• 제목/요약/키워드: polyethylene glycol (PEG)

검색결과 438건 처리시간 0.023초

비이온 폴리올을 이용한 Garment 코팅용 수분산 폴리우레탄의 합성 및 물성에 관한 연구 (A Study on the Synthesis and Properties of Water-Dispersion Polyurethane for Garment Coating Using Nonionic Polyol)

  • 이주엽
    • 한국응용과학기술학회지
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    • 제34권1호
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    • pp.83-90
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    • 2017
  • Garment skin leather 표면 코팅에 사용된 폴리우레탄 수지는 polyethylene glycole(PEG)의 함유를 [NCO]/[OH] mole % 비로 달리하면서 합성하였으며, 합성된 폴리우레탄 수지의 기계적 특성은 SEM, FT-IR, UTM 등을 이용하여 측정하였다. 비이온성을 띄고 있는 PEG(poly ethylene glycol)의 [NCO]/[OH] mole % 비가 증가함에 따라 내굴곡성(건식, 습식)의 변화는 없었으며, 내마모도, 인장강도수치가 낮아짐을 알 수 있었다. 반대로 연신율 물성은 증가함을 알 수 있었다. 점도 변화 측정 결과에는 PEG의 [NCO]/[OH] mole % 증가에 따라 점도가 묽어짐을 알 수 있었다.

High-Temperature Drying of Bamboo Tubes Pretreated with Polyethylen Glycol Solution

  • Kang, Chun-Won;Chung, Woo-Yang;Han, Jae-Ok;Kang, Ho-Yang
    • Journal of the Korean Wood Science and Technology
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    • 제45권2호
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    • pp.139-146
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    • 2017
  • This study was conducted to develop a new drying technology in order to quickly and massively dry bamboo tubes without crack and check. The bamboo tubes with the diameter of 45 mm - 68 mm had been impregnated in the solution of PEG-1000, and then were dried under room temperature and high temperature, respectively. The cracks occurred on all control specimens while no cracks were found on PEG treated specimens during drying at room temperature due to effect of PEG restraining the circumferential shrinkage of bamboo tube. But the drying period of this method was too long (200 days) compared to 10 hours of kiln drying. During fast high temperature drying, cracks occurred on all control specimens, but no cracks were found on PEG treated specimens, which could be accounted for more solidified PEG due to higher drying temperature and faster drying rate, and the tension set formed on the surface of bamboo tube in the early stage of drying owning to high drying temperature and low relative humidity. Thus, it is advised that PEG treated bamboo tube should be fast dried at high temperature in order to not only prevent crack or check in short drying period but also increase the dimensional stability of the products made of bamboo tubes.

전기방사법으로 제조한 PU/PEG 복합 지지체의 특성 (Characteristics of PU/PEG Hybrid Scaffolds Prepared by Electrospinning)

  • 설보경;신지연;오가연;이득용;이명현
    • 대한의용생체공학회:의공학회지
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    • 제38권5호
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    • pp.248-255
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    • 2017
  • Polyurethane/polyethylene glycol(PU/PEG) hybrid scaffolds with various concentrations of PEG (0 to 50wt%) were prepared by electrospinning to evaluate the mechanical properties and the biocompatibility of the PU/PEG blend scaffolds. The 12wt% PU/PEG polymers were studied due to the absence of beads. The ultimate tensile strength of 12wt% PU was $8.2{\pm}0.5MPa$. The strength increased to $9.2{\pm}0.7MPa$ when 10% PEG was added to PU. However, the dry and the wet strength of PU/PEG scaffolds began to decrease dramatically when the PEG content was more than 10wt%. No cytotoxicity was observed for all the PU/PEG scaffolds investigated, indicating that the PU/PEG hybrid scaffolds are clinically safe and effective to small-diameter vascular grafts. In addition, the L-929 cells attached and proliferated well on the PU/PEG hybrid scaffolds.

새로운 생체적합성 폴리펩티드공중합체의 합성과 혈액적합성에 관한 연구 : 측쇄에 에틸렌글리콜을 함유하는 폴리펩티드 공중합체의 혈액적합성 (Synthesis and Blood Compatibility of New Biocompatible Copolypeptides : Blood Compatibility of Copolypeptide Having Ethylene Glycol Oligomers Substituted in the Side Chain)

  • 강인규;박상동;조종수;성용길
    • 대한화학회지
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    • 제36권6호
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    • pp.947-954
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    • 1992
  • Poly (γ-benzyl L-glutamate) (PBLG)와 말단에 아미노기를 갖는 Polyethylene glycol (PEG)의 치환반응을 행하여 PEG-grafted PBLG (PEG-g-PBLG)를 합성하였다. 또한 PEG-g-PBLG 필름표면에 ethanolamine(EA)을 치환반응하여 표면에 히드록시그룹을 갖는 PEG-g-PBLG-EA 필름을 얻었다. 폴리펩티드중합체와 혈액성분과의 상호작용에 관한 실험결과, PEG-g-PBLG 상에서의 혈소판의 점착율 및 형태변화는 PEG-g-PBLG-EA보다 적게 나타났고, PEG-g-PBLG상에서의 혈장 단백질의 응고시간은 PEG-g-PBLG-EA 또는 PBLG의 응고시간보다 길게 나타났다. 이들 결과는 혈액응고시간 및 혈액응고량을 조사한 실험결과와 일치하였다. 따라서 폴리펩티드상의 히드록시그룹은 혈액성분과의 상호작용을 강하게 하여 혈액적합성이 저하하는 반면, PEG-g-PBLG는 비교적 좋은 혈액적합성을 나타냄을 알 수 있었다.

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Effect of Dihydroxybenzoic Acid Isomers on the Analysis of Polyethylene Glycols in MALDI-MS

  • Lee, Ae-Ra;Yang, Hyo-Jik;Kim, Yang-Sun;Kim, Jeong-Kwon
    • Bulletin of the Korean Chemical Society
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    • 제30권5호
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    • pp.1127-1130
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    • 2009
  • The effects of different dihydroxybenzoic acid (DHB) isomers, when used as matrix materials in matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS), were investigated in analyses of polyethylene glycol (PEG) polymers. PEG polymers ranging from 400 to 8,000 Da were prepared in different DHB isomer matrices using solvent-based and solvent-free methods. PEG samples were detected only in matrices of 2,3-DHB, 2,5-DHB, and 2,6-DHB while the most intense peaks were observed using 2,6-DHB in both solvent-free and solvent-based preparations.

Recovery of serine protease inhibitor from fish roes by polyethylene glycol precipitation

  • Lee, Hyun Ji;Kim, Hyung Jun;Park, Sung Hwan;Yoon, In Seong;Lee, Gyoon-Woo;Kim, Yong Jung;Kim, Jin-Soo;Heu, Min Soo
    • Fisheries and Aquatic Sciences
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    • 제19권5호
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    • pp.25.1-25.8
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    • 2016
  • The fractionation of serine protease inhibitor (SPI) from fish roe extracts was carried out using polyethylene glycol-4000 (PEG4000) precipitation. The protease inhibitory activity of extracts and PEG fractions from Alaska pollock (AP), bastard halibut (BH), skipjack tuna (ST), and yellowfin tuna (YT) roes were determined against target proteases. All of the roe extracts showed inhibitory activity toward bromelain (BR), chymotrypsin (CH), trypsin (TR), papain-EDTA (PED), and alcalase (AL) as target proteases. PEG fractions, which have positive inhibitory activity and high recovery (%), were the PEG1 fraction (0-5 %, w/v) against cysteine proteases (BR and PA) and the PEG4 fraction (20-40 %, w/v) against serine proteases (CH and TR). The strongest specific inhibitory activity toward CH and TR of PEG4 fractions was AP (9278 and 1170 U/mg) followed by ST (6687 and 2064 U/mg), YT (3951 and 1536 U/mg), and BH (538 and 98 U/mg). The inhibitory activity of serine protease in extracts and PEG fractions from fish roe was stronger than that of cysteine protease toward common casein substrate. Therefore, SPI is mainly distributed in fish roe and PEG fractionation effectively isolated the SPI from fish roes.

Agrobacterium tumefaciens Spheroplast의 연초엽육 Protoplast내 도입에 관한 세포학적 연구 (Cytological Study of the Introduction of Agrobacterium tumefaciens Spheroplasts into Nicotiana tabacum Protoplasts)

  • 김정희;구용범;이기영
    • Journal of Yeungnam Medical Science
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    • 제2권1호
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    • pp.175-181
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    • 1985
  • Polyethylene glycol(PEG) 처리에 의한 Agrobacterium tumefaciens spheroplast와 연초 엽육 protoplast의 상호작용을 연구하기 위하여, 효소적 방법으로 분리한 연초엽육 protoplast와 carbenicillin 및 lysozyme의 처리에 의해 제조된 Agrobacterium tumefaciens ATCC 15955 spheroplast를 섞어서 polyethylene glycol (PEG) 및 high pH-high $Ca^{2+}$ buffer를 처리한 후 시료를 취하여 전자현미경으로 관찰한 결과, spheroplast는 초기 단계에서 protoplast membrane에 부착하고, 시간이 경과함에 따라 endocytosis에 의해 protoplast의 세포질 내부로 도입된 다음, 점차로 그 형체(cell integrity)가 파괴되어지는 것을 관찰할 수 있었다. 이러한 관찰 결과로부터 spheroplast는 polyethylene glycol(PEG)에 의해 protoplast내부로 endocytosis되어짐을 알 수 있었다.

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알루미나-지르코니아 복합체의 제조공정 및 미세구조에 미치는 폴리머 첨가의 영향 (Effect of Polymer Content on Synthesis Process and Microstructure of Alumina-Zirconia Composite)

  • 이상진;권명도;이충효;조경식
    • 한국분말재료학회지
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    • 제10권5호
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    • pp.310-317
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    • 2003
  • Two-component ceramic (alumina-zirconia) composites were fabricated by a soft-solution process in which polyethylene glycol (PEG) was used as a polymeric carrier. Metal salts and PEG were dissolved in ethyl alcohol without any precipitation in 1:1 volume ratio of alumina and zirconia. In the non-aqueous system, the flammable solvent made explosive, exothermic reaction during drying process. The reaction resulted in formation of volume expanded, porous precursor powders by a vigorous decomposition of organic components in the precursor sol. The PEG content affected the grain size of sintered composites as well as the morphology of precursor powders. The difference of microstructure in sintered composite was attribute to the solubility and homogeneity of metal cations in precursor sol. At the optimum amount of the PEG polymer, the metal ions were dispersed effectively in solution and a homogeneous polymeric network was formed. It made less agglomerated particles in the precursor sol and affected on uniform grain size in sintered composite.

생체적합성과 생분해성을 갖는 Polypeptide Copolymer의 합성과 물성에 관한 연구(II) (Synthesis and Physical Properties of Biocompatible and Biodegradable Polypeptide Copolymers(II))

  • 강인규;권대룡
    • 대한의용생체공학회:의공학회지
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    • 제10권3호
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    • pp.237-242
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    • 1989
  • The physical properties and drug release behaviours of polyethylene glycol grafted poly ${\gamma}$- benzyl L-glutamate (PEG- g- PBLG), polyethylene glycol crosslinked poly ${\gamma}$-benzyl L- glutamate(PEG-c-PBLG), and PBLG homopolymer are compared. PBLG containing PEG segements showed higher wettability and larger enlongation than PBLG homoplymer, but lower elastic modulus. The release rate of rhodamine is strongly influenced by the wettability of the polymer. Rhodamine is more rapidly released from PEG-c-PBLG membrane having a larger water contact angle than from other polymer having a lower water contact angle. The surfaces of PBLG derivative membranes are modified by substitution reaction using hydroxyalkylamine. The resulting polymer membranes showed hider wettability and swelling ratio than virgin membranes.

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메쉬 침지여과분리형 회분식 생물반응조를 이용한 PEG제거의 기초 연구 (Fundamental Study on the Removal Properties of Polyethylene Glycols by Mesh Filtration Batch Bio-reactor)

  • 정용준
    • 한국물환경학회지
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    • 제25권4호
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    • pp.502-506
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    • 2009
  • The removal properties of Polyethylene glycols (PEGs) known as the important group of synthetic polymers of ethylene oxide were examined by the bio-reactor equipped with a mesh filter module. PEG-1000 and PEG-2000 were fairly removed on the basis of TOC, which were 75.1% and 51.6%, respectively. In the case of PEG-20000, the removal efficiency of TOC was less than 15.2% and the favorable acclimation of microbes was not obtained. It was suggested that this system could effectively maintain microbes for the biodegradation of low molecular weight of PEG and TOC removal was significantly influenced by PEG molecular weight.