• 제목/요약/키워드: polarization sensitivity

검색결과 106건 처리시간 0.056초

Corrosion Characteristics of Amorphous Alloy Ribbon ($Fe_{70}Cr_5Si_{10}B_{15}$ and $Co_{70}Cr_5Si_{10}B_{15}$) in Hydrochloric Acid Aqueous Solution

  • Choi, Chil-Nam;Hyo, Kyung-Yang;Yang, Myung-Sun
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2001년도 정기총회 및 봄 학술발표회 초록집
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    • pp.236-237
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    • 2001
  • In this study, experiments were carried out to measure the variations in the corrosion potential and current density of polarization curves with amorphous $Fe_{70}Cr_5Si_{10}B_{15}$ and $Co_{70}Cr_5Si_{10}B_{15}$ alloy ribbon. The results were particularly examined to identify the influences of corrosion potential including various conditions such as hydrochloric acid, temperature, salt, pH, and oxygen. The optimum conditions were established with variations including temperature, salt, pH, oxygen, corrosion rate, and resistance of corrosion potential. The mass tranfer coefficient(${\alpha}$) value was determined with the Tafel's slope for the anodic dissolution based on the polarization effect with optimum conditions. The second anodic current density peak and maximum passive current density were designated as the critical corrosion sensitivity($I_{r}/I_{f}$).

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PS-LCI를 이용한 혈당 농도에 따른 Stokes 파라미터 측정 (Measurement of Stokes parameter changes due to blood glucose using PS-LCI)

  • 이상원;김법민
    • 한국광학회:학술대회논문집
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    • 한국광학회 2003년도 하계학술발표회
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    • pp.258-259
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    • 2003
  • 최근 수년간 polarimetry, Raman spectroscopy, near infrared (NIR) absorption spectroscopy, NIR scattering, optoacoustics 등의 방법을 통하여 비침습적으로 Glucose의 농도를 측정하려는 연구가 많이 시도되었다. 일반적으로 이들 방법은 sensitivity 와 signal-to-noise ratio가 매우 낮고 복잡한 알고리즘이 요구되어져 glucose 농도 측정에 한계가 있음이 드러났다. 본 연구에서는 polarization sensitive low coherence interferometer (PS-LCI) 기법을 이용하여 농도에 따른 stokes parameters를 측정함으로써 비침습적으로 glucose를 측정하는 것이 가능한지 알아보는데 그 목적이 있다. (중략)

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끝단이 막힌 중공 원통형 광섬유 하이드로폰의 감도 해석 (Sensitivity Analysis of Fiber Optic Hydrophone for a End-Capped Hollow Cylinder)

  • 이종길;윤형규;서인창
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 1996년도 춘계학술대회논문집; 부산수산대학교, 10 May 1996
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    • pp.286-290
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    • 1996
  • 수중 음향센서로서 최근에 많이 연구되고 있는 광섬유 하이드로폰(fiber optic hydrophone)의 성능을 예측하기 위하여 광섬유의 편광특성(polarization)에 따른 정규화 감도식 (normalized sensitivity)을 유도하였다. 본 연구에서 사용된 하이드로폰은 광섬유가 끝단이 막힌 중공 원통형 맨드럴(mandrel)에 감긴 구조이며 음압이 하이드로폰에 작용할 때 응력 관계식을 이용하여 정규화 감도식을 유도하였으며 유도된 감도식을 맨드럴의 내외경비에 따라 특성을 수치해석하였다. 균일한 재질의 광섬유에서 맨드럴의 내외경비의 값이 클수록 그리고 맨드럴의 탄성계수의 값이 작을수록 감도가 증가함을 관찰 하였다.

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Transverse relaxation-optimized HCN experiment for tautomeric states of histidine sidechains

  • Schmidt, Holger;Himmel, Sebastian;Walter, Korvin F.A.;Klaukien, Volker;Funk, Michael;Lee, Dong-Han
    • 한국자기공명학회논문지
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    • 제12권2호
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    • pp.89-95
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    • 2008
  • Function of protein is frequently related with tautomeric states of histidine sidechains. Thus, several NMR experiments were developed to determine the tautomeric states of histidines. However, poor sensitivity of these experiments caused by long duration of magnetization transfer periods is unavoidable. Here, we alleviate the sensitivity of HCN experiment for determining the tautomeric states of histidine residues using TROSY principle to suppress transverse relaxation of $^{13}C$ spins during long polarization transfer delays involving $^{13}C-^{15}N$ scalar couplings. In addition, this experiment was used to assign the sidechain resonances of histidines. These assignments can be used to follow the pH-titration of histidine sidechains.

Hyperpolarization: Sensitivity Boost in Magnetic Resonance Spectroscopy and Imaging

  • Ko, Hyeji;Gong, Gyeonghyeon;Jeong, Gijin;Choi, Ikjang;Seo, Hyeonglim;Lee, Youngbok
    • 한국자기공명학회논문지
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    • 제19권3호
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    • pp.124-131
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    • 2015
  • Hyperpolarization methods are the most emerging techniques in the field of magnetic resonance (MR) researches since they make a contribution to overcoming sensitivity limitation of MR spectroscopy and imaging, leading to new fields of researches, real-time in vivo metabolic/molecular imaging and MR analysis of chemical/biological reactions in non-equilibrium conditions. Make use of enormous signal enrichments, it becomes feasible to investigate various chemical and biochemical systems with low ${\gamma}$ nuclei in real-time. This review deals with the theoretical principals of common hyperpolarization methods and their experimental features. In addition, more detailed theories, mechanisms, and applications of dissolution dynamic nuclear polarization (D-DNP) are discussed.

Sampling Methods for Quantification of Solid-state Phases in Powder Samples with Solid-state NMR Spectroscopy

  • Han, Oc-Hee;Kim, Sun-Ha;Ko, Tae-Jung
    • Bulletin of the Korean Chemical Society
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    • 제30권5호
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    • pp.1077-1079
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    • 2009
  • To minimize the variance in the quantification of solid-state phases in powder samples, gently placing polycrystalline samples one next to another directly in a sample holder is better than trying to mix them homogeneously prior to transferring to a sample holder. However, the solid-state cross polarization-magic angle spinning (CP-MAS) nuclear magnetic resonance (NMR) spectroscopy results demonstrated that it is essential in this sampling method to place all the samples in the location of consistent signal sensitivity. The same sampling method may be employed in other spectroscopic quantification techniques of solid-state phases if the method to limit the sample to the location with uniform signal sensitivity in the sample holder is adapted to each technique.

An Optical Intense 2D Electric Field Sensor Using a Single LiNO3 Crystal

  • Zhang, Yuanying;Zhang, Jiahong;Li, Yingna;Lei, Hongyi
    • Current Optics and Photonics
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    • 제6권2호
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    • pp.183-190
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    • 2022
  • Based on the linear electro-optic (EO) effect of lithium niobite (LiNbO3, LN) crystal, an intense two-dimensional (2D) electric field sensor was analyzed, fabricated and experimentally demonstrated. The linear polarized light beam transmits along the optical axis (z-axis) of the LN crystal, and the polarization direction of the polarized light is 45° to the y-axis. The sensor can detect the intensity of a 2D electric field that is perpendicular to the z-axis. Experimental results demonstrated that the minimum detectable electric field of the sensor is 10.5 kV/m. The maximum detected electric field of the sensor is larger than 178.9 kV/m. The sensitivity of the sensor is 0.444 mV/(kV·m-1). The variation of the sensitivity is within ±0.16 dB when the sensor is rotated around a z-axis from 0° to 360°. The variation of the sensor output optical power is within ±1.4 dB during temperature change from 19 ℃ to 26 ℃ in a day (from 7:00 AM to 23:00 PM) and temperature change from 0 ℃ to 40 ℃ in a controllable temperature chamber. All theoretical and experimental results revealed that the fabricated sensor provides technology for the direct detection of intense 2D electric fields.

편광을 이용한 눈의 공간주파수-대비민감도 함수 측정기구 설계 (Contrast Sensitivity as a function of spatial frequency by using polarization)

  • 김용근
    • 한국안광학회지
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    • 제5권1호
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    • pp.43-48
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    • 2000
  • Polarizer와 Analyzer의 Rotation 각에 의해 광의 luminance를 조절할 수 있다. Contrast Sensitivity에 대응한 luminance 값 $L_{max}$, $L_{min}$은 평균 luminance($L_m$)의 회전각 ${\theta}_m$ 최대 진폭과 최소 진폭에 대응하는 회전각 (${\theta}_{max}$, ${\theta}_{min}$)로 부터 구할 수 있다. $$L_{max}=I(0)e^{-2at}{\cdot}cos^2{\theta}_m(1+C_s^{-1})$$ $$L_{min}=I(0)e^{-2at}{\cdot}cos^2{\theta}_m(1-C_s^{-1})$$ 평균 luminance($L_m$)의 회전각 ${\theta}_m$과 측정할 Contrast Sensitivity($C_s$)로부터 polarizer와 analyzer의 회전각(${\theta}_{max}$, ${\theta}_{min}$)을 얻었다. $${\theta}_{max}=cos^{-1}[cos{\theta}_m{\cdot}(1+C_s^{-1})^{1/2}]$$ $${\theta}_{min}=cos^{-1}[cos{\theta}_m{\cdot}(1-C_s^{-1})^{1/2}]$$.

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페이퍼기반 이온 농도 분극 현상 구현 및 상용화 컨셉의 바이오 센서 (Implementation of paper-based Ion concentration polarization phenomenon and Bio-sensor of commercialization concept)

  • 한성일;곽노균;이정훈
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2015년도 제46회 하계학술대회
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    • pp.1219-1220
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    • 2015
  • 마이크로, 나노유체 (micro-, nanofluidics)을 이용한 종이 기반 분석 소자 (paper-based analytical devices, micro-PADs)에 대한 관심이 증가하고 있다. 종이 기반의 분석 소자는 초저가의 비용과 간단한 공정 방법으로 인하여 상용화 컨셉의 바이오센서로 각광받고 있다. 하지만, 종이 기반의 분석 소자는 낮은 검출 한계 (limit of detection, LOD)와 민감도 (sensitivity)의 제한이 있다. 그로 인해 우리는 이온 선택적 투과층 (ion permselective membrane, i.e. Nafion)을 종이 기반의 분석 소자와 결합하여 이온 농도 분극 (ion concentration polarization, ICP) 현상을 구현하여 낮은 검출한계와 민감도를 개선할 수 있었다. 접착력이 있는 테이프 표면에 이온 선택적 투과층을 패터닝 (patterning)하여 종이 기반 분석 소자와 결합하여 매우 간단하게 소자를 제작할 수 있었다. 따라서 종이 기반의 채널 양단에 직류 전압을 인가했을 때 발생하는 ICP 현상으로 인하여 형광 물질 (fluorescence dye)이 농축(preconcentration)되는 것을 확인할 수 있었다. 구체적으로, 초기 농도가 1.55 nM인 형광 물질을 이용하여 200 V의 외부전압을 인가했을 때, 500 초 이내에 1000 배 이상의 농축비를 얻을 수 있었다. 따라서, 외부 전압을 상용화된 건전지 출력값으로 낮출 수 있다면 다양한 종이 기반 분석 소자와 간단한 결합 방법을 통해 상용화 컨셉의 바이오센서로도 구현이 가능할 것이다.

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ESR detection of optically-induced hyperpolarization of nitrogen vacancy centers in diamond

  • An, Min-Gi;Shim, Jeong Hyun;Kim, Kiwoong;Oh, Sangwon;Jeong, Keunhong
    • 한국자기공명학회논문지
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    • 제24권1호
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    • pp.9-15
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    • 2020
  • Nitrogen vacancy center (NV center) in diamond has recently been appeared as a promising candidate for hyperpolarization applications due to its optical pumping property by laser. Optically Detected Magnetic Resonance (ODMR) has been used as a conventional method to obtain the resonance spectrum of NV centers. ODMR, however, has a shortcoming of sensitivity and a limitation of subjects, such that the degree of hyperpolarization can hardly be estimated, and that the spins other than NV centers are invisible. In contrast, Electron Spin Resonance (ESR) spectroscopy is known to proportionally reflect the degree of spin polarization. In this work, we successfully observed the optically-induced hyperpolarization of NV spins in diamond through CW-ESR spectroscopy with an X-band system. All the NV peaks were identified by calculating the eigenvalues of NV spin Hamiltonian. The intensities of NV peaks were enhanced over 240 times after optical pumping. The enhanced peaks corresponding to the transition from |ms=0> to |ms=-1> revealed inverted phases, while other peaks remained in-phase. The optically-induced hyperpolarization on NV spins can be a useful polarization source, leading to 13C nuclear hyperpolarization in diamond.