• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.1
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• pp.914-920
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• 2015

In this paper, the crystal structure and the crystallinity of PLA(PolyLactic Acid) were studied. PLA is a eco-friendly thermoplastic which completely decomposed by microorganisms, but has low thermal stability and low degree of crystallinity. The low crystallization rate makes the cycle time of injection molding longer and the degree of crystallinity lower. It is a very big disadvantage comparing the other thermoplastics. We improved the degree of crystallinity and the crystallization rate by introducing nucleating agents and plasticizer, and discussed the mechanism.

• Proceedings of the KIEE Conference
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• 2005.07c
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• pp.2052-2054
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• 2005

TFT-LCD requires to use poly silicon for High resolution and High integration. Thin film make of Poly silicon on the excimer laser-induced crystallization of PECVD(plasma-enhanced chemical vapor deposition)-grown amorphous silicon. In the thin film hydrogen affects to a device performance from bad elements like eruption, void and etc. So dehydrogenation prior to laser exposure was necessary. In this study, use RTP(Rapid Thermal Process) at various temperature from $670^{\circ}C$ to $750^{\circ}C$ and fabricate poly-silicon. it propose optimized RTP window to compare grain size to use poly silicon's SEM pictures and crystallization to analyze Raman curved lines.

• Macromolecular Research
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• v.12 no.2
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• pp.172-177
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• 2004

We have studied the lamella-level morphology of poly(ethylene terephthalate) (PET)/polycarbonate (PC) blends using small-angle X-ray scattering (SAXS). Measurements were made as a function of the holding time in the melt. We determined the morphological parameters at the lamellar level by correlation function analysis of the SAXS data. An increased amorphous layer thickness was identified in the blend, indicating that some PC was incorporated into the interlamellar regions of PET during crystallization. The blend also exhibits a larger lamella crystalline thickness (l$\sub$c/) than that of pure PET. A possible reason for the increase in l$\sub$c/ is that the inclusion of the PC molecules in the interlamellar regions causes an increase in the surface free energy of folding. At the early stage of isothermal crystallization, we observed a rapid drop in the value of l$\sub$c/ in the blend; this finding indicates that a relatively large fraction of secondary crystals form during the primary crystallization. In contrast, the value of l$\sub$c/ for the sample that underwent a prolonged holding time increased with time in the secondary crystallization-dominant regime; this observation suggests that the disruption of chain periodicity, which results from transesterification between the two polymers, favors the development of fringed micellar crystals that have larger values of l$\sub$c/ rather than the development of normal chain-folded crystals.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.287.1-287.1
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• 2014

본 연구에서는 현재 디스플레이에서 가장 널리 이용되는 저온 polycrystalline silicon (poly-Si)의 결정화 방법에 따른 thin-film transistor (TFT)의 전기적 특성을 분석하였다. 분석에 이용된 결정화 방식은 Excimer Laser Annealing (ELA)와 Metal Induced Crystallization (MIC)이다. ELA와 MIC TFTs의 전기적 특성 측정을 통한 분석결과 ELA와 MIC poly-Si TFTs의 전기적 특성 [field-effect mobility (${\mu}_{FE}$), on/off current ratio ($I_{ON}/I_{OFF}$), sub-threshold swing (SS)]은 큰 차이는 없지만, ELA를 이용한 poly-Si TFT의 전기적 특성이 조금 우수하다. 하지만, MIC poly-Si TFT의 경우 threshold voltage ($V_{TH}$)가 0V에 보다 가까울 뿐만 아니라, 전기적 스트레스를 통한 신뢰성 확인 시 ELA poly-Si TFT보다 조금 더 안정적이다. 이는 ELA의 경우 좁은 면에 선형 레이저 빔으로 조사하면서 생기는 hill-lock의 영향으로 표면이 거칠고 균일하지 못하여 바이어스 인가시 생기는 문제이다. 또한 MIC는 금속 촉매를 이용해 결정립 경계를 확장하고 결정 크기를 키워 대면적화에 유리하다. Thermal Stress에서는 (from 293K to 373K) TFT에 점차 높은 온도를 가하자 MIC poly-Si TFT의 경우 off 상태에서 누설 전류 값이 증가하며 열에 민감한 반응을 보이는 것을 확인하였다.

• Proceedings of the IEEK Conference
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• 2000.06b
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• pp.274-277
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• 2000

Thin Film Transistor(TFTs) were fabricated from poly-Si crystallized by a two-step annealing process on glass substrates. The combination of low-temperature(500$^{\circ}C$) Metal-Induced Lateral Crystallization(MILC) furnace annealing and high -temperature (700$^{\circ}C$) rapid thermal annealing leads to the improvement of the material quality The TFTs measured with this two-step annealing material exhibit better characteristics than those obtained by using conventional MILC furnace annealing.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.190-190
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• 2003

현재 a-Si TFT는 평판 디스플레이 소자로서 주로 사용되고 있으나 점차 고속응답속도 특성, 고화질이 요구됨에 따라 높은 전계효과 이동도를 가진 poly-Si TFT로 대체하기 위한 연구가 진행되고 있으며 특히 poly-Si TFT를 상용 유리 기판에 적용하기 위해 비정질 실리콘의 저온 결정화에 대한 연구가 활발히 진행 되고 있다. 본 연구에서는 극박막의 Ni을 선택적으로 증착하여 전계 유도방향성 결정화 (Field Aided Lateral Crystallization : FALC) 공정을 이용하여 결정화를 진행하였으며 전계를 인가하지 않은 경우와 전계를 인가한 경우, 전계 세기에 따른 결정화에 대하여 비교하였다.

• Proceedings of the Korean Fiber Society Conference
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• 2001.10a
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• pp.432-435
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• 2001

Polymer/clay nanocomposites have received much attention in recent years, because they often exhibit physical properties that are dramatically different from those observed in their micro- and rnacrocornposite counterparts. The presence of clay may affect the crystallization behavior of semicrystalline polymer. (omitted)

• Journal of the Korean Institute of Telematics and Electronics D
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• v.35D no.5
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• pp.48-53
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• 1998

Poly-Si TFT's could be fabricated on glass substrates by metal induced lateral crystallization (MILC) method at 450.deg. C. Channel area of the poly-Si TFT's was laterally crystallized from source and drain areas, where a thn nickel film was deposited. Dopants activation for the formation of source and drain region could be achieved by thermal annealing at 450.deg. C after the ion mass doping of phosphorus. The field effect mobility of thus formed N-channel poly-Si TFT's was 76cm$^{2}$/Vs, and the on/off current ratio was higher than 7E6.

• Macromolecular Research
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• v.10 no.1
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• pp.44-48
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• 2002

The supermolecular structures of poly(ethylene terephthalate) (PET), poly(ethylene 2,6-naphthalate) (PEN), and their blend were investigated with optical microscopy and small angle light scattering. With increasing the crystallization temperature, incomplete spherulitic texture was developed for the PET samples. At a high crystallization temperature of 220 $^{\circ}C$, the light scattering pattern represented a random collection of uncorrelated lamellae. The general morphological appearances for the PEN samples were similar to that of the PET. A notable feature was that the spherulites of the PEN formed at 200 $^{\circ}C$ showed regular concentric bands arising from a regular twist in the radiating lamellae. The spherulitic morphology of the PET/PEN blend was largely influenced by the changes of the sequence distribution in polymer chains determined by the level of transesterifcation. The increased sequential irregularity in the polymer chains via transesterification caused a morphological transition from a regular folded crystallite to a tilted lamellar crystallite.

• Journal of Information Display
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• v.10 no.2
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• pp.76-79
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• 2009

In Joule-heating-induced crystallization, solid-to-solid or liquid-to-solid phase transformation could occur. It was found that novel physical phenomena that randomly nucleated liquid seeds, followed by rapid solidification in an amorphous matrix, during the Joule-heating-up period play an important role especially in liquid-to-solid transformation. Under some processing conditions, super-grains sized 6-8 ${\um}m$ were produced by the lateral growth from the initial seeds, without any artificially control.