• Title/Summary/Keyword: polar effect(e)

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THE EFFECT OF ETHYLENE GLYCOL ANALOGS ON MECHANICAL PROPERTIES OF MOIST DEMINERALIZED DENTIN MATRIX (Ethylene Glycol 유사체가 탈회된 상아질의 물리적 성질에 미치는 영향)

  • Lee Kyung-Hee;Cho Young-Gon;Lee Kwang-Won
    • Restorative Dentistry and Endodontics
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    • v.31 no.4
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    • pp.290-299
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    • 2006
  • Objectives: The purpose of this study is to evaluate the effect of ethylene glycol analogs on modulus of elasticity and ultimate tensile strength of moist, demineralized dentin matrix. Methods: Dentin disks 0.5 mrn thick were prepared from mid-coronal dentin of extracted. unerupted, human third molars. 'I' beam and hour-glass shaped specimens were prepared from the disks, the ends protected with nail varnish and the central regions completely demineralized in 0.5M EDTA for 5 days. Ultimate tensile stress (UTS) and low strain modulus of elasticity (E) were determined with specimens immersed for 60 min in distilled water $(H_{2}O)$, ethylene glycol $(HO-CH_{2}-CH_{2}-OH)$, 2-methoxyethanol $(H_{3}CO-CH_{2}-CH_{2}-OH)$, and 1,2-dimethoxyethane $(H_{3}CO-CH_{2}-CH_{3}-OCH_{3})$ prior to testing in those same media. Modulus of elasticity was measured on the same specimens in a repeated measures experimental design. The results were analyzed with a one-way ANOVA on ranks, followed by Dunn's test at ${\alpha}\;=\;0.05$. Regression analysis examined the relationship between UTS or E and hoy's solubility parameter for hydrogen bonding $({\delta}_{h})$ of each solvent. Results: The UTS of demineralized dentin in water, ethylene glycol, 2-methoxyethanol, and 1,2-dimethoxyethane was 24 (3), 30 (5), 37 (6), and 45 (6) MPa, ${\times}$ (SD) N = 10. Low strain E for the same media were 16 (13), 23 (14), 52 (24), and 62 (22) MPa. Regression analysis of UTS vs ${\delta}_{h}$ revealed a significant $(p\;<\;0.0001,\;r\;=\;-0.99,\;R^{2}\;=\;0.98)$ inverse, exponential relationship. A similar inverse relationship was obtained between low strain E vs ${\delta}_{h}\;(p\;<\;0.0005,\;r\;=\;-0.93,\;R^{2}\;=\;0.86)$. Significance: The tensile properties of demineralized dentin are dependent upon the hydrogen bonding ability of polar solvents $({\delta}_{h})$. Solvents with low ${\delta}_{h}$ values may permit new interpeptide H-bonding in collagen that increases its tensile properties. Solvents with high ${\delta}_{h}$ values prevent the development of these new interpeptide H-bonds.

Cruise Report on TAO Real-time Monitoring Buoy System in the Pacific Ocean in April 2010 (2010년 4월 TAO 해양관측부이 시스템에 관한 탐사보고)

  • Kim, Dong-Guk;Kim, Seon-Jeong;Lee, Ha-Woong
    • Ocean and Polar Research
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    • v.33 no.4
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    • pp.507-516
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    • 2011
  • Tropical Atmosphere Ocean/Triangle Trans-Ocean Buoy Network (TAO/TRITON) Array is the series of buoys for the international ocean research project, which is mostly supported by National Ocean and Atmosphere Administration (NOAA) and Japan Agency for Marine-Earth Science and Technology (JAMSTEC). We can determine the effect of the equatorial and Pacific Ocean conditions on global climate change from buoy array measurement data. The TAO/TRITON array comprises around 70 measurement buoys from $10^{\circ}$ north to $10^{\circ}$ south in the tropics and between Galpagos and New Guinea. NOAA maintains ATLAS buoys in the central and eastern Pacific between $165^{\circ}E$ and $95^{\circ}W$, and JAMSTEC maintains the 12 buoys in the western Pacific along $137^{\circ}E$, $147^{\circ}E$, and $156^{\circ}E$. The KA-10-03 cruise excursion provided us with a good opportunity to obtain knowledge on oceanic buoy operation and maintenance. Further, we learned advanced techniques and know-how on buoy operation and maintenance. Once we are confident with our buoy management and maintenance techniques, both KORDI and NOAA technicians may be able to help each other when needed and share available resources.

TWO-COLOR VR CCD PHOTOMETRY OF THE INTERMEDIATE POLAR `RXS J062518.2+733433

  • Kim, Yong-Gi;Andronov Ivan L.;Park, Sung-Su;Chinarova Lidia L.;Baklanov Alexey V.;Jeon, Young-Beom
    • Journal of Astronomy and Space Sciences
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    • v.22 no.3
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    • pp.197-210
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    • 2005
  • Results of 7 nights of CCD VR photometry of the intermediate polar 1RXS J062518.2+733433 obtained at the Korean 1.8m telescope are reported. The corrected ephemeris for the orbital minimum is BJD (Orb.min) = 2453023.6159(42)+0.1966431(33) (E-1735). The corrected ephemeris for the spin maximum is BJD (spin max) = 2452893 78477 (10)+0.01374116815 (17) (E-15382) (cycle numbering corresponds to that of Staude et al.2003). The variations of the shape of the individual spin variations are highly correlated in V and R. The phase of the spin maximum is found to be dependent on the orbital phase. The corresponding semi-amplitude of sinusoidal variations of phase is $0.11{\pm}0.03.$ This new phenomenon is explained by the changing viewing conditions of the accreting magnetic white dwarf, and should be checked in further observations this star and for other intermediate polars. To avoid influence of this effect on the analysis of the long-term spin period variations, the runs of at least one orbital period are recommended. Results of time series analysis are presented in tables.

Allelopathic Effects of Medicinal Plants on Echinoclhoa crus-galli Beauv. (약용작물의 Allelopathy 효과에 관한 연구)

  • Kim, Sang-Yeol;Kim, Chil-Ryong;Park, Sung-Tae;Kim, Soon-Chul
    • Korean Journal of Weed Science
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    • v.17 no.4
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    • pp.407-412
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    • 1997
  • Allelopathic activity of methanol extract from medicinal plants was determined based on the inhibition of germination, shoot and root length of Echinochloa crus-galli. The response was depended on the source of extracts and concentrations. Of the 20 test plants tested, Cnidium officinale showed most inhibition according to germination, shoot and root length of E. crus-galli. Based on the plant parts, the root extract of C. officinale had more inhibitory effect on E. crus-galli than the stem+leaf extract. Phytotoxic effects of the root extract on E. crus-galli showed 75% inhibition of seed germination, 95% inhibition of shoot growth, and 100% inhibition of root growth at the concentration of 1g/petridish. Sequential partitioning of root extract with organic solvents with increasing polarity showed that the ethylacetate fraction had the greatest inhibitory effect on E. crus-galli. Germination was not inhibited at any rate of ethylacetate fraction but shoot and root growth, were significantly inhibited even at 2mg/petridish. This indicates that the most toxic phytotoxin present in the root extract may be moderate polar compound.

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Effect of Infra-Gravity Waves on Nearshore Morphodynamics in the East Coast : Case Study - Ilsan Beach (장주기 중력외파의 동해안 연안지형변화에 미치는 영향 연구 : 사례연구 - 일산해변)

  • Son, Donghwi;Yoo, Jeseon;Shin, Hyunhwa
    • Ocean and Polar Research
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    • v.40 no.2
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    • pp.87-98
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    • 2018
  • It is widely known that infragravity waves can exert significant influence on wave run-up over beaches. Large run-ups can lead to overwash, flooding and severe coastal erosion. In spite of the importance of infragravity waves in relation to wave run-up and coastal erosion, few studies have been carried out with regard to the impact of infragravity waves on nearshore morphodynamics with respect to eastern beaches in Korea. The purpose of this study is to investigate the importance of infragravity waves in nearshore numerical modelling. For the study, XBeach model was set up to analyze morphodynamics in December 2016, in Ilsan beach which is located in Ilsan-dong, Ulsan Metropolitan City. After validation of the XBeach model, numerical experiments were conducted by using various directional spreading coefficients. As the directional spreading coefficients are increased, the effect of infragravity waves is also enhanced by narrowband frequency. With the increasing effect of infragravity waves, the amount of sediment transport is also increased and an erosion dominant pattern is found in the south part of Ilsan beach and a deposition pattern in the north part of the beach mainly due to the wave incident direction of NNE.

Effect of Polar Amino Acid Residue Substitution by Site-Directed Mutagenesis in the N-terminal Domain of Pseudomonas sp. Phytase on Enzyme Activity

  • Lee, Ga Hye;Jang, Won Je;Kim, Soyeong;Kim, Yoonha;Kong, In-Soo
    • Journal of Microbiology and Biotechnology
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    • v.30 no.7
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    • pp.1104-1107
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    • 2020
  • The N-terminal domain of the Pseudomonas sp. FB15 phytase increases low-temperature activity and catalytic efficiency. In this study, the 3D structure of the N-terminal domain was predicted and substitutions for the amino acid residues of the region assumed to be the active site were made. The activity of mutants, in which alanine (A) was substituted for the original residue, was investigated at various temperatures and pH values. Significant differences in enzymatic activity were observed only in mutant E263A, suggesting that the amino acid residue at position 263 of the N-terminal domain is important in enzyme activity.

Significant Improvement of Catalytic Efficiencies in Ionic Liquids

  • Song, Choong-Eui;Yoon, Mi-Young;Choi, Doo-Seong
    • Bulletin of the Korean Chemical Society
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    • v.26 no.9
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    • pp.1321-1330
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    • 2005
  • The use of ionic liquids as reaction media can confer many advantages upon catalytic reactions over reactions in organic solvents. In ionic liquids, catalysts having polar or ionic character can easily be immobilized without additional structural modification and thus the ionic solutions containing the catalyst can easily be separated from the reagents and reaction products, and then, be reused. More interestingly, switching from an organic solvent to an ionic liquid often results in a significant improvement in catalytic performance (e.g., rate acceleration, (enantio)selectivity improvement and an increase in catalyst stability). In this review, some recent interesting results which can nicely demonstrate these positive “ionic liquid effect” on catalysis are discussed.

Strain Properties of Sn-Substituted PLZT(7.5/70/30) for Application of Ceramic Actuator (세라믹 엑튜에이터 응용을 위한 Sn 치환의 PLZT(7.5/70/30)의 변형특성)

  • 고태경;강현구;박재환
    • Journal of the Korean Ceramic Society
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    • v.35 no.5
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    • pp.512-520
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    • 1998
  • PLZT(7.5/70/30) was initially a cubic phase having diffuse phase transition at high temperatures. Sn-sub-stitution for PLZT(7.5/70/30) underwent an irreversible phase transition from cubic to rhom-bohedral structure. However PLZTS(7.5/70/30/y=5 & 10) could be reversibly switched from paraelectric to ferroelectric phase under electric field without showing a significant change in crystal structure. With in-creasing the amount of Sn-substitution the P-E behaviors of the PLZTS became more antiferroelectric which was similar to the effect of La-substitution of PLZT. Our study may suggest that Sn-substitution ef-fectively weakens a formation of long-range order between polar Ti-or Zr- containing octahedra which greatly affects strain properties.

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Effect of Chromium Chloride on the Mechanical and Dielectric Properties of EPDM Rubber

  • Salem, M.A.;Khaled, M.A.;Hussein, A.M.;Elway, E.
    • Macromolecular Research
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    • v.11 no.4
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    • pp.256-259
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    • 2003
  • Measurements of Young's modulus, dielectric loss and a.c. conductivity have been carried out on EPDM rubber samples loaded with different concentrations of $CrCl_3$ (0,2,4 and 6 phr). The values of Young's modulus was found to be linearly dependent on the $CrCl_3$ content. Variation of the dielectric loss with temperature showed that $CrCl_3$ may act as plasticizer. However, at higher frequencies the dielectric loss was found to be independent of frequency and the rubber samples may behave as non-polar dielectric. Investigations of the a.c conductivity suggested that the conduction in these rubber samples can be described by small polaron tunneling. In addition, conductivity was found to increase with $CrCl_3$ content.

The Effect of E.G.F. and Human Follicular fluid on the Maturation of Mouse Oocytes in in vitro Culture (생쥐난의 체외 배양에서 인간난포액과 표피 성장 인자가 난성숙에 미치는 영향)

  • Min, Bu-Kie
    • Clinical and Experimental Reproductive Medicine
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    • v.20 no.2
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    • pp.157-160
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    • 1993
  • The human follicular f1uids(F.F.) may be considered to contribute the maturation of the oocytes on the in vitro culture. To investigate the effects of epidermal growth factor (E.G.F.), which is present in mature and immature follicular fluids, we had experiments of mouse oocytes maturation in vitro. The endpoints assayed were rated as percentage of oocytes undergoing germinal vesicle breakdown(G.V.B.D.) and polar body(P.B.) formation at 12 hours after in vitro culture. The rates of G.B.B.D. were 87% in mature F.F. 68% in immature F.F. and 78% in Ham's F-10 medium respectively. And overall the mature F.F. seem to stimulate on in vitro oocyte maturation compared with either immature F.F. or Ham's F-10 medium. As the concentration of addition of E.G.F. in immature F.F., the rates of G.V.B.D. and P.B. formation were 82 %, 23% in addition with 2 ng/ml while 84%, 32% in addition with 4 ng/ml respectivly. And at the concentration of addition of E.G.F. in Ham's F-10 media as well, the rates of G.V.B.D. and P.B. formation were 84%, 40% and 82%, 44% in addition with each 2ng, 4ng. AccordinglY there was no influence on the oocytes maturation at the addition of E.G.F. to each immature F.F. and Ham's F-10 medium. In conclusion, the E.G.F. is not able to induce oocyte maturation independent of it's effects in immature F.F. and Ham's F-10 media.

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