• Title/Summary/Keyword: polar coordination

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Reactions of Metal Catalysts with Polar Vinyl Monomers

  • Jordan Richard F.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.153-154
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    • 2006
  • The development of metal catalysts that can polymerize or copolymerize "polar" $Ch_2=CHX$ monomers by insertion mechanisms would significantly expand the scope of metal-catalyzed polymerization and enable the synthesis of new materials with enhanced properties. We have studied the reactions of single-site olefin polymerization catalysts with vinyl chloride, acrylonitrile, and vinyl ethers, in order to probe monomer coordination trends, insertion rates and regioselectivity, and the structures and reactivity of metal alkyls that contain functional groups on the alpha and beta positions of the alkyl chain. These studies provide insights to the key issues that underlie the "polar monomer" problem. Copolymerization of olefins and selected vinyl ethers has been achieved.

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An Economic Feasibility Study of Manganese Nodule in Korea Area: Clarion-Clipperton Fracture Zone (심해저 망간단괴 개발사업의 경제적 타당성 재평가)

  • Nam, Kwang-Hyun;Oh, Wee-Yeong;Kwon, Suk-Jue
    • Ocean and Polar Research
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    • v.26 no.2
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    • pp.187-197
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    • 2004
  • The purpose of this paper is to investigate economic feasibility of manganese nodules in Korea area (Clarion-Clipperton Fracture Zone). We assumed that the production scale of manganese nodules were 3.0MT or 1.5MT and analyzed that the capital cost and operating cost were estimated in the four sectors, exploration, mining, transportation and metallurgical process. The capital cost and operating cost evaluation reflects the latest technical practices. First, for analyzing economic feasibility, the scenario suggests that the production of 4 metals can be made for 25 years. Assuming the discount rate at 8.0%, equity capital at 50% and tax at 27%. When manganese nodule were mininged 3.0 MT, economic feasibility analyses showed that IRR was 12.8 and pay-back period was 9.2 years, and when manganese nodules were mininged 1.5 MT, economic feasibility analyses showed that IRR was 4.0 and pay-back period was 11.8 years. This study indicated there is economic validity of at the product of manganese nodules 3.0 MT. In addition, we carried out a sensitivity analysis at the change of cobalt price on mining 1.5 MT. The result of sensitivity analysis clearly showed that economic validity is high at increasing of cobalt price 50% up.

A Study on the Application of the Mitigation System for Efficient Management of Coastal Wetlands in Korea -Enhancement of Legal Regime- (연안습지의 효율적 관리를 위한 Mitigation 개념의 한국적 적용방안에 관한 연구 -법제도 개선방안을 중심으로-)

  • Park Seong-Wook;Kwon Moon-Sang;Lee Yong-Hee;Lee Charity Mi-Jin
    • Ocean and Polar Research
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    • v.25 no.4
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    • pp.545-555
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    • 2003
  • It is widely known that compare to many other countries, the U.S.A. has a strong framework for efficient implementation of mitigation policy to protect wetlands. As indicated in many strong mitigation initiatives, mitigation policy primary requires avoidance rule for wetland damage and if a developer inevitability damages wetlands, the development should be minimize, and as a last resort, the policy impose legal duty that a developer should compensate wetland corresponding to the damaged wetlands. However, the legal system fur Korea's mitigation system does not provide any legal duty for the compensatory mitigation, although the possibility of creation of tidal flat is casually expressed in several Korean legal systems. Therefore, without any strong and enforceable legal system, Korean mitigation system cannot efficiently protect Korea's vast and productive wetlands. To introduce mitigation policy similar to the U.S.A. in Korea, we suggest that there (a) should be a strongly policy which regulate legal duty for the compensatory mitigation, (b) should be an improve management system for actively corresponding to special knowledge relating to environment, and lastly, (c) should be a system which consider a class action introduced in environmental regime for a long term protection of tidal wetlands for future generation.

A Study on the Visual Sensibility of Clothing Pattern (의복무늬의 시각적 감성연구)

  • 김윤경;이경희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.6
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    • pp.861-872
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    • 2000
  • The purpose of this study is to objectively explain the visual sensibility of clothing pattern and develop the design of clothing pattern that satisfies the consumer's sensibility. The photos stimuli on clothing pattern are divided into source, presentation, layout and are composed of each 6 photos per chapter totally 48 photos and semantic differential bi-polar scales are consist of 27 couples sensibility words. The subjects were 400 females in the twenties. Data were analyzed by SAS. The major finds were as follows: 1. As a result of the factor analysis, 4 factors of visual sensibility were consist of Coordination, Hardness and Softness, Attention, Rhythm. 2. As to the difference of visual sensibility based on the composition of clothing pattern, there were differences Hardness and Softness, Rhythm by source and there were significant differences among 4 factors by presentation and layout. 3. According to the age and education level, there were significant differences in Attention, Rhythm and according to the consuming areas, there were significant differences in Coordination, Rhythm. 4. According to sensibility positioning, The clothing pattern was classified as soft-hard, simple-complicated. 5. As a result of the regression analysis, preference, consuming desire and satisfaction appears to be closely related. Good quality is related with total clothing image which is brought about composition of clothing pattern.

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Analyzing an Economic Feasibility for Restoration/Creation of Artificial Tidal Flats (인공갯벌 조성에 관한 경제적 타당성 분석)

  • Nam, Kwang-Hyun;Oh, Wee-Yeong
    • Ocean and Polar Research
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    • v.25 no.4
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    • pp.593-601
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    • 2003
  • The purpose of this paper is to investigate economic feasibility of creating artificial tidal flats using cost-benefit analyses. We assumed that the cost factors are associated with designing, construction and monitoring, and the benefit factors are associated with fisheries production, habitation, prevention of disasters, water purification, aesthetic value and existence value. First, for analyzing economic feasibility, the scenario suggests that a design can be made in a year, construction can be completed in three years and monitoring must be made for 20 years. Assuming the discount rate of 7.5%, economic feasibility analyses showed that B/C was 2.26 and IRR was 14.50. This study indicated there is economic validity of implementing creation of artificial tidal flat. In addition, we carried out a sensitivity analysis at the change of discount rate and restoration rate. The result of sensitivity analysis clearly showed that economic validity is low when discount rate is over 15%, and changes in restoration rate did not significantly effect on the economic validity.

A Study on Improvement of Management Framework for Coastal Erosion Protection (연안침식방지를 위한 관리체계 개선방안)

  • Lee, Moon-Suk;Park, Seong-Wook
    • Ocean and Polar Research
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    • v.29 no.2
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    • pp.155-165
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    • 2007
  • Recently, coastal erosion has become an important issue in relation to keeping territorial integrity of a nation as well as protecting the coastal marine ecosystem. This study examines some apprehensions about the effectiveness of the existing legal system concerning prevention of coastal erosion. After examining several case studies in Scotland, the USA, and the Netherlands, this study proposes appropriate revisional legal measures that can be applied in Korea: first, the coastal management act should be revised for stronger, enforceable and practical legal grounds emphasizing minimal coastal erosion; second, the proposed "Comprehensive Coastal Erosion Prevention Plan" should be established and implemented in four steps such as characterization of issues through surveys of stakeholders and demand assessment, plan establishment, execution, and maintenance and management; third, there is a demand to establish and implement a legal framework to support monitoring activities which provide important data and information to prevent coastal erosion; fourth, the chronic region of damage is designated as the "Vulnerable Area" to be protected and managed accordingly; fifth, the "Coastal Coordination council" is established and operated for developing an integrated coastal management policy and visions for sustainable coastal zone, as well as coordinating and intervention of any activities which may cause coastal erosion.

Novel Nickel Catalysts Containing Tetradentate Chelating Ligands for the Polymerization of Norbornene

  • Lee, Dong Hwan;Lee, Jun Yong;Ryu, Ji Young;Kim, Youngmee;Kim, Cheal;Lee, Ik-Mo
    • Bulletin of the Korean Chemical Society
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    • v.27 no.7
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    • pp.1031-1037
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    • 2006
  • New nickel complexes containing novel tetradentate ligands, 4,5-substituted-1,2-bis(pyridine-2-carboxamide)-benzene ligands but lacking alkyl or halide ligands in the coordination sphere have been prepared. They were activated with MMAO (modified methylaluminoxane) to be proven as efficient catalysts for the polymerization of norbornene. Both electron-donating and -withdrawing substituents on the benzene ring and polar solvents enhance the catalytic activity for olefin polymerization. Improvement in thermal stability of the complexes was observed. Some of these complexes were crystallographically determined to have square planar geometry. A plausible mechanism involving dissociation of ligands is proposed.

ROAD MAP OF SOLAR-TERRESTRIAL PROGRAMS IN THE USA

  • POLAND A.I.
    • Journal of The Korean Astronomical Society
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    • v.36 no.spc1
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    • pp.151-154
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    • 2003
  • During the past decade the world solar physics community has made significant progress in understanding the Sun and its interaction with the heliosphere and Earth's magnetosphere. NASA in coordination and cooperation with many other countries has had impressive results with the SOHO, YOHKOH, POLAR, GEOTAIL, etc spacecraft. These successes have given us a sound foundation to proceed into the new century. The two current main efforts in the U.S. are the Solar Terrestrial Probes (STP) and Living With A Star (LWS) programs. The STP program is basically science driven with new missions being selected on the basis of basic science discovery. The LWS program is focused on understanding the basic physics of solar variability and its effects on Earth systems. The current plans for these two programs are discussed.

The Effect of Color Coordination Type on Impression of Male (part I) - Focus on Tone-on-tone Coloration - (컬러코디네이션 기법이 남성 착용자의 인상에 미치는 영향 (제1보) -톤 온 톤 배색을 중심으로-)

  • Lim Ji-Young;Kang Kyung-Ja
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.7 s.155
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    • pp.1012-1024
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    • 2006
  • The purpose of this study is to investigate the effect of color, shirt tone, tie tone, perceiver's gender on impression formation by applying tone on tone coloration of shirt and necktie: coloration of two colors. The experimental materials developed for this study were a set of stimulus and response scales. The stimuli were 32 upper body photographs which were color outputs by CAD system(4D-box program). We unified those colors of shirts and neckties same, then made shirt and necktie tone differently. 27 bi-polar adjectives, each of which was graded into seven in its degree, were used to evaluate the impression. The subjects of this research were 192 male and 192 female college students in Gyeongnam province including Jinju City. The data was analyzed by using SPSS program. Analysis methods were four-way ANOVA. The items of the adjectives were classified into 5 impression dimension. - potency, activity, attractiveness, visibility and tenderness. Color, shirt tone, tie tone, and perceiver gender influenced on 5 impression formation by interaction as well as independently. Blue tie with vivid, light or dull tone had an effect on the formation of potency impression, vivid or light tone of shirt affected activity regardless of color or tie tone. As shirt and tie had different tone, effect on the formation of attractiveness impression, light tone had a negative effect on visibility but positive effect on tenderness. red color were more effective than blue expressed on visibility and tenderness in shirt or tie.