• 제목/요약/키워드: polar force

검색결과 93건 처리시간 0.025초

반응성 가스 분위기하에서 이온빔을 이용한 폴리머 표면의 친수성 증대 및 세라믹표 면개질 (Improving the Wettability of Polymeric Surfaces and Surface Modification of Ceramic by Ion Beam in Reactive gases Environments)

  • 손용배
    • 마이크로전자및패키징학회지
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    • 제3권1호
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    • pp.11-24
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    • 1996
  • 부분압이 다른 여러 가지 반응성 가스분위기하에서 이른곤 이온을 이용하여 PC, PET PMMA 그리고 PTFE 폴리머 표면의 삼차 증류수에대한 진수성을 증대하였다. 폴리머 표면의 친수성의 변화는 여러 가지 반응성 가스 분위기하에서 아르곤 이온의 조사량을 1014 부터 1x1017cm2까지 변화하면서 조사하였다. 접촉감은 아르곤 이온이 조사되는 폴리머 표면 근처에 유입된 가스의 방응성(O2>N2>H2)에 따라 많이 감소하였다, 폴리머 표면에 형성된 친수성기는 XPS Cls, Ols, 그리고 Nls 스펙트럼을 분석하여 확인하였다. 표면 개질된 PC와 PTFE에 대한 Al 금속의 접착력 증대를 Scotch tape와 인장실험을 통하여 확인하였다. 접착 력 증가는 표면 에너지 중 polar force의 증가에 의한 것으로 입증되었다. 에너지를 가진 아 르곤 입자 폴리머 체인 그리고 반응성 가스 사이의 반응기구는 2단계 모델로 설명가능하였 는데 그 기구는 첫 번째 이온의 조사에 의한 불안정한 폴리머 체인의 형성과 두 번째 단계 로 이렇게 형성된 폴리머 체인과 반응성 가스들 사이의 화학반응으로 이루어진다. 질화아루 미늄의 표면을 산소분위기하에서 아르곤 빔을 조사하여 표면개질한후 AlON층이 새롭게 형 성된 것을 XPS를 이용하여 확인할수 있었다. 개질된 질화알루미늄과 구리금속 박막간의 접 착력을 scratch 실험을 통하여 조사하였다.

non-polar 6H-SiC wafer의 CMP 가공에 대한 연구

  • 이태우;심병철;이원재
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
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    • pp.141-141
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    • 2009
  • Blue light-emitting diodes (LEDs), violet laser diodes 같은 광전소자들은 질화물 c-plane 기판위에 소자로 응용되어 이미 상품화 되어 왔다. 그러나 2족-질화물 재료들은 wurtzite 구조를 가지므로 c-plane에 평행한 자연적인 극성을 띌 뿐만 아니라 결정 내부 stress로 인한 압전현상 또한 나타나 큰 내부 전기장을 형성하게 된다. 이렇게 생성된 내부 전기장은 전자와 홀의 재결합 효율을 감소시키고 소자 응용 시 red-shift의 원인이 되곤 한다. 따라서 최근 들어 m-plane(1-100), a-plane (11-20)같은 무극성을 뛰는 기판 위에 소자를 만드는 방법이 각광을 받고 있는 추세다. 그러나 무극성 기판을 소자에 응용 시 Chemical Mechanical Planarization (CMP)에 의한 가공은 반도체 기판으로써 이용하기 위한 필수 불가결의 공정이다. c면(0001) SiC wafer에 대한 연구는 현재 많이 발표가 되어 있으나 무극성면 SiC wafer에 대한 CMP 공정에 대한 연구사례는 없는 실정이다. 본 연구에서는 C면 (0001)으로 성장된 잉곳을 a면(11-20)과 m(1-100)면으로 절단 후, slurry type (KOH-based colloidal silica slurry, NaOCl), 산화제, 연마제등을 변화하여 CMP 공정을 거침으로서 일어나는 기계 화학적 가공 양상에 대하여 알아보았다. 그 후 표면 형상 분석 하기위해 Atomic Force Microscope(AFM)을 사용하였고, 표면 스크레치를 SEM을 이용해서 알아보았다.

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Kevlar-29 섬유강화 복합재료의 기계적 계면 특성 연구 (Studies on Mechanical Interfacial Properties of Kevlar-29 Fibers Reinforced Composites)

  • Park, Soo-Jin;Seo, Min-Kang;Ma, Tae-Jun;Lee, Jae-Rock
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2001년도 추계학술발표대회 논문집
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    • pp.158-162
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    • 2001
  • The effects of chemical treatment on Kevlar-29 fibers have been studied in a composite system. The surface characteristics of the Kevlar-29 fibers were characterized by pH, acid-base value and X-ray photoelectron spectroscopy (XPS). The mechanical interfacial properties of final composites were studied by interlaminar shear strength (ILSS) and critical stress intensity factor ($K_{IC}$). Also, the impact properties of the composites were investigated in the differentiating studies between initiation and propagation energies, and ductile index (DI) along with maximum farce and total energy. It was found that the chemical treatment with phosphoric acid ($H_3PO_4$) solution significantly affected the degree of adhesion at interfaces between fibers and resin matrix, resulting in improving the mechanical interfacial strength of the composites. This was probably due to the presence of chemical polar groups on Kevlar surfaces, leading to an increment of interfacial binding force in a composite system.

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Solvent Treatment for PEDOT:PSS Conductivity Enhancement

  • 황기환;정원석;남상훈;유정훈;주동훈;부진효
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.333-333
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    • 2013
  • The poor conductivity of poly (3,4-ethylene dioxythiophene): poly (styrenesulfonate) (PEDOT:PSS) film hinders to use for a flexible electrode in solar cells. In this report we demonstrate that the conductivity of PEDOT:PSS film can be enhanced by modifying structures in a mixture of PEDOT: PSS aqueous solution and various organic solvents such as polar protic (2-propanol, methanol, ethanol, formic acid) and aprotic solvents (acetone and acetonitrile). To comparatively study the structural effects on the resulted electrical properties, the films are spin-coated on glasses and ITO. At the same time, a contact angle goniometer is used for clarifying a mechanism of wettability of PEDOT (hydrophobic) and PSS (hydrophilic) on the observed conductivity. The structures and electrical properties are investigated by FE-SEM (Field Emission Scanning Electron Microscopy), AFM (Atomic Force Microscopy), and 4-point probe, respectively.

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The Sociopolitical Economics of Marine Ranching Program in Korea

  • Park, Seong-Kwae
    • Ocean and Polar Research
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    • 제23권3호
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    • pp.265-277
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    • 2001
  • This paper aims at overviewing Korean fisheries profile with a view on why Korean fisheries need marine ranching program as a new fisheries paradigm - a community-based co-management approach and drawing some policy implications from the advanced experience in fisheries. The aims of community-based co-management approach as a planned approach can be set out under the planning objectives of efficiency and equity. In this context Tongyeong marine ranching program is an important government-sponsored pilot enterprise. Experiences in the advanced fisheries such as Canadian Snow-Crab case suggest that in order to be successful for marine ranching be successful it is necessary that (i) there should be high-value species, (ii) property right should be established, (iii) there should be the reasonable number of participants involved, (iv) the participants and the government should be able to share resource enhancement/management/utilization responsibilities and associated fisheries management expenses. Among these, management cost sharing based on the practical partnership between fishing communities and government is of particular importance because the government must have a full responsibility for all ranching program expenditure unless revenues sufficient to guarantee reasonable income and to share management cost are generated from the ranching business.

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5,000톤급 대형 해양과학연구선 설계 특성 (Key Layouts of the 5,000 ton' New Scientific Research Vessel of KIOST)

  • 박정기
    • Ocean and Polar Research
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    • 제37권3호
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    • pp.235-247
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    • 2015
  • The main purpose of procuring the oceanographic research vessel with state-of-the-art technology is to provide a floating laboratory to conduct field work on the global oceans. The vessel should be properly utilized to locate and evaluate unexplored natural resources as well as to contribute international efforts to better understand and manage global environmental issues. Top priorities in the vessel design are high safety standards, noise and vibration control efficiency, and effective application of research equipment. For the accomplishment of all activities, the vessel length over all should be extended ~100 m with a gross tonnage of ~5,900 ton. In particular, the dynamic positioning system II will essentially operate at sea state 6. The high efficiency emissions reduction system will also be adopted in preparation for entry into force of 3rd exhaust emission control (Tier III). About 130 navigational and scientific instruments will be installed. The final design and model test of the new research vessel were reviewed and completed, respectively, in 2014. Currently, the ship is being built on schedule and expected to be delivered in December 2015. Within the near future, the new vessel will assume the role of carrying out multidisciplinary oceanographic researches of the highest standards in a technologically advanced and environment friendly manner.

곡관내의 주유동에 분사되는 난류제트에 대한 3차원 국소타원형 수치해석 (3-Dimensional Locally Elliptic Numerical Predictions of Turbulent Jet in a Crossflow In A Curved Duct)

  • 정형호;이택식;이준식
    • 대한기계학회논문집
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    • 제14권2호
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    • pp.470-483
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    • 1990
  • Turbulent jet in a crossflow, issuing from a row of holes on a convex surface of 90 .deg. bend duct, is predicted by a 3-dimensional numerical method. The Cartesian coordinate system in adopted in upstream and downstream tangents and the cylindrical polar coordinate system in curved region. The Reynolds stresses and heat fluxes are obtained from a standard k-e model in the core region and van Driest model in the vicinity of the wall. The governing equations are discretized by a finite volume method and solutions are obtained by a locally elliptic calculation procedure. Pressure and convective terms are treated by SIMPLE algorithm and hybrid scheme respectively. A vortex initially induced by the injected jet has been built up due to the interaction with the secondary flow caused by pressure gradient and centrifugal force. The vortex structure has a strong influence on the wall cooling effectiveness. Another vortex like horseshoe is formed in the vicinity of the injection hole and its strength is getting weak as it moves downward.

심해저 광물자원 개발제도의 운영결과 분석 및 향후전망 (Evaluation on the Outcome of International Deep Seabed Mining Regime and Its Prospect)

  • 이용희
    • Ocean and Polar Research
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    • 제27권1호
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    • pp.97-108
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    • 2005
  • The International Seabed Authority (ISA) formally came into existence upon the entry into force of the UNCLOS on 16 November 1994. By adopting the Implementing Agreement in 1994, UNCLOS has the universality as a Magna Carta of International Ocean Regime, and the Deep Seabed Mining Regime could be operated as a unique one for the benefit of mankind. During last 10 years, ISA established the institutional framework successfully and made substantial and tangible progress in formulating the rules, regulations and procedures for the prospecting and exploration for polymetally nodules. Furthermore, RPI's obligations had been carried out completely, and the 7 RPI made contract with ISA to become a contractor who has an at least 15 you exclusive right for exploration in their allocated site. However, due to the uncertainty of commercial mining, the number of representatives from developing countries has been getting looser and looser and ISA has a problem of quorum of the Assembly. Land-based producers took a very strong opposite position to the contractors to make their loss in the minimum level. For the next decade, it might be prospected that ISA will focus on monitoring the contractor's activities, making rules, regulations and procedures for exploration on cobalt rich crust, sulphide and methane hydrate and implementing environment studies.

비연성 수직형 마이크로 자이로스코프의 구조해석 및 최적설계 (Structural Analysis and Optimum Design of a De-coupled Vertical Micro-Gyroscope)

  • 박성균;정희문;김명훈;김형태;하성규
    • 대한기계학회논문집A
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    • 제27권11호
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    • pp.1840-1848
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    • 2003
  • This paper presents the structural analysis and optimum design of a vertical micro-gyroscope with decoupled 2 degrees of freedom (DOF), driven by electrostatic force. Simplified beam models were presented to derive the structural stiffness of the driving spring of the U shape and the sensing spring of I shape. A finite element analysis (FEA) was performed to validate each derivation. A total mass and a polar mass moment of inertia were also obtained and used in calculating the resonance frequency at each mode of the 2 DOF. The resonance frequencies of the total system were calculated using the proposed models and it has been found that they were in excellent agreement with those of the FEA. Finally, the developed analysis program was then linked to an optimum design module, and an optimum design of the micro-gyroscope was successfully performed.

Surface modification of $TiO_2$ by atmospheric pressure plasma

  • 조상진;정충경;부진효
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.96-96
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    • 2010
  • To improve surface wettability, each sample was treated by atmospheric pressure plasma (APP) using dielectric barrier discharge (DBD) system. Argon and oxygen gases were used for treatment gas to modify the $TiO_2$ surface by APP with RF power range from 50 to 200 W. Water contact angle was decreased from $20^{\circ}$ to $10^{\circ}$ with argon only. However, water contact angle was decreased from $20^{\circ}$ to < $1^{\circ}$ with mixture of argon and oxygen. Water contact angle with $O_2$ plasma was lower than water contact angle with Ar plasma at the same RF power. It seems to be increasing the polar force of $TiO_2$ surface. Also, analysis result of X-ray photoelectron spectra (XPS) shows the increase of intensity of O1s shoulder peak, resulting in increasing of surface wettability by APP. Moreover, each water contact angle increased according to increase past time. However, contact angle increase with plasma treatment was lower than without plasma treatment. Additionally, the efficiency of $TiO_2$ photocatalyst was improved by plasma surface-treatment through the degradation experiment of phenol

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