• Title/Summary/Keyword: po

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EO, PO가 부가된 도데실 에테르 황산화물의 계면성 (Interfacial Phenomena of Dodecyl Ether Sulfates Containing Various Ethylene Oxide(EO) and Isopropylene Oxide(PO))

  • 유영창;김상춘;김태영;주명종;남기대
    • 공업화학
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    • 제7권2호
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    • pp.299-307
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    • 1996
  • $10^{-6}{\sim}10^{-3}mol/{\ell}$ 농도범위에서 PO가 먼저 부가된 sodium poly(oxyethylene(EO), oxyisopropylene(PO)) dodecyl ether sulfates의 표면장력은 EO가 부가된 화합물보다 낮게 나왔다. 그리고 대체적으로 일반적인 음이온성계면활성제보다도 낮게 나왔다. PO가 먼저 부가된 화합물에 대하여 Gibbs' 흡착등온선으로 계산한 흡착능(${\Gamma}=2.2{\times}10^{-10}mol/cm^2$)은 EO가 부가된 화합물보다는 높지만 sodium dodecyl ether sulfate(${\Gamma}=3.2{\times}10^{-10}mol/cm^2$)보다는 낮다. 이러한 현상은 PO가 부가된 화합물의 분자량이 크기 때문으로 사료된다. 기포력, n-hexane과 benzene에 대한 유화력, 돼지기름과 소기름에 대한 세정력 그리고 산화철에 대한 분산성은 PO 화합물이 EO 화합물보다 우수하게 나타났다. 이러한 현상들은 친수성과 소수성 부분이 각각 따로 따로 존재할 때 계면활성이 높음을 의미한다. 수계에서 n-hexane과 benzene에 대한 유화력 측정결과는 n-hexane보다 benzene에 대하여 높게 나왔으며, 불규칙적인 분산특성을 나타내었다.

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Fe3(PO4)2 생성에 미치는 침전제와 첨가량의 영향 (Effect of Precipitator and Quantity on the Formation of Fe3(PO4)2)

  • 안석진;이선영;오경환;서동수
    • 한국재료학회지
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    • 제21권11호
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    • pp.587-591
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    • 2011
  • The effect of the precipitator (NaOH, $NH_4OH$) and the amount of the precipitator (150, 200, 250, 300 ml) on the formation of $Fe_3(PO_4)_2$, which is the precursor used for cathode material $LiFePO_4$ in Li-ion rechargeable batteries was investigated by the co-precipitation method. A pure precursor of olivine $LiFePO_4$ was successfully prepared with coprecipitation from an aqueous solution containing trivalent iron ions. The acid solution was prepared by mixing 150 ml $FeSO_4$(1M) and 100 ml $H_3PO_4$(1M). The concentration of the NaOH and $NH_4OH$ solution was 1 M. The reaction temperature (25$^{\circ}C$) and reaction time (30 min) were fixed. Nitrogen gas (500 ml/min) was flowed during the reaction to prevent oxidation of $Fe^{2+}$. Single phase $Fe_3(PO_4)_2$ was formed when 150, 200, 250 and 300 ml NaOH solutions were added and 150, 200 ml $NH_4OH$ solutions were added. However, $Fe_3(PO_4)_2$ and $NH_4FePO_4$ were formed when 250 and 300 ml $NH_4OH$ was added. The morphology of the $Fe_3(PO_4)_2$ changed according to the pH. Plate-like lenticular shaped $Fe_3(PO_4)_2$ formed in the acidic solution below pH 5 and plate-like rhombus shaped $Fe_3(PO_4)_2$ formed around pH 9. For the $NH_4OH$, the pH value after 30 min reaction was higher with the same amount of additions of NaOH and $NH_4OH$. It is believed that the formation mechanism of $Fe_3(PO_4)_2$ is quite different between NaOH and $NH_4OH$. Further investigation on this mechanism is needed. The prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and the pH value was measured by pH-Meter.

흡수경로에 따른 약물동태학적 고찰 (The Study on Pharmacokinetics According to the Administration Route)

  • 박민철;김환영;조은희
    • 한방안이비인후피부과학회지
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    • 제22권3호
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    • pp.95-107
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    • 2009
  • Objective : The purpose of this study is to search for more effective administraion route of herbal medicine. Methods : Pharmacokinetic issues with the methods in experimental papers, which deal with finding the effectiveness of two or more administration routes of herbal medicine, searched from KERIS, KSI, KISTI and KTKP, have been analyzed by, first, categorizing the papers and comparing the validity of administration routes. Results and Conclusions : 1. Upon comparing in total of 24 papers on the basis of each administration route, per oral(PO)-herbal acupuncture(HA) was most superior in terms of number in that there were 13 cases and PO-per rectal(PR) was next superior in that there were 5 cases. PO-per dermal(PD)-inhalation therapy(IT), PO-IT and PO-PR-HA had 3, 2 and 1 cases respectively. 2. Out of the total 24 papers which compares different administration routes, 16 of them were pharmacokinetically appropriate, whereas, the remaining 8 were pharmacokinetically inappropriate. 3. Comparisons were made between PO-HA, PO-PR, PO-IT, PO-PD-IT and PO-PR-HA routes. However, none of them was not particularly effective regardless of the administered medicine or target organ. 4. No route was particularly effective against a particular drug target as a result of comparing damaged liver, asthma, endometriosis and anti-inflammation. 5. In the case of Injinhotang in medicine comparison, HA tended to be more associated with hepatotoxicity over PO. However, Cordyceps Militaris Mycelia, Gagamsohaphyangwon and Hongdeungtang showed no prominent effective administration route.

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다포계 공포의 살미 변천에 관한 연구 - 내외 2출목·내외 3출목 공포를 중심으로 - (A Study on the Transition of Salmi in Dapo Type Kong-Po(拱包) - Focused on Inner and Outer Same Chulmok(出目) -)

  • 이병춘;이호열
    • 건축역사연구
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    • 제22권4호
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    • pp.7-18
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    • 2013
  • Integrated-Salmi can be suggested as a character of Da-po type Kong-po in Korea's traditional architecture. However, only few studies are made on this subject yet. This study is to investigate the integration process of Salmi through cases of certain Kong-po which have the same number of inner and outer Chul-mok and are also known to precede in time. The results of the study are like below. First, Integrated-Salmi is more dominant in inner and outer 3 Chul-mok Kong-po than in inner and outer 2 Chul-mok Kong-po. Second, While inner and outer 2 Chul-mok prevail in Yeong-nam region, inner and outer 3 Chul-mok prevail in Ho-nam region. Third, integrated Salmi of Inner and outer 3 Chul-mok, first appeared in internal Jusangpo to be carried over to internal Juganpo then eventually to outer Salmi. Fourth, the reason why integrated form precede in internal salmi of inner and outer 3 Chul-mok Kong-po is due to 2 main factors. First of which is the impact of integrated Boaji that developed in Da-po type since the early 16th century. The second factor is downward expansion of Cho-gak's Boaji which was adopted to cope with disorders made in structure of Chum-Cha, due to inner and outer 3 Chul-mok type buddhist temples' wide reconstruction throughout Jeolla region following the Japanese invasion of Korea in 1592. This study is to disclose the regularity of development process of Salmi's Cho-gak(草刻) which is a characteristic of Korea's Da-po type Kong-po.

올리빈형 $LiFePO_4$ 분말의 전기전도도와 입도 크기에 미치는 도핑의 영향 (Effects of doping on the electrical conductivity and particle size in olivine type $LiFePO_4$ powders)

  • 백진도;하정수;김창삼
    • 한국결정성장학회지
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    • 제18권6호
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    • pp.248-252
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    • 2008
  • 전기전도성이 우수하면서 입자 크기가 작은 $LiFePO_4$ 분말을 얻기 위해서, 이종원소(Cr+B 또는 Cr+Al) 도핑이 $LiFePO_4$의 전기전도도에 미치는 영향과 열처리 조건이 입자 크기에 미치는 영향에 대해서 조사하였다. 조성이 $LiFe_{0.965}Cr_{0.03}B_{0.005}PO_4$ and $LiFe_{0.065}Cr_{0.03}Al_{0.005}PO_4$인 두 종류의 분말을 기계화학적 밀링법으로 혼합 후 $675{\sim}759^{\circ}C$에서 $5{\sim}10$시간 열처리하여 합성하였다. 이종원소 도핑은 입자성장을 촉진하였고 전기전도도를 높이는 효과가 있었다. $LiFe_{0.065}Cr_{0.03}Al_{0.005}PO_4$의 전기전도도는 $1{\times}10^{-8}S/cm$로 도핑하지 않은 것의 $5{\times}10^{-10}S/cm$보다 높았다.

디젤유/바이오디젤유-열분해유-부탄올 혼합유의 디젤 엔진 적용 가능성에 관한 연구 (A Feasibility Study of Using Diesel/Biodiesel-Pyrolysis Oil-Butanol Blends in a Diesel Engine)

  • 김호승;장영운;이석환;김태영;강건용;윤준규
    • 한국자동차공학회논문집
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    • 제22권5호
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    • pp.116-125
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    • 2014
  • Pyrolysis oil (PO), derived from biomass through fast pyrolysis process have the potential to displace significant amounts of petroleum fuels. The PO derived from wood has been regarded as an alternative fuel to be used in diesel engines. However, the use of PO in a diesel engine is very limited due to its poor properties like low energy density, low cetane number, high acidity and high viscosity of PO. Therefore, one of the easiest way to adopt PO to diesel engine without modifications is blended with other fuels that have high centane number. However, PO that has high amount of polar chemicals is immiscible with non polar hydrocarbons of diesel or biodiesel. Thus, to stabilize a homogeneous phase of diesel/biodiesel-PO blends, a proper surfactant should be used. Nevertheless, PO which was produced from different biomass type have varied characteristics and this complicates the selection of a suitable additive for a specific PO-diesel emulsion. In this regard, a more simple approach such as the use of a co-solvent like ethanol or butanol to induce a more stable phase of the PO-diesel mixture could be a promising alternative. In this study, a diesel engine operated with diesel/biodiesel-PO-butanol blends was experimentally investigated. Performance and gaseous & particle emission characteristics of a diesel engine were examined under the engine loads of IMEP 0.2 ~ 0.8MPa.

우황포용환(牛黃抱龍丸)이 Rat 및 Mouse의 해열(解熱).진통(鎭通) 진경작용(鎭經作用)에 미치는 영향 (Experimental Studies on the Antipyretic, Analgetic, Anticonvulsive effects of the Woo-Whang-Po-Lyong-Whan to Rats and Mice)

  • 원종훈;구본홍
    • 대한한방소아과학회지
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    • 제1권1호
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    • pp.1-12
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    • 1986
  • The Woo-Whang-po-Lyong-Whan has been used as one of the traditional medicines in the field of pediatrics so far since Song dynasty, and still it is widely being used nowadays. It might be considered to be a contribution to do further basic experimental studies on antipyretic, anticonvulsive and analgetic action of the Woo-Whang-po-Lyong-Whan. So it's pharmacological studies were carried out comparing to control drugs. ?Following conclusions were obtained. 1. It's antipyretic action was compared to that of aspirin by Writhing response using acetic acid-method. Mice were given one twentith, one tenth and one fifth tablets of the Woo-Whang-po-Lyong-Whan per Kg of body weight, respecitively. Writhing syndrome frequencies were noted as 38.4 in control group. and $18.0{\pm}12$, $13.17{\pm}2.28$, $7.33{\pm}12$ in above esperimental groups, respectively. In aspirin group it was $18.5{\pm}1.0$ when 2mg aspirin per body weight of mice was given. So it was recognized that antipyretic action of the Woo-Whang-Po-Lyong-Whan become remarkable by increasing amounts of the Woo-Whang-Po-Lyong-Whan. ?2. Antipyretic action in normal temperature mice group was not significant by increasing concentration of the Woo-Whang-Po-Lyong-Whan, but body temperature dropping in normal mice group was slightly noted than control. group, but less temperature dropping was noted than aminopyrin group. ?3. In fever provocated rats groups using Salmonella typhimurium, antipyretic action of the Woo-Whang-Po-Lyong-Whan was not observed significantly than control group. And slight antipyretic action was noted in aminopyrin group. So that antipyretic action of the Woo-Whang-Po-Lyong-Whan was not significant than those of general antipyretic used nowadays, but slower action was recognized. ?4. Anticonvulsive action of the Woo-Whang-Po-Lyong-Whan was studies comparing to that of phenobarbital. Action was not remarkable than phenobarbital, but was significant than control group. No significant intesifying action was noted by increasing amounts of the Woo-Whang-Po- Lyong-Whang.

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수산화 인산칼슘의 합성 (Synthesis of Hydroxycalciumphosphate)

  • Hwang, Young-Gil;Kim, Youn-Soo;Kim, Jae-Il
    • 자원리싸이클링
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    • 제5권3호
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    • pp.50-55
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    • 1996
  • CaO를 $HNO_3$로 용해하여 제조한 (NO$Ca_3$)$_2$용액을 $NH_4$OH로 pH를 조절하고, 상압하의 온도에서 (NH$_4$)$_2$HPO$_4$를 주입시켜서 소정의 시간동안 Ca,,(PO$_4$),(OH)$_2$합성실험을 하였다. Ca,,(PO$_4$),(OH)$_2$는 pH 10~13 범위에서 생성되었고 이 HAP의 입경을 전자현미경으로 조사한 결과 0.1~0.5$mu extrm{m}$이었다. 반응온도는 $40~70^{\circ}C$, 결정화온도 $90^{\circ}C$이며 반응시간은 30분이 적당하였다. 생성된 Ca\ulcorner(PO$_4$)\ulcorner(OH)$_2$$500^{\circ}C$, 1시간동안 하소하여도 변화하지 않으나 80$0^{\circ}C$에서 1시간동안 하소한 시료는 $Ca_3$($PO_4$)$_2$와 HAP, CaO로 변화되었고, 구형의 미립자로 되어 있었다.

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축산폐수에 함유된 ${PO}_4^{3-}$-P의 제거를 위한 폐콘크리트의 재활용에 관한 연구 (A Study on recycling of waste concrete for ${PO}_4^{3-}$-P removal contained in livestock wastewater)

  • 김은호;박진식;성낙창;이영형;신남철;전기일
    • 한국환경과학회지
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    • 제8권2호
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    • pp.227-231
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    • 1999
  • This study was conducted to investigate the removal characteristics of $PO_4^{3-}-P$ contained in livestock wastewater using waste concrete. With small particle size, increased dosage and temperature of water, $PO_4^{3-}-P$ was well removed by waste concrete.$PO_4^{3-}-P$ was removed by adsorption reaction in low pH of the primary phase, but the crystallization reaction predominated for increasing pH with passed time. As a result of adapting the adsorption isotherm equation, $PO_4^{3-}-P$ removal was more affected by the crystallization reaction than the adsorption reaction. In the SEM micrograph, there was no evident change on the waste concreter surface. Particle size was plate-phase before reaction but appeared a dense form to progress in the crystallization reaction.

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신규 참여자의 형평성 향상을 위한 블록체인에서의 새로운 증명 방식 연구: Proof-of-Probability

  • 김성민;김경선;김중헌
    • 정보보호학회지
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    • 제28권3호
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    • pp.18-25
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    • 2018
  • 최근 블록체인 기술을 응용한 가상화폐에 대한 관심이 높아지면서 자본금이 많지 않은 사람들도 블록체인 네트워크에 참여하기 시작했다. 가장 유명한 가상화폐인 비트코인이 채택한 PoW 방식은 고성능 하드웨어의 과열된 열풍을 불어왔고 PoS 방식은 기존 지분이 많은 참여자들이 많이 존재하여 소수의 자본금을 가진 신규 참여자들이 네트워크에 새로 참여하기 어려운 환경이다. 따라서 본 논문에서는 기존 블록체인 증명방식인 PoW, PoS 방식보다 네트워크 참여를 위한 자본금이 적고 신규로 참여하더라도 리스크가 적은 PoP(Proof-of-Probability) 방식을 소개한다. PoP 방식은 블록을 생성할 시 실제 암호화된 해쉬와 수많은 가짜 해쉬를 각 노드들이 정렬하여 진짜 해쉬를 복호화하여 찾은 노드가 블록을 생성하는 방식이다. 또한 1개의 해쉬를 복호화하여 검증받을 때 1분의 대기시간을 두어 과열된 컴퓨팅파워 경쟁을 제한한다. 지분(Stake)이 많을수록 블록을 생성할 확률은 높아지지만 이는 PoS 방식처럼 절대적이지 않다. 이 방식을 이용한다면 지분을 많이 가진 유효성 검증자(Validators)에 의한 집중화를 피하며 블록체인 네트워크에 참여하려는 진입장벽도 낮출 수 있을 것 이다.