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Quantum Confinement Effect Induced by Thermal Treatment of CdSe Adsorbed on $TiO_2$ Nanostructure

  • Lee, Jin-Wook;Im, Jeong-Hyeok;Park, Nam-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.213-213
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    • 2012
  • It has been known that quantum confinement effect of CdSe nanocrystal was observed by increasing the number of deposition cycle using successive ionic layer adsorption and reaction (SILAR) method. Here, we report on thermally-induced quantum confinement effect of CdSe at the given cycle number using spin-coating technology. A cation precursor solution containing $0.3\;M\;Cd(NO_3)_2{\cdot}4H_2O$ is spun onto a $TiO_2$ nanoparticulate film, which is followed by spinning an anion precursor solution containing $0.3\;M\;Na_2\;SeSO_3$ to complete one cycle. The cycle is repeated up to 10 cycles, where the spin-coated $TiO_2$ film at each cycle is heated at temperature ranging from $100^{\circ}C$ to $250^{\circ}C$. The CdSe-sensitized $TiO_2$ nanostructured film is contacted with polysulfide redox electrolyte to construct photoelectrochemical solar cell. Photovoltaic performance is significantly dependent on the heat-treatment temperature. Incident photon-to-current conversion efficiency (IPCE) increases with increasing temperature, where the onset of the absorption increases from 600 nm for the $100^{\circ}C$- to 700 nm for the $150^{\circ}C$- and to 800 nm for the $200^{\circ}C$- and the $250^{\circ}C$-heat treatment. This is an indicative of quantum size effect. According to Tauc plot, the band gap energy decreases from 2.09 eV to 1.93 eV and to 1.76 eV as the temperature increases from $100^{\circ}C$ to $150^{\circ}C$ and to $200^{\circ}C$ (also $250^{\circ}C$), respectively. In addition, the size of CdSe increases gradually from 4.4 nm to 12.8 nm as the temperature increases from $100^{\circ}C$ to $250^{\circ}C$. From the differential thermogravimetric analysis, the increased size in CdSe by increasing the temperature at the same deposition condition is found to be attributed to the increase in energy for crystallization with $dH=240cal/^{\circ}C$. Due to the thermally induced quantum confinement effect, the conversion efficiency is substantially improved from 0.48% to 1.8% with increasing the heat-treatment temperature from $100^{\circ}C$ to $200^{\circ}C$.

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EFFECTS OF INTERCROPPING, SEEDLING RATE AND FERTILIZER ON FODDER PRODUCTION IN THE LOW LYING AREA OF BANGLADESH

  • Sarker, N.R.;Giasuddin, M.;Islam, M.M.;Rahman, M.M.;Yasmin, L.
    • Asian-Australasian Journal of Animal Sciences
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    • v.7 no.1
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    • pp.57-61
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    • 1994
  • The study was conducted at low lying areas in Pabna Sirajgong districts of Bangladesh. To observe the potentiality of bio-mass production two trials were conducted. In first trial maize intercropped with Khesari taking 15 experimental plots of each size $5m{\times}5m$ were arranged in 5 blocks having homogenous soil characteristics. The study showed that the bio-mass yield of sole maize and sole Khesari were 35.25 t/ha. and 56.80 t/ha. respectively and there was a significant difference (p < 0.01) among them. The results also showed that bio-mass yield of maize and Kherasi was higher ($70.04{\pm}6.25t/ha$, $98.88{\pm}10.77t/ha$ and $80.56{\pm}9.5t/ha$) compared to sole maize and sole Khesari and land equivalent ratio was also lower. For second trial, one hectare of land was divided into 16 experimental plots with 4 replications in each plot. Four levels of urea (0 kg/ha, 30 kg/ha, 45 kg/ha, and 60 kg/ha.) were applied to experimental plot. The seed rates were 98.8 kg/ha (farmer's practice), 86.45 kg/ha, 74.1 kg/ha and 61.75 kg/ha. average bio-mass yield of matikalai at different seed rates along with urea fertilizer ranged from 38.49 t/ha, to 65.35 t/ha. the highest seed rate along with highest fertilizer also correspond to the peak production (65.35 t/ha) and the lowest seed rate (61.75 kg/ha) along with the lowest fertilizer rate (30 kg/ha.) showed lowest production (38.49 t/ha.). Here, it was found that the bio-mass yield of matikalai increased with the incremental amount of seed, indicating significant effect (p < 0.05) of seed rates on the bio-mass yield of matikalai. On the other hand, fertilizer doses in different treatment combinations had significant effect (p < 0.05) on bio-mass yield. Two levels of seed rates at zero level of fertilizer were recommended : 86.45 kg/ha for the resource rich farmers and 61.75 kg/ha for the resource poor farmers.

Sensing NO3-N and K Ions in Hydroponic Solution Using Ion-Selective Membranes (이온선택성 멤브레인을 이용한 양액 내 질산태 질소 및 칼륨 측정)

  • Kim, Won-Kyung;Park, Tu-San;Kim, Young-Joo;Roh, Mi-Young;Cho, Seong-In;Kim, Hak-Jin
    • Journal of Biosystems Engineering
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    • v.35 no.5
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    • pp.343-349
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    • 2010
  • Rapid on-site sensing of nitrate-nitrogen and potassium ions in hydroponic solution would increase the efficiency of nutrient use for greenhouse crops cultivated in closed hydroponic systems while reducing the potential for environmental pollution in water and soil. Ion-selective electrodes (ISEs) are a promising approach because of their small size, rapid response, and the ability to directly measure the analyte. The capabilities of the ISEs for sensing nitrate and potassium in hydroponic solution can be affected by the presence of other ions such as calcium, magnesium, sulfate, sodium, and chloride in the solution itself. This study was conducted to investigate the applicability of two ISEs consisting of TDDA-NPOE and valinomycin-DOS PVC membranes for quantitative determinations of $NO_3$-N and K in hydroponic solution. Nine hydroponic solutions were prepared by diluting highly concentrated paprika hydroponic solution to provide a concentration range of 3 to 400 mg/L for $NO_3$-N and K. Two of the calibration curves relating membrane response and nutrient concentration provided coefficients of determination ($R^2$) > 0.98 and standard errors of calibration (SEC) of < 3.79 mV. The use of the direct potentiometry method, in conjunction with an one-point EMF compensation technique, was feasible for measuring $NO_3$-N and K in paprika hydroponic solution due to almost 1:1 relationships and high coefficients of determination ($R^2$ > 0.97) between the levels of $NO_3$-N and K obtained with the ion-selective electrodes and standard instruments. However, even though there were strong linear relationships ($R^2$ > 0.94) between the $NO_3$-N and K concentrations determined by the Gran's plot-based multiple standard addition method and by standard instruments, hydroponic $NO_3$-N concentrations measured with the ISEs, on average, were about 10% higher than those obtained with the automated analyzer whereas the K ISE predicted about 59% lower K than did the ICP spectrometer, probably due to no compensation for a difference between actual and expected concentrations of standard solutions directly prepared.

The Effect of Self-Management Intervention for Reducing Depression and Anxiety in Osteoarthritis Patients : A Meta-analysis (골관절염 환자의 우울과 불안 감소를 위한 자가관리중재의 효과: 메타분석)

  • Lee, Chun-Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.2
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    • pp.94-102
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    • 2020
  • This study conducted a meta-analysis of the effects of self-management intervention for reducing the depression and anxiety of osteoarthritis patients. The research sources were PubMed, EMBASE, CINAHL, Ovid-MEDLINE and Korean databases from the Korean and foreign literature published until September 30, 2019. The R version 3.5.1 program was used to identify the effectiveness of self-management intervention. As a result, 11 studies from a total of 1,877 articles in the relevant literature were analyzed, and the total number of participants was 2,751. The results showed that the overall effect size for reducing depression and anxiety was -0.44 (95% CI: -0.66, -0.22) in osteoarthritis patients (p <.001). On the sub-analysis, depression was -0.37 (95% CI: -0.66, -0.08), and anxiety was -0.56 (95% CI: -0.92, -0.20). To explain the heterogeneity, the meta-ANOVA was the setting, duration, and provider of intervention. Analysis of the publication bias was performed by a Funnel plot, which was visually relatively symmetrical and was not asymmetric according to Egger's Regression test (bias=0.19, p=.928). The results of this study established clinical evidence by identifying the effects of self-management intervention for reducing the depression and anxiety of osteoarthritis patients.

Forest Structure of the Hwaomsa Valley and the Piagol Valley in the Chirisan National Park -Forest Community Analysis by the Classification and Ordination Techniques- (지리산국립공원 화엄사계곡 및 피아골계곡의 삼림군집구조에 관한 연구 -Classification 및 Ordination 방법에 의한 식생분석 -)

  • Park, In-Hyeop;Choi, Young-Cheol;Cho, Woo
    • Korean Journal of Environment and Ecology
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    • v.5 no.1
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    • pp.42-53
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    • 1991
  • The Hwaomsa valley forest and the Piagol valley rarest in Mt. Chiri were studied to investigate forest structure and succession. Thirty plots in the Hwaomsa valley forest and thirty-nine plots in the Piagol valley forest were set up, and vegetation analysis of TWINSPAN classification and DCA ordination was carried out. The size of each plot was 20m $\times$ 25m, and the trees above 2cm DBH in each plot were measured. The Hwaomsa valley forest and the Piagol valley forest were classified into four communities and three communities by the altitude, respectively. The successional trends of major tree species seem to be from Pinus densiflora and Quercus mangalica through Quercus serrata to Carpinus spp. in the Hwaomsa valley forest. and from Quercus mongalica through Quercus serrata to Carpinus Spp. in the Piagol valley forest. The Hwaomsa valley is assumed to be interfered by the man more, and develop into the climax less than the Piagol rarest.

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Photosynthesis and Regrowth of Leaf in Sorghum-Sudangrass Hybrid, Pearl Millet, and Barnyard Millet after 2nd Cutting (청예용 수수-수단 그라스 잡종, 진주조, 사료용 피의 후기 생육에서 재생엽의 생장과 광합성)

  • 이호진;김태훈
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.38 no.5
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    • pp.466-476
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    • 1993
  • Field experiment was carried out to study the new and old leaf development and photosynthesis of sorghum-sudangrass hybrid 855F, pearl millet Suwon No.6 and barnyard millet in cutting and non-cutting plots from the 2nd cutting day(September, 17th). Leaf regrowth of sorghum-sudangrass hybrid and pearl millet begun after the 2nd cutting day, except barnyard millet. Photosynthetic rate of new leaf blades in cutting plots reached to higher level than old leaf at 12th to 20th day after cutting(DAC). Stomatal density of leaf blade of each crop in non-cutting plot was observed higher pearl millet and sorghum-sudangrass hybrid than barnyard millet. New leaf blade of each crop in cutting plot was showed complete development in stomata size, form and vascular bundles in 12th DAC. Non-structural carbohydrates(NSC) contents of stembase in sorghum-sudan hybrid which had 17 %, the highest among three forages decreased daily into 8th DAC and begun to increase from 20th DAC. But, those of pearl millet and barnyard millet in cutting plots were about 10 % at cutting day and inclined to decrease continuously into the 20th DAC and reached about 3~4% in 32nd DAC. These results showed that regrowth energy of sorghum-sudangrass hybrid was mainly dependent on non-structural carbohydrates of stembase until 12th DAC, but pearl millet had active lower leaves supported its regrowth by concurrent photosynthesis. As barnyard millet which did not reserve enough NSC, its regrowth fail to survive under low temperature. Also, late regrowth of rest two forage crops was delayed with decreasing daily temperature after mid-September.

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Habitat Environment and Vegetation Structure of Forest Communities Growing Schisandra nigra Maxim. in Cheju Island of Korea (흑오미자 자생 임분의 입지환경과 식생구조)

  • Lee Kab-Yeon;Kim Sea-Hyun;Kim Pan-Gi;Shin Chang-Ho;Han Sang-Sup
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.1 no.2
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    • pp.81-89
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    • 1999
  • To propose basic information for natural resource management and conservation strategy of Schisan-dra nigra Maxim., its habitat environment and vegetation structure of forest communities growing the species was investigated. Fourteen plots (each plot size 400 $m^2$) were set up at the distributed area of Cheju island, southern part of Korea. S. nigra is the economic useful species that scatteringly grows at 850~920 m in the western part, at 660~710 m in the northern part and at 750~1,250 m in the southern part of Mt. Halla. The community of S. nigra in Mt. Halla is the mixed secondary forest of pine and broad leaved trees that are mainly composed of Pinus densif1ora, Quercus serrata, Styrax japonica, Lin-dera erythrocarpa and Carpinus laxiflora. The density in a main distribution sector of S. nigra appears in the range of 3~39 individuals per each 20$\times$20 m plot. The distribution patterns by Morisita's Index showed that S. nigra was distributed randomly in all of the stands. The association analysis showed that the following tree species were positively associated with S. nigra. In other words, the following trees were appeared to require the same ecological niche together with S. nigra: Lindera erythrocarpa, Cornus waltri, Acer mono, and Styrax japonica.

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Development of Nurserγ Soil for Rice Seedling (Phyllite를 이용한 수도용(水稻用) 육묘(育苗) 상토개발(床土開發))

  • Park, Young-Hee;Chang, Ki-Woon;Hong, Jei-Gu
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.2
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    • pp.71-81
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    • 2002
  • The study was carried out to develop nursery soil for rice seedling of phyllite. First of all, physico-chemical properties of used phyllite in the study through the analysis for agricultural utilization evaluation are as following. Bulk density(BD) of phyllite was $1.31g/cm^3$ each other and porosity had 65% of entire pore size. Also, the water holding capacity(WHC) was 43% at 1/3bar pressure, which phyllite has high WHC. According to, the results the experiments for nursery soil were conducted by mixing the materials such as phyllite, zeolite and hill soil. The mixing ratios were 30, 50, and 70% for zeolite and hill soil into phyllite. These mixed materials were packed in a box by adding 0, 1 and 2g of N-fertilizer. At seedling test, there were increases in the growth of shoot and root of rice for phyllite to zeolite and phyllite to hill soil, respectively. On the other hand, the length of leaf increased with increasing application rate of phyllite, while length and a number of root increased with increasing application rate of hill soil. The growth in the plots of phyllite to zeolite and phyllite to hill soil was better than in control plot. Finally, phyllite plot had efficient results when it compared with others and the study used with phyllite will have to more research and effort for agricultural useful material.

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Usefulness and Limitations of Extreme Value Theory VAR model : The Korean Stock Market (극한치이론을 이용한 VAR 추정치의 유용성과 한계 - 우리나라 주식시장을 중심으로 -)

  • Kim, Kyu-Hyong;Lee, Joon-Haeng
    • The Korean Journal of Financial Management
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    • v.22 no.1
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    • pp.119-146
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    • 2005
  • This study applies extreme value theory to get extreme value-VAR for Korean Stock market and showed the usefulness of the approach. Block maxima model and POT model were used as extreme value models and tested which model was more appropriate through back testing. It was shown that the block maxima model was unstable as the variation of the estimate was very large depending on the confidence level and the magnitude of the estimates depended largely on the block size. This shows that block maxima model was not appropriate for Korean Stock market. On the other hand POT model was relatively stable even though extreme value VAR depended on the selection of the critical value. Back test also showed VAR showed a better result than delta VAR above 97.5% confidence level. POT model performs better the higher the confidence level, which suggests that POT model is useful as a risk management tool especially for VAR estimates with a confidence level higher than 99%. This study picks up the right tail and left tail of the return distribution and estimates the EVT-VAR for each, which reflects the asymmetry of the return distribution of the Korean Stock market.

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Effects of an Abdominal Obesity Management Program on Physiological Bio-markers of Middle-aged Women in Korea: A Meta-analysis (국내 중년기 비만 여성의 생리적 지표에 대한 복부비만관리프로그램의 효과: 메타분석)

  • Kim, KyengJin;Hong, HaeSook;Park, WanJu;Ko, SangJin;Na, YeonKyung
    • Journal of Obesity & Metabolic Syndrome
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    • v.25 no.3
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    • pp.138-148
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    • 2016
  • Background: The purpose of this study is to analyze the effects of an abdominal obesity management program in middle-aged women in Korea. Methods: Examination of databases, including the Research Information Sharing Service, Database Periodical Information Academic, and Korean Studies Information, resulted in identification of 772 studies performed up to 2014, of which 43 satisfied the inclusion data. Data analysis was performed using R version 3.2 to calculate the effect sizes, explore possible causes of heterogeneity, and check for publication bias, using a funnel plot and its trim-and-fill analysis. Results: The mean effect size of the management program was small (g=0.22), along with the anthropometric index (g=0.18), metabolism index (g=0.21), fat-distribution (g=0.36), and inflammatory index (g=0.36). Moderator analysis was performed to determine heterogeneity, but no significant differences were found between the randomized controlled trial (RCT) group and non-RCT group. In addition, the length of the session was found to be statistically significant after performing a meta-regression. Finally, a funnel plot with a trim-and-fill analysis was produced to check for publication bias, but no significant bias was detected. Conclusion: Based on these findings, the abdominal obesity management program affects middle-aged women in Korea. Further research is needed to target other age groups with abdominal obesity.