• 폴리머
• /
• 제25권2호
• /
• pp.160-167
• /
• 2001

특성이 서로 다른 polyimide (PI) 전구체와 polyamideimide (PAI) 블렌드물을 solvent casting법으로 제조한 후 열처리하여 다양한 조성의 PI/PAI 복합체를 제조하였다. Poly(amic acid) (PAA)를 전구체로 사용한 PAA/PAI 복합체의 경우 산-염기에 의한 ionic force 또는 수소 결합에 의한 분자간력으로 인하여 좋은 혼화성을 나타냈지만, poly(amic dimethyl ester) (PAME)를 전구체로 사용한 PAME/PAI 복합체는 약화된 분자간력으로 인하여 상분리가 뚜렷하게 발생함을 편광 현미경을 통해 관찰하였다. 전구체의 종류에 관계없이 이미드화된 복합체의 인장 탄성 계수는 선형치보나 증가하였으나 PAI 매트릭스 영역에서의 인장강도 및 전 혼합 조성에서의 파단 변형률은 감소하였다 상대적으로 낮은 유리 전이 온도를 가진 PAI에 의한 가소화 때문에 열적 이미드화 과정 중에 PI 분자쇄의 재정렬이 촉진됨을 편광현미경 및 X-선 회절 결과로부터 확인하였다.

• Transactions on Electrical and Electronic Materials
• /
• 제16권3호
• /
• pp.146-150
• /
• 2015

Insulation breakdown voltage and insulation lifetime were investigated in straight lines or twisted pairs with polyesterimide-polyamideimide enameled round wires (EI/AIW ). The enamel thickness was 50 μm and the conducting copper radius was 0.50, 0.75, 1.09, and 1.50 mm, respectively. There were many air gaps in a twisted pair therefore, when voltage was applied to the twisted pair, enamel erosion took place in the air gap area because of partial discharge according to Paschen's law. Insulation breakdown voltage and insulation lifetime were highest in the sample of 0.75 mm conductor radius, which was higher than those values for 0.50 mm or 1.09 and 1.55 mm.

• Transactions on Electrical and Electronic Materials
• /
• 제17권4호
• /
• pp.231-234
• /
• 2016

The AC insulation breakdown voltage was investigated for seven types of winding coils made of polyamideimide (PAI), flexural PAI (nanosilica 5 wt%) and anti-corona PAI (nanosilica 15 wt%) wires with various winding coil diameters of φ5, φ15 and φ25 mm. The winding coil was made of enameled wire with an enamel thickness of 30~50 μm, and the rectangular copper wire had a thickness of 0.77~ to 0.83 mm and width of 1.17~ to 1.23 mm, respectively. The insulation breakdown voltages of the original PAI coils with diameters of φ5, φ15 and φ25 mm were 7.30, 6.58, and 5.95 kV, respectively, and those values decreased as the winding coil diameter increased, regardless of the wire types.

• 폴리머
• /
• 제26권5호
• /
• pp.599-606
• /
• 2002

본 연구에서는 DDS로 경화된 4관능성 에폭시 (TGDDM)/폴리아마이드이미드 (PAI) 블렌드의 PAI 함량에 따른 블렌드계의 열적, 기계적 및 형태학적 특성에 대해 연구하였다 경화된 시편의 경화거동과 열안정성은 DSC와 TGA로 각각 조사하였다. 또한 $K_{IC}$ 는 UTM을 사용하여 측정하였으며, TGDDM/PAI 블렌드의 상거동과 최종 모폴로지는 SEM을 사용하여 관찰하였다. 그 결과 PAI 함량이 증가할수록 경화온도와 경화활성화 에너지는 감소하였다 경화온도와 경화활성화 에너지의 감소는 PAI 주쇄의 2차 아민이 co-initiator로서 사용되었기 때문인 것으로 사료된다. 그러나 분해활성화 에너지와 $K_{IC}$ 값은 각각 PAI 함량 5, 10 phr까지 증가하다 그 이상치 한량에서는 감소하는 경향을 보였다. 이러한 결과들은 에테르화에 의한 사슬절단 반응에 기초하여 설명되었다. 그리고 SEM에 의한 모폴로지 관찰로부터 블렌드계의 co-continuous 구조가 확인되었다.

• Transactions on Electrical and Electronic Materials
• /
• 제17권5호
• /
• pp.297-301
• /
• 2016

The effects of ambient temperature and diameter on the insulation lifetime of winding coils prepared with polyamideimide (PAI), flexural PAI (nanosilica 5 wt%) and anti-corona PAI (nanosilica 15 wt%) wires were investigated. The winding coils were made of enameled wire with enamel thickness of 30~50 μm. The thickness and width of the rectangular copper wires were 0.77~0.83 mm and 1.17~1.23 mm, respectively. The insulation breakdown lifetime decreased with increasing ambient temperature regardless of wire type and winding coil diameter under an inverter surge of 1.5 kV/20 kHz. The insulation breakdown lifetimes of φ5 mm winding coils at 150, 200, and 250℃ were 11.38, 5.19, and 4.22 min respectively, and those of φ10 mm winding coils at 150, 200, and 250℃ were 11.32, 5.79, and 4.57min respectively. The winding coil diameter had little effect on the insulation lifetime.

• 전기학회논문지
• /
• 제65권10호
• /
• pp.1721-1726
• /
• 2016

4-types of coils were prepared by coating with polyamideimide (PAI) organic/inorganic hybrid. One type was made with original PAI vanish and the other 3-types were made of double layers, that was to say, high flexural PAI layer and high anti-corona PAI/nanosilica (15 wt%) layer. Drying temperature (T/D) were $220^{\circ}C$, $240^{\circ}C$, and $260^{\circ}C$, respectively and rectangular type coil for high-voltage rotating machine was used. DC and AC electrical breakdown tests were carried out in order to study the insulation properties according to T/D temperature and coil curvature (5, 15, and $25mm{\Phi}$). As the curvature increased, electrical breakdown voltage decreased and as T/D temperature decreased, electrical breakdown voltage increased.

• 한국전기전자재료학회논문지
• /
• 제29권10호
• /
• pp.641-646
• /
• 2016

Coil specimen was prepared by coating a copper wire with two varnish thin layers: the first was polyamideimide (PAI)/nanosilica (5 wt%) varnish and the second was anti-corona PAI/nanosilica (15 wt%) varnish. Insulation breakdown voltage was investigated under inverter surge condition at $20^{\circ}C$, $70^{\circ}C$, $100^{\circ}C$, $150^{\circ}C$, $200^{\circ}C$, $250^{\circ}C$, respectively. The insulation lifetime of the two layered coil was tens of times longer than that of original PAI coil. And the insulation lifetime decreased with increasing ambient temperature because there was weak binding strength between copper and varnish layer.

• 한국전기전자재료학회논문지
• /
• 제29권12호
• /
• pp.829-834
• /
• 2016

Coil specimens were prepared by continuous coating on a copper wire with flexible PAI (polyamideimide) and PAI/nanosilica (5 wt%) varnish and thermally aged at 150, 200 and $250^{\circ}C$ for 5, 10 and 15 days, respectively. AC insulation breakdown voltage was investigated under inverter surge condition at 60 Hz and 1,000 Hz and insulation breakdown voltage decreased with increasing aging temperature and aging time at each 60 and 1,000 Hz.

• Investigative Magnetic Resonance Imaging
• /
• 제13권2호
• /
• pp.171-176
• /
• 2009

목적 : 자기공명영상 장비에서 신호를 주고 받는 주요 부분인 RF 코일의 성능 특성인 Q 값 (quality factor)과 신호대잡음비 (SNR, signal-to-noise ratio) 값에 미치는 코일 구리선 코팅 재질의 영향을 조사하고자 하였다. 대상 및 방법 : 폴리에스테르 (polyester), 폴리우레탄 (polyurethane), 폴리이미드 (polyimide), 폴리아마이드이미드 (polyamideimide), 폴리에스테르이미드 (polyester-imide)가 코팅된 직경 0.4 mm 구리선을 사용하여, 내경이 1.7mm인 RF 코일을 솔레노이드 형태로 제작한 후 network analyzer로 Q 값을 측정하였다. 또한 제작된 RF 코일을 600 MHz MRI (14.1 T, Bruker DMX600) 장비를 이용하여 표준시료를 이용한 자기공명영상 실험을 수행하였으며, 5개의 다른 코팅 재질과 코팅이 없는 경우에 대하여 영상에서의 신호대잡음비를 비교하였다. 결과 : 코팅 피복을 벗겨내고 측정한 신호대잡음비는 오차 범위에서 유사하였으며, 코팅되어 있는 경우에는 그 재질에 따라 Q 값 및 신호대잡음비가 다르고, 폴리에스테르의 경우를 제외하면 코팅 피복이 없는 경우와 비교하여 큰 값을 보였다. 폴리우레탄 코팅 구리선을 사용하였을 때 Q 값 및 신호대잡음비가 가장 크게 나타났으며, 가장 작은 값을 보인 폴리에스테르 코팅재질인 경우와 비교할 때 신호대잡음비가 34% 정도 큰 값을 보였다. 결론 : 1.2 mm 이하의 작은 생체시료에 적합한 솔레노이드형 RF 코일을 상용 프로브에 장착하여 사용할 수 있도록 손쉽게 제작하였으며, 폴리우레탄으로 코팅된 구리선으로 만들어진 코일의 경우 신호대잡음비가 30% 이상으로 가장 우수한 결과를 보였고, 따라서 코팅 재질의 선택이 자기공명영상의 결과에 중요하게 작용함을 확인할 수 있었다.

• Transactions on Electrical and Electronic Materials
• /
• 제17권3호
• /
• pp.163-167
• /
• 2016

Inverter surge resistant enameled wire was prepared with an organic/inorganic hybrid nanocomposite, and the effect of ambient temperature on the insulation lifetime of the enameled wire in the form of twisted pair was studied by a withstanding voltage tester. The organic polymer was Polyesterimide-polyamideimide (EI/AI) and the inorganic material was a Nano-sized silica (average particle size : 15 nm). The enamel thickness was 50 μm and the ambient temperature was 100, 150, 200, and 250, respectively. Transmission electron microscopy (TEM) observation showed that Nano-sized Silica were evenly dispersed in EI/AI. There were many air gaps in a twisted pair, therefore, when voltage was applied to the twisted pair, enamel erosion took place in the air gap area because of partial discharge accordi, ng to Paschen’s law. As ambient temperature increased, insulation lifetime decreased according to Arrhenius relationship, which was explained by the increasing mobility of polymer chains in EI or AI. And insulation breakdown voltage value at 10 kHz was 1,864.5 sec (31.1 min), which is 1.9 times higher than at 20 kHz, 981.6 sec (16.4 min).