• Title/Summary/Keyword: polar effect(e)

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Electron Transport Mechanisms in Ag Schottky Contacts Fabricated on O-polar and Nonpolar m-plane Bulk ZnO

  • Kim, Hogyoung
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.5
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    • pp.285-289
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    • 2015
  • We prepared silver Schottky contacts to O-polar and nonpolar m-plane bulk ZnO wafers. Then, by considering various transport models, we performed a comparative analysis of the current transport properties of Ag/bulk ZnO Schottky diodes, which were measured at 300, 200, and 100 K. The fitting of the forward bias current-voltage (I-V) characteristics revealed that the tunneling current is dominant as the transport component in both the samples. Compared to thermionic emission (TE), a stronger contribution of tunneling current was observed at low temperature. The reverse bias I-V characteristics were well fitted with the thermionic field emission (TFE) in both the samples. The presence of acceptor-like adsorbates, such as O2 and H2O, modulated the surface conductive state of ZnO, thereby affecting the tunneling effect. The degree of activation/passivation of acceptor-like adsorbates might be different in both the samples owing to their different surface morphologies and surface defects (e.g., oxygen vacancies).

Estimation of Excited State Dipole Moment of Exalite Dyes by Solvatochromic Shift Studies

  • Inamdar, S. R.;Nadaf, Y.F.;Deshpande, D.K.;Karguppikar, A.M.
    • Journal of Photoscience
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    • v.9 no.1
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    • pp.29-32
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    • 2002
  • The solvent effect in a series of polar and non-polar solvents of varying dielectric constants and refractive indices has been investigated by studying electronic spectra (S$_1$band) of a series of exalite laser dyes at room temperature (25$\pm$1$\^{C}$). These data are used to determine the magnitude ($\mu$$\_$e/) and direction ($\theta$) of the electric dipole moments in the first electronically excited state. The results indicate that the observed band systems in these compounds may be attributed to ←$\pi$ transition.

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Effect of Polar Components on Phase Inversion Temperatures in Systems Containing Nonionic Surfactants and Nonpolar Oils (비이온성 계면활성제, 비극성 오일을 포함한 계에서의 극성 성분의 Phase Inversion Temperature에 대한 영향)

  • Lim, Jong-Choo;Mori, Fuyuhiko
    • Applied Chemistry for Engineering
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    • v.5 no.2
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    • pp.274-284
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    • 1994
  • Phase Inversion Temperature (PIT) measurements showed that the addition of polar components such as oleyl alcohol and oleic acid to the system comprising n-dodecylpentaoxyethylene monoether ($C_{12}E_5$), nonpolar oil (n-hexadecane) and water produced large reductions in the PIT. The PIT was lowered as the additive-to-surfactant ratio in the surfactant films in the microemulsion phase was increased. Another dramatic effect of additive was the manner in which it affects the volume of the microemulsion phase at the PIT of the oil and water solubilization characteristics. Microemulsion phase volume was increased rapidly with decreasing PIT, i.e., with increasing amounts of additive in the system. Also with a decrease in PIT, the solubilization parameters of both oil and water in the microemulsion phase were strikingly increased. Even though soil removal data were not available for the conditions where our results obtained, PIT measurement seems a useful starting point for estimating conditions when middle-phase microemulsion formation and its associated high solubilization of oil can be expected.

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Molecular Interactions of Soaked Nonionic Dye in Ionomer Films (아이오노머 필름에 흡수된 비이온계 염료의 분자간 상호작용에 관한 연구)

  • ;;;;;;Forrest A. Landis;Robert B. Moore
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.671-678
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    • 2001
  • Sodium and zinc salts of poly(ethyaene-co-methacrylic acid) ionomers consist of three phases, i.e. ionic aggregates, amorphous, and crystalline phases. Dye molecules after soaked from the methanol solution are located near the amorphous phase or ionic aggregates within ionomer films. Depending on the location of the molecules in the ionomer film, they are under influence of dispersion forces (ethylene parts), polar forces (acid parts). and ionic dipole (ionic aggregates) interactions. The UV/Vis absorption peak of Nile Red under the dispersion force is found at near 500 nm, for the dye under the polar force effect 525 nm, and 550 and 610 nm for the dyes under $Na^+$ and $Zn^{2+}$ ionization effects, respectively. Since the divalent $Zn^{2+}$ ion has larger ionic dipole than the monovalent $Na^+$ ion, the larger red-shift of the absorption band due to the ionic dipole interaction is observed for $Zn^{2+}$ counter ion.

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Antiestrogenic Effects of Marijuana Smoke Condensate and Cannabinoid Compounds

  • Lee Soo Yeun;Oh Seung Min;Lee Sang Ki;Chung Kyu Hyuck
    • Archives of Pharmacal Research
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    • v.28 no.12
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    • pp.1365-1375
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    • 2005
  • The antiestrogenic effects of marijuana smoke condensate (MSC) and three major cannabinoids, i.e., $\bigtriangleup^{9}$-tetrahydrocannabinol (THC), cannabidiol (CBD), and cannabinol (CBN), were evaluated using in vitro bioassays, viz., the human breast cancer cell proliferation assay, the recombinant human estrogen receptor (ER) competitive binding assay, and the reporter gene assay. The inhibitory effects on estrogen were also examined using the ethoxyresorufin-O­deethylase (EROD) assay, the aromatase assay, and the 17$\beta$-estradiol ($E_{2}$) metabolism assay. The results showed that MSC induced the antiestrogenic effect via the ER-mediated pathway, while THC, CBD, and CBN did not have any antiestrogenic activity. This suggests that the combined effects of the marijuana smoke components are responsible for the antiestrogenicity of marijuana use. In addition, MSC induced the CYP1A activity and the $E_{2}$ metabolism, but inhibited the aromatase activity, suggesting that the antiestrogenic activity of MSC is also related to the indirect ER-dependent pathway, as a result of the depletion of the in situ $E_{2}$ level available to bind to the ER. In conclusion, pyrogenic products including polycyclic aromatic hydrocarbons (PAHs) in the non-polar fraction, which is the most biologically active fraction among the seven fractions of MSC, might be responsible for the antiestrogenic effect.

Free-Radical Copolymerization of Glycidyl Methacrylate with Phthalimidoethyl Acrylate : Synthesis and Determination of Monomer Reactivity Ratios (GMA와 프탈이미드아크릴레이트의 공중합체 합성과 반응성비)

  • Oh, Seung-Min;Oh, Dae-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.2
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    • pp.297-304
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    • 2013
  • Free-radical copolymerization of glycidyl methacrylate(GMA) and N-phthalimidoethyl acrylate(NPEA) were carried out at $60^{\circ}C$ in dimethylformamide(DMF) solution in the presence of benzoylperoxide(BPO) at low conversion. The polymers were characterized by IR and $^1H$-NMR. The compositions of the copolymer was analyzed by ultra violet(UV/Vis) spectrophotometry. The reactivity ratios of the monomer was determined by the application of Fineman-Ross(FR) and Kelen-T$\ddot{u}$d$\ddot{o}$s(KT) methods. The monomer reactivity ratios of the system and Alfrey-Price's resonance effect(Q) and polar effect(e) value for NIEA were determined as follow. The reactivity ratios of the monomer obtained from FR and KT are found to be $r_1$=0.87, $r_2$=0.98 and $r_1$=0.88, $r_2$=0.99 respectively. The Q and e values of poly(GMA-co-NPEM) calculated from $r_1$ and $r_2$ was Q= 1.31, e=0.75 respectively.

CLIMATOLOGICAL CHARACTERISTICS OF THE POLAR IONOSPHERE BASED ON THE SONDRESTROM INCOHERENT SCATTER RADAR MEASUREMENTS (SONDRESTROM 비간섭 산란 레이더 자료를 이용한 극지방 전리층의 기후학적 특성 연구)

  • 곽영실;안병호
    • Journal of Astronomy and Space Sciences
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    • v.19 no.1
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    • pp.75-88
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    • 2002
  • The climatological characteristics of the polar ionosphere is examined in terms of the ionospheric conductance and electric field. For this purpose, 109 days of measurements from the Sondrestrom incoherent scatter radar are utilized. By combining these two quantities, it is possible to deduce the overhead ionospheric current distributions. The ionospheric current density thus obtained is compared with the corresponding ground magnetic disturbance. Also examined is the effect of the field-aligned current on the ground magnetic disturbance, particularly on the D component Several interesting climatological characteristics about the ionosphere over the Sonderstrom are apparent from this study. (1) The conductance distribution is mainly due to solar EUV radiation during day-time On the other hand, the conductance distribution during the night-time is very low. (2) The conductance distribution one. the polar cap region during the day-time is controlled mostly by the solar EUV radiation, while it is extremely low during night-time wish the Hall and Pedersen conductances being 1.6 and 1.2 siemen, respectively (3) The region of the maximum N-S electric field tend to locate in the dayside sector. The E-W component of the electric field is stronger than that over Chatanika (4) The E-W auroal inospheric current (J/sub E/) is more important in the sunlit hemisphere than the night hemisphere. And a strong southward current is noted in the prenoon sector (5) There is a significant correlation between the overhead ionospheric current and the simultaneously observed ground magnetic disturbance. However, the assumption for the infinite sheet current approximation is far from realistic, underestimating the current density. And the correlation between ${\Delta}H$ and J/sub E/ is higher than the one between ${\Delta}D$ and J/sub N/ , indicating that field-aligned current affects significantly ${\Delta}D$.

Orthogonal NOMA Strong Channel User Capacity: Zero Power Non-Zero Capacity Transmission

  • Chung, Kyuhyuk
    • Journal of IKEEE
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    • v.23 no.2
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    • pp.735-738
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    • 2019
  • Recently, orthogonal non-orthogonal multiple access (O NOMA) with polar on-off keying (POOK) has been proposed to mitigate the severe effect of the superposition. However, it is observed that the performance of the O NOMA strong channel user is better than that of the perfect successive interference cancellation (SIC), i.e., the performance of a single user transmission with binary phase shift keying (BPSK). Can the performance of the BPSK modulation be better that that of itself? It is not normal. It should be clearly understood theoretically, with the ultimate bound, i.e., the channel capacity. This paper proves that the channel capacity of the O NOMA strong channel user is non-zero with zero power allocation. Thus, it is shown that the interference is transformed effectively into the meaningful signal.

Synthesis of Naphthalimidopropyl Acrylate and GMA Copolymers and Their Physical Properties (나프탈이미도프로필 아크릴레이트와 GMA 공중합체의 합성과 물성)

  • Lim, Deok Jum;Oh, Seung Min;Kim, Boo Yoon;Park, Jae Kyung;Kang, Inn-Kyu;Seo, Kwan-Ho;Oh, Dae Hee
    • Polymer(Korea)
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    • v.38 no.4
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    • pp.535-543
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    • 2014
  • This work, which was about the synthesis of naphthalimidopropyl acrylate and GMA copolymers and their physical properties, investigated the compositions of the copolymer, the reactivity ratios of the monomer, resonance effect (Q), polar effect (e) and fluorescence of naphthalene. Azobisisobutyronitronitryl (AIBN) as an initiator was employed at $60^{\circ}C$ with dimethylformamide (DMF) of solvent for the copolymerization of NIPA. $r_1$ was found to be higher than $r_2$ from the reactivity ratios of the monomer obtained from Fineman-Ross (F-R), Kelen-$T{\ddot{u}}d{\ddot{o}}s$(K-T) methods. NIPA was found to be more copolymerized than GMA. $r_1{\cdot}r_2$ product was lower than 1, copolymerization was maked random-alternating type. The fluorescence spectrum of these polymers showed a weak monomer fluorescence band at 380 nm and a strong excimer fluorescence band at about 460 nm. Fluorescence life time of NIPA monomer showed fluorescence cover with UV 355 nm at room temperature, and life time showed $5.1449{\times}10^{-7}s$.

COMPARISON OF TURBULENCE MODELS ON ANALYSIS OF AIRCRAFT CONFIGURATIONS AT TRANSONIC SPEED (천음속 영역에서 항공기 유동해석에 미치는 난류모델의 영향 비교)

  • Huh, J.;Lee, N.;Lee, S.;Kwak, E.
    • Journal of computational fluids engineering
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    • v.20 no.1
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    • pp.47-56
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    • 2015
  • In this paper, we study the effect of various turbulence models by comparing the aerodynamic characteristics and the flow patterns computed for aircraft models. An in-house CFD solver, MSAPv, that solves the three dimensional RANS equations with the turbulence model equations is used. The turbulence models used in this study are the Spalart-Allmaras model, Menter's $k-{\omega}$ SST model, Coakley's $q-{\omega}$ model, and Huang and Coakley's $k-{\varepsilon}$ model. DLR-F6 WB and WBNP configurations are selected for the study. We concentrate on the separated flow pattern variations with the turbulence models at the wing-body junction and the wing-pylon junction as well as drag polar curves.