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http://dx.doi.org/10.7317/pk.2014.38.4.535

Synthesis of Naphthalimidopropyl Acrylate and GMA Copolymers and Their Physical Properties  

Lim, Deok Jum (Dept. of Industrial Chemistry, Pukyoung National University)
Oh, Seung Min (Ulsan Girl's High School)
Kim, Boo Yoon (Det. of Mathematic Education, Pusan National University)
Park, Jae Kyung (Dept. of Nanoengeering, Kyungpook National University)
Kang, Inn-Kyu (Dept. of Polymer Science & Engeneering, Kyungpook National University)
Seo, Kwan-Ho (Dept. of Polymer Science & Engeneering, Kyungpook National University)
Oh, Dae Hee (Ulsan Girl's High School)
Publication Information
Polymer(Korea) / v.38, no.4, 2014 , pp. 535-543 More about this Journal
Abstract
This work, which was about the synthesis of naphthalimidopropyl acrylate and GMA copolymers and their physical properties, investigated the compositions of the copolymer, the reactivity ratios of the monomer, resonance effect (Q), polar effect (e) and fluorescence of naphthalene. Azobisisobutyronitronitryl (AIBN) as an initiator was employed at $60^{\circ}C$ with dimethylformamide (DMF) of solvent for the copolymerization of NIPA. $r_1$ was found to be higher than $r_2$ from the reactivity ratios of the monomer obtained from Fineman-Ross (F-R), Kelen-$T{\ddot{u}}d{\ddot{o}}s$(K-T) methods. NIPA was found to be more copolymerized than GMA. $r_1{\cdot}r_2$ product was lower than 1, copolymerization was maked random-alternating type. The fluorescence spectrum of these polymers showed a weak monomer fluorescence band at 380 nm and a strong excimer fluorescence band at about 460 nm. Fluorescence life time of NIPA monomer showed fluorescence cover with UV 355 nm at room temperature, and life time showed $5.1449{\times}10^{-7}s$.
Keywords
3-(1,8-naphthalimido) propyl acrylate; monomer reactivity ratios; resonance effect (Q); polar effect (e); fluorescence life time;
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