• Carbon letters
• /
• 제15권4호
• /
• pp.282-289
• /
• 2014

Blends of poly(vinyl alcohol) (PVA), polyethyleneimine (PEI), and graphene oxide (GO) were prepared by solution casting method. Calorimetric thermal properties of the blends were investigated. The $T_gs$ of PVA/PEI blends were higher than the $T_gs$ of either of the component polymers at low concentrations of PEI. These abnormal increases of $T_gs$ may be due to the negative entropy of mixing which is associated with strong hydrogen bonding between PVA and PEI. The degree of depression of $T^0_ms$ was not reduced by the negative entropy of mixing, since strong hydrogen bonding also causes an increase in the magnitude of negative ${\chi}$ between PVA and PEI. The $T_g$ of PVA was increased significantly by adding 0.7 wt.% GO into PVA. The magnitude of negative ${\chi}$ was increased by adding GO into the blends of PVA and PEI.

• 한국세라믹학회지
• /
• 제38권7호
• /
• pp.654-659
• /
• 2001

고령토 슬러리의 분산특성에 미치는 양이온성 polyethyleneimine 결합제의 영향을 고찰하였다. 분산제인 Sodium Hexametaphosphate (SHP)를 0.8 wt% 첨가한 경우와 첨가하지 않은 두 가지 슬러리 내에서 polyethyleneimine (PEI)의 첨가량에 따른 슬러리의 응집, 분산거동을 점도 및 제타전위 측정을 통해 평가하였다. 슬러리 내에 SHP 유무에 상관없이 PEI 농도가 0.02 wt%일 경우에는 응집, 0.6 wt%에서는 분산, 0.6 wt% 이상에서는 재응집되는 것으로 각각 나타났다. 슬러리가 응집-분산-재응집과정을 거치는 동안 점토입자의 제타전위는 항상 일정한 값을 유지하였다. 또한 입자표면의 PEI의 흡착량은 SHP를 첨가한 슬러리의 경우가 크게 나타났으며, 분산성은 상대적으로 더 향상됨을 알 수 있었다.

• 대한화학회지
• /
• 제25권6호
• /
• pp.394-398
• /
• 1981

두 가지의 팔면체형 Ni(II)-polyethyleneimine (PEI) 착물, [Ni(PEI)]$Cl_2$ 및 [Ni(PEI)$Cl_2$]를 합성하여 과산화수소 분해반응에서 이들 착물의 촉매활성도를 조사하고, 유사한 구조를 한 ethylenediamine 착물, $[Ni(en)_3]Cl_2$ 및 $[Ni(en)_2Cl_2$의 촉매활성도와 비교해 본 결과, 다음과 같은 순서로 촉매 활성도가 증가함이 관찰되었다 : $0{\approx}[Ni(en)_3]Cl_2{\le}[Ni(en)_2Cl_2]<[Ni(PEI)]Cl_2<[Ni(PEI)Cl_2]$ 가시선 및 적외선 흡수 스펙트럼을 측정하여 두 가지 Ni(II)-PEI 착물의 구조를 조사하여 본 결과 이들 착물의 촉매활성도는 배위자와 Ni(II)이온사이의 결합세기에 의존함을 알 수 있었다.

• 한국염색가공학회지
• /
• 제33권1호
• /
• pp.1-9
• /
• 2021

This study aims to prepare the fabric with detoxification properties against chemical warfare agent by the simple treatment. For this purpose, polypropylene non-woven fabric(PP) was treated with polyethyleneimine(PEI) and guanidinylated PEI and detoxification properties of the guanidinylated PEI treated PP were evaluated using diisopropylfluorophosphate(DFP), as a chemical warfare agent simulant, and compared with the untreated and PEI treated PP. The half-lives of DFP on guanidinylated PEI treated PP and untreated PP were 334 min and 714 min, respectively. The half-life of DFP with guanidinylated PEI treated PP was 53.22% shorter than with untreated PP. This result shows that guanidine group in guanidinylated PEI treated PP was acted as a base catalyst for hydrolysis of DFP and decreased half-life of DFP. Therefore, it is expected that guanidinylated PEI treatment can be an simple pathway to prepare the detoxification fabric material for protective clothing against chemical warfare agents.

• 멤브레인
• /
• 제25권5호
• /
• pp.391-397
• /
• 2015

다공성 지지체인 Polyvinylidene fluoride (PVDF) 중공사막에 염석법을 기반으로 하여 Polyethyleneimine (PEI)와 Polyvinylsulfonic acid (PVSA)를 가압법(phase separated and pressurization, PSP)으로 코팅시켜 다층막을 제조하였다. 이에 열처리 온도, 코팅농도, 유입수 농도, 가교시간 및 가교제 농도에 대하여 NaCl 100 ppm을 공급액으로 하여 4 atm에서 투과도와 제거율을 알아보고자 하였다. 가장 좋은 결과로는 PEI 20,000 ppm과 PVSA 1,000 ppm, PEI 15%에 말산 2% 수용액으로 가압코팅 후 열처리하였을 때 투과도 24.3 LMH, 제거율 82.1%의 결과를 얻을 수 있었다.

• Elastomers and Composites
• /
• 제45권1호
• /
• pp.7-11
• /
• 2010

본 논문에서는 polyethyleneimine (PEI)를 커플링제로 사용하여 간단한 공정을 통하여 아세틸렌 블랙/실리카 복합체 입자를 제조하였다. 복합체 입자는 PEI를 아세틸렌 블랙 표면에 흡착시키고 졸-겔 합성공정을 통하여 실리카를 아세틸렌 블랙 위에서 합성하는 두단계 공정을 통하여 제조되었다. 복합체 입자의 모폴로지 분석 결과 실리카가 아세틸렌 블랙위에 존재하는 core-shell 구조를 확인하였으며, 표면에 상당한 미세기공이 존재함을 알 수 있었다.

• 한국의류학회지
• /
• 제37권4호
• /
• pp.590-597
• /
• 2013

This study examined the change in the dyeability of natural dyes on cotton fabrics by a PEI (polyethyleneimine) pretreatment instead of mordants. Cotton fabrics were treated with PEI and the changes in the dyeability were shown by measuring the amount of PEI on cotton fabrics. Samples treated with PEI were dyed with two natural polychromatic dyes with a different affinity to cotton fibers: Alizarin Red S and Curcumin. The changes in dyeability by three variables (time, temperature and concentration of dyes) on cotton fabrics were analyzed by the K/S value to define optimum dyeing conditions. Subsequently, the PEI treatment improved the dyeability of cotton fabrics with both dyes of low and high affinity to cotton fibers. Thus, PEI could be a suitable heavy metal mordant replacement.

• Bulletin of the Korean Chemical Society
• /
• 제33권8호
• /
• pp.2567-2573
• /
• 2012

We successfully synthesized $Fe_3O_4@SiO_2$ nanoparticles with ultrathin silica layer of $1.0{\pm}0.5$ nm that polyethyleneimine (PEI) with low molecular weight of 2.0-4.0 kDa was covalently conjugated with the resulting $Fe_3O_4@SiO_2$ nanoparticles by silane coupling reaction. The PEI-$Fe_3O_4@SiO_2$ nanoparticles were further used as gene delivery vector for a human fibroblast cell (IMR-90) line. Gene transfection efficiency of the PEI-$Fe_3O_4@SiO_2$ complexes did not increase remarkably after magnetofection; however, the addition of Lipofectamine 2000 significantly increased the transfection efficiency of the PEI-$Fe_3O_4@SiO_2$ complexes. We believe that the present approach could be utilized for magnetofection as alternative to $Fe_3O_4$ nanoparticles conjugated with the PEI of high molecular weight thanks to its relatively low cytotoxicity and high transfection efficiency.

• Biotechnology and Bioprocess Engineering:BBE
• /
• 제10권3호
• /
• pp.205-211
• /
• 2005

Water-soluble polyethyleneimine (PE) derivatives containing nucleic acid bases and hydrophilic amino acids such as homoserine (Hse) and serine were prepared by the activated ester method as nucleic acid models. From spectroscopic measurements, the polymers were found to interact with DNA accompanied by an induction of conformational change. Hypochromicity in UV spectra indicated that a stable polymer complex was formed between poly (A) with PEI­Hse-Ura by complementary hydrogen bonding with equimolar nucleic base units (adenine:uracil=1:1). The induced conformation of DNA by the interaction with the polymer containing uracil and homoserine (PEI-Hse-Ura) was concluded to be a super triple helical structure. The formation of the polymer complex, DNA: PEI-Hse-Ura, was found to be affected by the presence of metal ions such as $Ca^{2+}\;and\;Cu^{2+}$.

• 대한환경공학회지
• /
• 제37권3호
• /
• pp.175-181
• /
• 2015

이산화탄소 포집을 위한 기능성 흡착제인 폴리에틸렌이민(PEI)을 함침한 활성탄을 평가하였다. 이산화탄소 흡착제의 흡착 특성은 GC/TCD, BET 표면적 및 FT-IR을 사용하였다. 활성탄에 PEI를 10, 30, 50 wt%를 함침하여 흡착제를 합성하고, 온도변화에 따른 이산화탄소의 흡착능을 조사하였다. $20^{\circ}C$와 $100^{\circ}C$에서의 이산화탄소 흡착능은 다음과 같다: $20^{\circ}C$에서는 AC > PEI(10)-AC > PEI(30)-AC > PEI(50)-AC의 순으로 나타났으며, $100^{\circ}C$에서는 PEI(10)-AC > PEI(30)-AC > PEI(50)-AC > AC 순으로 나타났다. 아민 기능기의 활성탄의 흡착능이 순수 활성탄보다 아미노기에 의하여 화학 흡착 때문에 높은 온도에서 높게 나타났다. 본 연구의 결과로 PEI(10) 활성탄은 고온의 가스로부터 이산화탄소 포집에 가장 유능한 흡착제 중 하나로 보여진다.