• Bulletin of the Korean Chemical Society
• /
• v.26 no.8
• /
• pp.1246-1250
• /
• 2005

We have evaluated the hydroxyl group-solvent specific interactions by using a Lichrosorb RP18 stationary phase and by measuring the retention data of carefully selected solutes in 50/50, 60/40, 70/30, 80/20, and 90/10(v/v%) methanol/water eluents at 25, 30, 35, 40, 45, and 50 ${^{\circ}C}$. The selected solutes are 3 positional isomers of phenylpropanol, that is, 1-phenyl-1-propanol, 1-phenyl-2-propanol, and 3-phenyl-1-propanol. There exist clear discrepancies in ${\Delta}H^o$ (solute transfer enthalpy from the mobile to the stationary phase) and $T{\Delta}S^o$ (solute transfer entropy) among positional isomers. The difference in ${\Delta}H^o$ and $T{\Delta}S^o$ between secondary alcohols (1-phenyl-1-propanol and 1-phenyl-2-propanol)is negligible compared to the difference between the primary alcohol (1-phenyl-3-propanol) and secondary alcohols. The $T{\Delta}S^o$ values of 3-phenyl-1-propanol are close to those of butylbenzene while the $T{\Delta}S^o$ values of secondary alcohols are close to those of propylbenzene. The difference in ${\Delta}{\Delta}H^o$ (specific solute-mobile phase interaction enthalpy) between the primary alcohol and the secondary alcohol decreases with increase of methanol content in the mobile phase. A unique observation is an extremum for 1-phenyl-3-propanol in the plot of $T{\Delta}{\Delta}S^o$ vs. methanol volume %. The positive sign of $T{\Delta}{\Delta}S^o$ of 3-phenyl-1-propanol implies that the entropy of 3-phenyl-1-propanol is greater than that of the hypothetical alkylbenzene (the same size and shape as phenylpropanol) in the mobile phase.

• Journal of Life Science
• /
• v.25 no.4
• /
• pp.369-375
• /
• 2015

Data on the spatial distribution of a plant population among administrative areas is useful for various purposes. In this study, I analyzed the spatial distribution of the geographical distances of Carex siderosticta at Mt. Geumjeong and Mt. Ahop in Korea. The aim was to test a spatial structure within two populations of C. siderosticta. Most natural plots of C. siderosticta are not uniformly distributed in the forest community; for example, uniform plots were aggregately distributed within a space of 6.0 m $\times$ 6.0 m. When the sampling plots were larger than 6.0 m $\times$ 12.0 m, the individuals of C. siderosticta were aggregately distributed. The neighboring patches of C. siderosticta were predominantly 7.5 m to 9.0 m apart, on average; however, if the natural populations were disturbed by human activities, the aggregation occurred in shorter distances than a scale of 9.0 m. Moran's I of C. siderosticta significantly differed from the expected value in only 16 of 40 cases (40%). In conclusion, the geographical distribution of C. siderosticta is not even, with varying degrees of size in the plots, while human activities give rise to density effects in the plots at both Mt. Geumjeong and Mt. Ahop in Korea.

• The Journal of Engineering Geology
• /
• v.25 no.4
• /
• pp.525-532
• /
• 2015

After comparing the effectiveness of standoff compensation between current techniques using data obtained from a series of borehole model experiments for standoff compensation in 2007, 2008, and 2009, a follow-up study was conducted to find a more effective standoff compensation algorithm, Comparing the results of the application of the conventional spine and ribs technique, and the spine and ribs technique in terms of apparent density shows that the standoff compensation error obtained from the latter method is more than twice that obtained from the former. The larger size of the compensation error from the spine and ribs plot using the radioactive decay equation indicates that there are no benefits in using this equation in standoff compensation. Based on these results, we propose a reverse transform spine and ribs technique by essentially combining the conventional spine and ribs technique and the spine and ribs technique in terms of apparent density.

• Journal of the Korean institute of surface engineering
• /
• v.50 no.5
• /
• pp.405-410
• /
• 2017

In order to study current-voltage-luminance and impedance characteristics according to elapsed time, a blue fluorescent OLED was fabricated. The current density and luminance gradually decreased in accordance with elapsed time and did not emit light after 480 hours, and the threshold voltage increased as time elapsed. The Cole-Cole plot was a semicircular shape of a very large size at 2 V of the applied voltage below the threshold voltage, and the maximum value of the real number impedance did not change greatly from 9314.5 to $9902.2{\Omega}$ as time elapsed. Applied voltages 4, 6, and 8 V above the threshold voltage showed a large change in the real number impedance value at the semicircle end to 9,678.2, 9,826, $9,535.4{\Omega}$ according to the elapsed time from 2,222.5, 183.7, $48.2{\Omega}$ immediately after fabricating the device. By increasing the applied voltage beyond the threshold voltage just after device fabrication, the energy difference between the device and the organic layer was overcome and the current flowed, the maximum value of the real number impedance sharply decreased. As time passed, current did not flow through the element even at high applied voltage due to degradation of the element, and even when the applied voltage was higher than the threshold voltage, it showed an impedance value such as applied voltage equal to or less than the threshold voltage. As a result, it can be learned that the change in the impedance with elapsed time reflects the characteristics due to the degradation of the OLED and can predict the characteristics and lifetime of the OLED.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.37 no.1
• /
• pp.105-111
• /
• 2013

The spindle is the main component in machine tools. The static and dynamic characteristics of the spindle directly affect the machining accuracy of workpieces. The characteristics of the spindle depend on the shaft size, bearing span, built-in motor location, and so on. Therefore, the appropriate selection of these parameters is important to improve the spindle characteristics. This paper presents the analysis of the static and dynamic characteristics and optimization design of a 40,000-rpm high-speed spindle. Statistical analysis for optimization and finite element analysis were performed. This study uses the response surface method to optimize the objective function and design factors. The targets are the natural frequency and displacement. The design factors are the shaft length, shaft diameter, bearing span, and motor location. The optimized design provides better results than the initial model, and these results are expected to improve the static and dynamic characteristics of the spindle.

• Advances in nano research
• /
• v.7 no.3
• /
• pp.209-221
• /
• 2019

Graphene, with impressive electronic properties, have high potential in the microelectronic field. However, graphene itself is a zero bandgap material which is not suitable for digital logic gates and its application. Thus, much focus is on graphene nanoribbons (GNRs) that are narrow strips of graphene. During GNRs fabrication process, the occurrence of defects that ultimately change electronic properties of graphene is difficult to avoid. The modelling of GNRs with defects is crucial to study the non-idealities effects. In this work, nearest-neighbor tight-binding (TB) model for GNRs is presented with three main simplifying assumptions. They are utilization of basis function, Hamiltonian operator discretization and plane wave approximation. Two major edges of GNRs, armchair-edged GNRs (AGNRs) and zigzag-edged GNRs (ZGNRs) are explored. With single vacancy (SV) defects, the components within the Hamiltonian operator are transformed due to the disappearance of tight-binding energies around the missing carbon atoms in GNRs. The size of the lattices namely width and length are varied and studied. Non-equilibrium Green's function (NEGF) formalism is employed to obtain the electronics structure namely band structure and density of states (DOS) and all simulation is implemented in MATLAB. The band structure and DOS plot are then compared between pristine and defected GNRs under varying length and width of GNRs. It is revealed that there are clear distinctions between band structure, numerical DOS and Green's function DOS of pristine and defective GNRs.

• Advances in materials Research
• /
• v.11 no.3
• /
• pp.225-235
• /
• 2022

It includes the synthesis of pristine ZnO nanoparticles and a series of Ag-doped zinc oxide nanoparticles was carried out by reflux method by varying the amount of silver (1, 3, 5, 7 and 9% by mol.). The morphology of these nanoparticles was investigated by SEM, XRD and FT-IR techniques. These techniques show that synthesized particles are homogenous spherical nanoparticles having an average particle size of about 50-100 nm along with some agglomeration. The photocatalytic activity of the ZnO nanoparticles and Ag doped ZnO nanoparticles were investigated via photodegradation of methylene blue (MB) as a standard dye. The data from the photocatalytic activity of these nanoparticles show that 7% Ag-doped ZnO nanoparticles exhibit much enhanced photocatalytic activity as compared to pristine ZnO nanoparticles and other percentages of Ag-doped ZnO nanoparticles. Furthermore, 7% Ag-doped ZnO was made composites with sulfur-doped graphitic carbon nitride by physical mixing method and a series of nanocomposites were made (3.5, 7.5, 25, 50, 75% by weight). It was observed that the 25% composites exhibited better photocatalytic performance than pristine S-g-C 3 N 4 and pure 7% Ag-doped ZnO. Tauc's plot also supports the photodegradation results.

• Food Science of Animal Resources
• /
• v.42 no.2
• /
• pp.280-294
• /
• 2022

This study aimed to evaluate the effectiveness of propolis extract as a natural preservative for livestock products in term of chemical and microbiological characteristics by meta-analysis. The stages carried out in this study were identification, selection, checking suitability, and the resulting selected articles were used in the meta-analysis. The selection results obtained a total of 22 selected journal articles consisting of 9 articles for analysis of the antimicrobial activity of propolis extract and 13 articles for analysis of the chemical and mirobiological characteristics of livestock products. The articles were obtained from electronic databases, namely Science Direct and Google Scholar. The model used in this study is the random-effect model involving two groups, control and experimental. Heterogeneity and effect size values were carried out in this study using Hedge's obtained through openMEE software. Forest plot tests and data validation on publication bias was obtained using Kendall's test throught JASP 0.14.1 software. The results showed that there is a significant relationship between propolis extract with the results of the antimicrobial activity (p<0.05). In addition, the results of the application of propolis extract on the livestock products for the test microbes and the value of thiobarbituric acid reactive substances (TBARs) showed significant results (p<0.05). Conclusion based on the random-effect model on the effectiveness of antimicrobial activity of propolis extract and their apllication as a natural preservative of the chemical and microbiological characteristics of livestock products is valid by Kendall's test (p>0.05). Propolis in this case effectively used as natural preservatives in livestock products.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.28 no.2A
• /
• pp.197-205
• /
• 2008

In order to estimate mean wind speed in the Gwangyang-Myodo Region, the probability distribution model of extreme values has been used in the statistical analysis of joint distribution probability of daily maximum wind speed and corresponding direction in this paper. For this purpose frequency of daily maximum records at respective stations is inquired into and sample of largest yearly wind speed of sixteen compass direction and non-direction is extracted from daily data of maximum wind speed and appropriate direction of the meteorological observing stations nearby the bridge construction site. These extreme speed records are applied to Gumbel and Weibull distribution model and parameters are estimated through method of moment and method of least squares etc. And also, distribution and parameters are inquired into whether it is fitted through the probability plot correlation coefficient examination. From fitted parameters the largest yearly wind speed of sixteen compass direction and non-direction is extrapolated taking into account factors regarding sample size of data and distance from the bridge construction site according to the appropriate stations.

• Proceedings of the Korean Society of Crop Science Conference
• /
• 2022.10a
• /
• pp.75-75
• /
• 2022

Traditional agriculture mostly focused on activity in the field, but current agriculture faces problems such as reduction of agricultural inputs, labor shortage and so on. Accordingly, traditional agricultural experiments generally considered the simple treatment effects, but current agricultural experiments need to consider the several and complicate treatment effects. To analyze such several and complicate treatment effects, data collection has the first priority. Remote sensing is a quite effective tool to collect information in agriculture, and recent easier availability of UAVs (Unmanned Aerial Vehicles) enhances the effectiveness. LAI (Leaf Area Index) is one of the most important information for evaluating the condition of crop growth. In this study, we utilized UAV with multispectral camera to evaluate plant-based LAI of sweetcorn in a small-scale field experiment and discussed the feasibility of a new experimental design to analyze the several and complicate treatment effects. The plant-based SR measured by UAV showed the highest correlation coefficient with LAI measured by a canopy analyzer in 2018 and 2019. Application of linear mix model showed that plant-based SR data had higher detection power due to its huge number of data although SR was inferior to evaluate LAI than the canopy analyzer. The distribution of plant-based data also statistically revealed the border effect in treatment plots in the traditional experimental design. These results suggest that remote sensing with UAVs has the advantage even in a small-scale experimental plot and has a possibility to provide a new experimental design if combined with various analytical applications such as plant size, shape, and color.