• Title/Summary/Keyword: poly-urethane

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Growth Characteristics of Spinaches by Nursery Media and the Seeding Number Per Plug Tray Cell in Hydroponics (시금치의 육묘배지와 파종 종자량에 따른 수경재배 생육 특성)

  • Seo, Jong-Bun;Jung, Jong-Mo;Kim, Sun-Kook;Choi, Kyong-Ju;Kim, Joung-Geun;Hong, Sae-Jin
    • Journal of Bio-Environment Control
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    • v.16 no.1
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    • pp.62-66
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    • 2007
  • This study was carried out to develop the stable plug seedling production for hydroponics of spinaches by various nursery media, plug tray size and seed number per plug tray cell. When plant grown in various nursery media, the seeding stand rate was shown in order of granular rockwool with good water retention, granular rockwool>granular rockwool mixed with pearlite>cocopeat>pearlite>poly urethane foame. Thus, poly urethane foame indicated the lower seedling stand rate. There was no difference in growth of the seedlings md the seeding stand rate by the plug tray size, and no significant difference in the plant height and the number of leaves among the seed number per plug tray cell. But, leaf area of plant in 2 grains seeding per cell was $113.0cm^2$, was wider in compared with 5 grains seeding of which leaf area was $88.0cm^2$. Accordingly, the leaf area per plant decreased as more and more the number of seeds per plug tray cell increased. The fresh weight of a plant per plug tray cell was the heaviest with 12.5g in the 2 grains, and the total fresh weight of plants per cell was 33.9g in 4 grains seeding, thus it tended to was bigger compared with other treatments. Consequently, given that the number of seeds per cell was decreased, the fresh weight of a plant increased. On the other hand, the total fresh weight per cell showed a tendency to be reducing as more and more the number of seeds per plug tray cell decreased. The yield in the 4 grains seeding was increased by 46% as $14,910kg{\cdot}ha^{-1}$ in compared with the yield in 2 grains seeding as $10,200kg{\cdot}ha^{-1}$.

Moment Resistance Performance Evaluation of Larch Glulam Joint Bonded in Glass Fiber Reinforced Plastic Rods (봉형 GFRP를 삽입접착한 낙엽송 집성재 접합부의 모멘트저항 성능 평가)

  • Lee, In-Hwan;Song, Yo-Jin;Jung, Hong-Ju;Hong, Soon-Il
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.1
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    • pp.60-67
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    • 2015
  • In order to evaluate the bond performance of domestic larch glulam and the glass fiber reinforced plastic (GFRP) rod, the specimen with the GFRP rod bonded-in domestic larch glulam for pull-out test was produced. The test was carried out using various specimens with different gluing depth, width of glue-line and type of adhesive. The cantilever type rahmen structure specimen with bonded-in GFRP rods was produced based on the result of pull-out test, and its moment resistance performance was compared and examined with the moment resistance performance of slotted-in steel plate specimen. As a result of the pull-out test, the most excellent bond performance was found when the insertion depth of GFRP rods was 5 times larger than the diameter of GFRP rods. When the glue-line thickness was 1 mm, the bond performance improved by 17%~29% in comparison to the bond performance in the case of the glue-line thickness of 2 mm. Also, the bonded strength of the specimen used with poly-urethane adhesive was 2.9~4.0 times greater than the bonded strength of specimen used with resorcinol adhesive. The cantilever type rahmen structure specimen with bonded-in GFRP rods showed the moment resistance performance 0.82 times lower in comparison to the slotted-in steel plate specimen used with the drift pin, but the initial stiffness was similar as 0.93 times.

Silica/polymer Nanocomposite Containing High Silica Nanoparticle Content : Change in Proton Conduction and Water Swelling with Surface Property of Silica Nanoparticles (고농도의 Silica Nanoparticle을 함유한 Silica/polymer 나노복합체 : 실리카 표면 특성에 따른 수소이온 전도성 및 수팽윤도 변화)

  • Kim, Ju-Young;Kim, Seung-Jin;Na, Jae-Sik
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.514-521
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    • 2010
  • A new one-shot process was employed to fabricate proton exchange membranes (PEMs) over conventional solvent-casting process. Here, PEMs containing nano-dispersed silica nanoparticles were fabricated using one-shot process similar to the bulk-molding compounds (BMC). Different components such as reactive dispersant, urethane acrylate nonionmer (UAN), styrene, styrene sulfuric acid and silica nano particles were dissolved in a single solvent dimethyl sulfoxide (DMSO) followed by copolymerization within a mold in the presence of radical initiator. We have successfully studied the water-swelling and proton conductivity of obtained nanocomposite membranes which are strongly depended on the surface property of dispersed silica nano particles. In case of dispersion of hydrophilic silica nanoparticles, the nanocomposite membranes exhibited an increase in water-swelling and a decrease in methanol permeability with almost unchanged proton conductivity compared to neat polymeric membrane. The reverse observations were achieved for hydrophobic silica nanoparticles. Hence, hydrophilic and hydrophobic silica nanoparticles were effectively dispersed in hydrophilic and hydrophobic medium respectively. Hydrophobic silica nanoparticles dispersed in hydrophobic domains of PEMs largely suppressed swelling of hydrophilic domains by absorbing water without interrupting proton conduction occurred in hydrophilic membrane. Consequently, proton conductivity and water-swelling could be freely controlled by simply dispersing silica nanopartilces within the membrane.

Effect of Coupling Agent, Methylene Diisocyanate, in the Blending of Poly(methyl methacrylate)-Modified Starch and Styrene-Butadiene Rubber (폴리(메틸 메타크릴레이트)-개질된 전분과 스티렌-부타디엔 고무의 혼합에서 커플링제 메틸렌 디이소시아네이트의 효과)

  • Li, Mei-Chun;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.49 no.2
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    • pp.117-126
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    • 2014
  • Methylene diisocyanate (MDI) was investigated as a novel interfacial modifier to enhance the performances of poly(methyl methacrylate)-modified starch/styrene-butadiene rubber (PMMA-modified starch/SBR) composites. Owing to the formation urethane linkage on one side and ${\pi}-{\pi}$ adhesion on the other side, MDI acted as an intermediated linkage role in the PMMA-modified starch/SBR interfaces, which was evidenced by the morphological, mechanical, dynamic mechanical and thermal decomposition studies. As a result, the presence of MDI significantly improved the mechanical properties and thermal stability of PMMA-modified starch/SBR composites. In addition, the effect of starch concentration on the various performances of the resulted MDI/PMMA-modified starch/SBR composites, such as morphology, vulcanization characteristics, mechanical properties, toluene swelling behavior, and thermal stability were investigated and discussed in detail. The obtained MDI/PMMA-modified starch/SBR composites exhibited superior mechanical properties to carbon black/SBR (CB/SBR) composites, demonstrating the potential use of the renewable starch as a substitute for CB in the rubber compounds.

Synthesis of Aminosilane treated Waterborne Poly Urethane/Epoxy Hybrid Resin used for Loudspeaker Damper (스피커 댐퍼용 아미노실란 처리 수분산 폴리우레탄/에폭시 하이브리드 수지의 합성)

  • Choi, Hyun-Seuk;Choi, Dong-Ho;Park, Ju-Yong;Huh, Man-Woo
    • Textile Coloration and Finishing
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    • v.29 no.1
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    • pp.25-36
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    • 2017
  • This study worked on the synthesis of waterborne polyurethane/epoxy hybrid resins containing aminosilane compound to replace conventional phenol resins used for a coating material for loudspeaker dampers, which are not harmful to human being. Waterborne polyurethane resins were synthesized from two diisocyanate of 4,4'-diphenylethane diisocyanate and toluene diisocyanate, two polyols of polyester polyols(PEP), polycarbonatediol(PCD), including and anionic center of dimethylol butanoic acid, a chain extenders of ethylenediamine(EDA), and a neutral agent of triethylamine. Synthesized polyurethane resins and commercially available bisphenol A type waterborne epoxy resin were blended in weight ratios of 80:20 to prepare polyurethane/epoxy hybrid resins. The synthesized waterborne polyurethane/epoxy hybrid resins were reacted with aminosilane compound to improve mechanical properties. Aminosilane-treated polyurethane /epoxy hybrid resins showed better mechanical properties.

Heavy-weight Impact Noise Reduction of Concrete Slab Reinforcement Using F.R.P (F.R.P 재료 보강에 의한 신개념 중량충격음 저감대책)

  • Jeong, Jeong-Ho;Yoo, Seung-Yup;Lee, Pyoung-Jik;Jeon, Jin-Yong;Jo, A-Hyoung
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.05a
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    • pp.383-386
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    • 2005
  • Low frequency heavy-weight impact noise is the most irritating noise in Korean high-rise reinforced concrete apartment buildings. This low frequency noise is generated by foot traffic due to the fact that Koreans do not wear shoes at home. The transmission of the noise is facilitated by a load bearing wall structural system without beams and columns which is used in these buildings. In order to control low frequency heavy-weight impact noise, floating floors using isolation materials such as glass-wool mat and poly-urethane mat are used. However, it was difficult to control low frequency heavy-weight impact sound using isolation material. In this study, reinforcement of concrete slab using beams and plate was conducted. Using the FEM analysis, the effect of concrete slab reinforcement using FRP(fiber-glass reinforced plastic) on the bang machine impact vibration acceleration level and sound were conducted at the standard floor impact sound test building. The $3{\sim}4dB$ floor impact vibration acceleration level and impact sound pressure level were reduced and the natural frequency of slabs were changed.

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Capillary-driven Rigiflex Lithography for Fabricating High Aspect-Ratio Polymer Nanostructures (모세관 리소그라피를 이용한 고종횡비 나노구조 형성법)

  • Jeong, Hoon-Eui;Lee, Sung-Hoon;Kim, Pil-Nam;Suh, Kahp-Y.
    • Journal of the Korean Society of Visualization
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    • v.5 no.1
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    • pp.3-8
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    • 2007
  • We present simple methods for fabricating high aspect-ratio polymer nanostructures on a solid substrate by rigiflex lithography with tailored capillarity and adhesive force. In the first method, a thin, thermoplastic polymer film was prepared by spin coating on a substrate and the temperature was raised above the polymer's glass transition temperature ($T_g$) while in conformal contact with a poly(urethane acrylate) (PUA) mold having nano-cavities. Consequently, capillarity forces the polymer film to rise into the void space of the mold, resulting in nanostructures with an aspect ratio of ${\sim}4$. In the second method, very high aspect-ratio (>20) nanohairs were fabricated by elongating the pre-formed nanostructures upon removal of the mold with the aid of tailored capillarity and adhesive force at the mold/polymer interface. Finally, these two methods were further used to fabricate micro/nano hierarchical structures by sequential application of the molding process for mimicking nature's functional surfaces such as a lotus leaf and gecko foot hairs.

Performance Test Method on the Influence Waterproofing as Behavior of Concrete Structure (지하 콘크리트 구조물의 거동에 대한 방수층의 대응성 평가에 관한 실험적 연구)

  • Noh Jong-Soo;Kwon Shi-Won;Kwak Kyu-Sung;Kwon Kee-Joo;Oh Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • v.y2004m10
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    • pp.77-81
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    • 2004
  • The massive structures are not free to move with vibration, differential settlement, thermal stresses because, construction and expansion joint, crack etc., can be large enough to cause leakage as deformation of waterproofing. It has been depended on the test method of tensile/tear strength which is waterproofing performance as behavior of concrete structure crack. However, not to practically confirm the creep applied to concrete surface, even waterproofing membrane have more performance than definite strength and elasticity. Therefore, in this study will focus on the test method to consider a resistance performance about loose adhesion and deformation of waterproofing and behavior of concrete structure as construction/expansion joint, crack. Performance test method on the influence as behavior of concrete structure crack is to choose waterproofing materials and construction method which possible to confront with behavior of 50mm crack in the atmosphere and low temperature. Examine the deformation of waterproofing membrane and loose adhesion which can occur to structure in general job site, suggest standard testing method to analyze correlation waterproofing membrane and structure with 5-types of materials used in this study, such as Adhesion membrane and sheet complex, sheet and urethane complex, self-adhesive sheet, spray poly-urea, spray membrane of rubberized Asphalt.

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Analyses of incident ion energy and flux in plasma based surface treatment using a conducting grid (플라즈마 표면 처리시 전도성 그리드를 통한 표면 입사 이온 에너지와 입사량 증대에 관한 분석 및 그 응용)

  • Cho, Yong-Sung;Choi, Won-Young;Park, Hyun-Dong;Choi, Joon-Young;Lee, Hae-June;Lee, Ho-Jun;Park, Chung-Hoo
    • Proceedings of the KIEE Conference
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    • 2005.11a
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    • pp.197-200
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    • 2005
  • As Plasma Immersion ion Implantation (PIII) using a conducting grid is very useful to reduce the effect of capacitance and charging in surface modification. If the bias voltage applied to the conducting grid is in the range of hundreds of volts, the effects of surface charge and space charge substantially affect the incident ion energy and ion current to the surface. In this paper, through an 1d and a 2d PIC simulation the time varying formation of the space charge and surface charge is analyzed. Experiment with the optimally designed grid on the basis of the simulation results is conducted, and the results of both cases with grid and without grid are compared. In our work with Poly Urethane(PU), the improvement of adhesion is yielded by increasing surface roughness and decreasing Si component of PU.

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Establishment of Design Standard and Analysis of Insulation Property for Underground Space in Architecture (건축물의 지하공간을 위한 단열재의 특성 분석 및 설계 기준 수립)

  • Hwang, Min-Kyu;Cho, Woo-Jin;Kim, Kang-Soo
    • KIEAE Journal
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    • v.13 no.2
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    • pp.107-112
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    • 2013
  • The purpose of this study is to analyze an insulation property and to establish a design standard for the underground space in architecture. Insulation materials for this study are 12 kinds of Insulation which qualified KS standards(3 classes of EPS type 1, 3 classes of EPS type 2(Neopor), 3 classes of XPS and 3 classes of PU Boards). For insulation materials of underground space, insulating and water tightening property are desired. So conductivity for insulating and water absorption for water tightening are measured in this study. Temperature, insulation is exposed to in the underground space, is different from temperature above the ground. Conductivity is measured in a temperature of $17^{\circ}C$, $20^{\circ}C$, $23^{\circ}C$ and $26^{\circ}C$. In KS standards, water absorption are measure after 24 hours, but insulation is exposed to water for a long time in the underground. So after 110 days, water absorption are measured. As time goes by, increasing of water absorption means decreasing of water tightening and insulating. So after water absorption had measured for 110 days, conductivity has measured again. As a result, XPS is selected as optimized insulation for underground. And Conductivity of XPS insulation with water should be added by 20%.