WITH HELIUM GAS INJECTION (헬륨가스 주입식 유리섬유 냉각장치의 냉각성능 해석)

  • Oh, I.S.;Kim, D.;Umarov, A.;Kwak, H.S.;Kim, K.
    • Journal of computational fluids engineering
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    • v.16 no.4
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    • pp.110-115
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    • 2011
  • A modern optical fiber manufacturing process requires the sufficient cooling of glass fibers freshly drawn from the heated and softened silica preform in the furnace, since the inadequately cooled glass fibers are known to cause improper polymer resin coating on the fiber surface and to adversely affect the product quality of optical fibers. In order to greatly enhance the fiber cooling effectiveness at increasingly high fiber drawing speed, it is necessary to use a dedicated glass fiber cooling unit with helium gas injection between glass fiber drawing and coating processes. The present numerical study features a series of three-dimensional flow and heat transfer computations on the cooling gas and the fast moving glass fiber to analyze the cooling performance of glass fiber cooling unit, in which the helium is supplied through the discretely located rectangular injection holes. The air entrainment into the cooling unit at the fiber inlet is also included in the computational model and it is found to be critical in determining the helium purity in the cooling gas and the cooling effectiveness on glass fiber. The effects of fiber drawing speed and helium injection rate on the helium purity decrease by air entrainment and the glass fiber cooling are also investigated and discussed.

Screening of Agricultural and Food Processing Waste Materials as New Sources for Biodegradable Food Packaging Application

  • Wang, Long-Feng;Reddy, Jeevan Prasad;Rhim, Jong-Whan
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.20 no.1
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    • pp.7-15
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    • 2014
  • Agar-based composite films were prepared with variety of food processing and agricultural processing waste materials in order to screen natural lingo-cellulosic resources for the value-added utilization of the under-utilized materials. The effect of these waste materials (10 wt% based on agar) on mechanical properties, moisture content (MC), water vapor permeability (WVP), water absorption behavior of biocomposite films were investigated. Biocomposite films prepared with various fibers resulted in significant increase or decrease in color and percent transmittance. The MC, WVP, and surface hydrophobicity of biocomposite films increased significantly by incorporation of fibers, while the water uptake ratio and solubility of the film decreased. SEM images of biocomposite film showed better adhesion between the fiber and agar polymer. Among the tested cellulosic waste materials, rice wine waste, onion and garlic fibers were promising for the value-added utilization as a reinforcing material for the preparation of biocomposite food packaging films.

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Alternatives to Enhance Flat Slab Ductility

  • Husain, Mohamed;Eisa, Ahmed S.;Roshdy, Ramy
    • International Journal of Concrete Structures and Materials
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    • v.11 no.1
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    • pp.161-169
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    • 2017
  • Flat slab systems are vastly used in multi-story buildings because of their savings in story height and construction time, as well as for their flexibility in architectural remodeling. However, they frequently suffer brittle punching-shear failure around columns, especially when subjected to lateral loads. Therefore, seismic codes labeled flat slabs as non-ductile systems. This research goal is investigating some construction alternatives to enhance flat slab ductility and deformability. The alternatives are: adding different types of punching-shear reinforcement, using discreet fibers in concrete mixes, and increasing thickness of slab around columns. The experimental study included preparation and testing of seven half-scale interior slab-column connections up to failure. The first specimen is considered a reference, the second two specimens made of concrete mixes with different volumetric ratios of polymer fibers. Another three specimens reinforced with different types of punching-shear reinforcement, and the last specimen constructed with drop panel of inverted pyramidal shape. It is found that using the inverted pyramid-shape drop panel of specimen, increases the punching-shear capacity, and the initial and the post-cracking stiffnesses. The initial elastic stiffnesses are different for all specimens especially for the slab with closed stirrups where it is experienced the highest initial stiffness compared to the reference slab.

Surface Hydrolysis of Fibrous Poly(${\epsilon}$-caprolactone) Scaffolds for Enhanced Osteoblast Adhesion and Proliferation

  • Park, Jeong-Soo;Kim, Jung-Man;Lee, Sung-Jun;Lee, Se-Geun;Jeong, Young-Keun;Kim, Sung-Eun;Lee, Sang-Cheon
    • Macromolecular Research
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    • v.15 no.5
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    • pp.424-429
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    • 2007
  • A procedure for the surface hydrolysis of an electrospun poly(${\epsilon}$-caprolactone) (PCL) fibrous scaffold was developed to enhance the adhesion and proliferation of osteoblasts. The surface hydrolysis of fibrous scaffolds was performed using NaOH treatment for the formation of carboxyl groups on the fiber surfaces. The hydrolysis process did not induce deformation of the fibers, and the fibers retained their diameter. The cell seeding density on the NaOH-treated PCL fibrous scaffolds was more pronounced than on the non-treated PCL fibers used as a control. The alkaline phosphatase activity, osteocalcin and a mineralization assay strongly supported that the surface-hydrolyzed PCL fibrous scaffolds provided more favorable environments for the proliferation and functions of osteoblasts compared to the non-treated PCL fibrous scaffolds use as a control.

A Review of Carbon-Reinforced Carbon Nanotube Fibers Composites (탄소강화 탄소나노튜브 섬유 복합소재 연구 동향)

  • Lee, Dongju;Ryu, Seongwoo;Ku, Bon-Cheol
    • Composites Research
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    • v.32 no.3
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    • pp.127-133
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    • 2019
  • Although carbon nanotubes(CNTs) have outstanding theoretical mechanical and electrical properties, CNT fibers(CNTFs) have not yet reached that level. Particularly, tensile strength is only about 10% or less, so studies for making up for it are being actively conducted. As a way for improving mechanical strength, methods such as synthesizing long CNT, orientation, chemical cross-linking, hydrogen bonding and polymer infiltration are being studied. In this review paper, we report preparation methods for highly conductive and strong CNTF/Carbon composites through coating and infiltration followed by carbonization of carbon precursor polymers such as polyacrylonitrile (PAN) and polydopamine (PDA) on CNTFs.

Preparation of Antibacterial Nanofibrous PMMA Nonwoven Fabrics (항균성 PMMA 나노섬유 부직포의 제조)

  • Kim, Chang-Nam;Xing, Zhi-Cai;Baek, Jin-Young;Bae, Hyun-Su;Kang, Inn-Kyu
    • Polymer(Korea)
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    • v.33 no.5
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    • pp.429-434
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    • 2009
  • In this study, electro spinning conditions for PMMA were studied. Namely, the ratio of DMF and THF and its maximum concentration were examined. Conductivity of the polymer solution containing silver nanoparticles and its effect on fiber diameter were also studied. As the results, the maximum concentration for the electro spinning of PMMA was found at 18 wt%, and the ratio of DMF/THF was 7:3. The diameter of nanofibers obtained was 100-400 nm when the PMMA solution containing 1000 ppm silver was electrospun. It was found, from TEM results, that silver nanoparticles were distributed on the edge of fibers and the resulting nanofiber mats showed a good antibacterial activity.

Study on Peel Strength Measurement of 3D Printing Composite Fabric by Using FDM (FDM 방식을 활용한 3D 프린팅 복합직물의 박리강력 측정 연구)

  • Han, Yoojung;Kim, Jongjun
    • Journal of Fashion Business
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    • v.23 no.2
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    • pp.77-88
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    • 2019
  • One way of appling 3D printing to garments is through the combination of 3D polymer filaments in textile fabrics. it is essential to understand the interface between the polymer and the 3D composite fabric in order to enhance the adhesion strength between the polymers and the peeling strength between the fabric and the polymer. In this study, the adhesion of composite printed specimens using a combination of fabric and polymers for 3D printing was investigated, and also the change in adhesion was investigated after the composite fabric printed with polymers was subjected to constant pressure. Through this process, the aims to help develop and utilize 3D printing textures by providing basic data to enhance durability of 3D printing composite fabrics. The measure of the peeling strength of the composite fabric prepared by printing on a fabric using PLA, TPU, Nylon polymer was obtained as follows; TPU polymer for 3D printing showed significantly higher peel strength than polymers of composite fabric using PLA and Nylon polymer. In the case of TPU polymer, the adhesive was crosslinked because of the reaction between polyurethane and water on the surface of the fabric, thus increasing the adhesion. It could be observed that the adhesion between the polymer and the fiber is determined more by the mechanical effect rather than by its chemical composition. To achieve efficient bonding of the fibers, it is possible to modify the fiber surface mechanically and chemically, and consider the deposition process in terms of temperature, pressure and build density.