• Title/Summary/Keyword: plasticizer

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Strength Development of Low Heat Portland Cement Concrete in High Strength Range (저열 포틀랜드 시멘트 콘크리트의 고강도 영역에서의 강도발현 특성)

  • Ha Jae Dam;Um Tai Sun;Lee Jong Ryul;Kwon Young Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.353-356
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    • 2005
  • Strength development of low heat portland cement(Type IV) concrete in high strength range is tested. In this study strength development according to water-binder ratio, strength development according to age, effect of fly ash and super plasticizer are tested. This study tests effect of low heat portland cement in high strength range concrete and provide guide line concrete mix design for later study and/or construction.

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A Study on the Improvement in Impact Resistance and Thermal Stability of Microbial Polyester by Biodegradable Plasticizer (생분해성 가소제에 의한 미생물 폴리에스테르의 내충격성 및 열안정성 증진에 대한 연구)

  • 최재신;김소현;이택승;박원호
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.199-202
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    • 2001
  • 현재 플라스틱에 의한 환경오염이 사회문제로까지 확대되면서 이를 해결하기 위한 한가지 대책으로 분해성 플라스틱의 개발이 절실히 요구되어 전세계적으로 많은 연구가 이루어지고 있다. 생분해성을 가지는 미생물 폴리에스테르 중에서 가장 대표적인 poly(3-hydroxybutyrate), PHB는 우수한 역학적 성질을 가지며, 또한 천연고분자 중에서 융점을 가지는 유일한 열가소성 재료이다. (중략)

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A Study of Plasticizer in Food and Drug PVC Packaging (PVC포장재에 사용된 가소제에 관한 조사연구)

  • Yoon Mi-Hye;Eom Mi-Na;Do Young-Sook;Jung Hong-Rae;Jeong Il-Heoung;Ko Hoan-Uck;Son Jin-Seok
    • Journal of environmental and Sanitary engineering
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    • v.20 no.2 s.56
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    • pp.39-46
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    • 2005
  • This study was Performed to survey and evaluate the contents of Plasticizers such as DEP(diethyl phthalate), DPrP(di-n-Phthalate), DBP(di-n-butyl Phthalate), DPP(di-n-pentyl Phthalate), DCHP(dicyclohexyl phthalate), BBP (butylbenzyl phthalate), DEHP(di-(2-ethylhexyl) phthalate) and DEHA(di-(2-ethylheryl) adipate), which are suspected as endocrine disruptors, in food and drug PVC packaging. Tested samples were 5 food wraps, 35 food containers, 40 food and drug packages(type of tablet and capsule) in Gyeonggi-Do area. The contents of DEHA in wrap were 188.9g/kg, 203.1g/kg, 238.4g/kg, 290.9g/kg and 308.3g/kg, respectively, while the other plasticizers were not detected. DEHP was used in 4 samples of food containers and DEHP contents were 4.7g/kg, 30.7g/kg, 35.8g/kg and 53.4g/kg, respectively. In food and drug packaging materials(type of tablet and capsule), the plasticizers were not detected.

Plastic Shrinkage Cracking Reduction of Press Concrete Using Admixtures in Basement (주차장바닥에서 혼화재료들을 사용한 누름콘크리트의 소성수축 균열저감)

  • Kim, Young-Su;Lee, Dong-Un
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.11
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    • pp.416-424
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    • 2019
  • In Korea, press concrete in basements is mainly applied using plain concrete. This system has undesirable defects such as cracks caused by plastic shrinkage and irregular temperature distribution. To solve this problem, metal lath and fibers have been used in the past. However, they have not been effective in controlling cracks. This study analyzed the reduction of plastic shrinkage cracking for press concrete using various admixtures in a basement has been. In the air contents test, the specimens with various admixtures showed air contents similar to plain concrete (4.5±1.5%). The specimens using silica fume, super plasticizer agent, and SBR showed higher compressive strength by about 10-15% than plain concrete. Cracking decreased when the MC, super plasticizer, and SBR were added. When MC was used in the concrete, the plastic shrinkage did not occur.

Enhanced Controlled Transdermal Delivery of Hydrochlorothiazide from an Ethylene-vinyl Acetate Matrix

  • Kim, Dal-Keun;Park, Jung-Chan;Chang, Ik-Hyun;Kang, Chung;Ryu, Sang-Rok;Shin, Sang-Chul
    • Journal of Pharmaceutical Investigation
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    • v.40 no.3
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    • pp.167-173
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    • 2010
  • Repeated oral administration of hydrochlorothiazide, a loop diuretic, due to transient high blood levels, may cause adverse effects such as gastric disturbance, nausea, high blood sugar, and hyper lipidemia. Transdermal administration could avoid some of these systemic side effects and gastric disorders. We have developed a matrix using ethylene-vinyl acetate (EVA), a heat-processible and flexible material, for transdermal delivery of hydrochlorothiazide. Drug solubility was highest at 40% PEG-400 volume fraction. Drug release increased as concentration increased with a linear relationship between the release rate and the square root of loading dose. Increasing temperature increased drug release from the EVA matrix. The activation energy, measured from the slope of log P versus 1000/T, was 11.9 kcal/mol for a 2.5% loading dose from EVA matrix. Diethyl phthalate had the highest plasticizing effects on the release of hydrochlorothiazide. To increase the skin permeation of hydrochlorothiazide from the EVA matrix, enhancers such as the saturated fatty acids, the unsaturated fatty acids, and the non-ionic surfactants were added to the EVA matrix, and skin permeation was evaluated using a modified Keshary-Chien diffusion cell fitted with intact excised rat skin. Polyoxyethylene 23-lauryl ether showed the highest enhancing effects. In conclusion, transdermal delivery of hydrochlorothiazide could be improved from an EVA matrix containing plasticizer and permeation enhancer.

Complex Modulus of Alumina Green Tapes Measured by Micro Fourier Rheometer (Micro Fourier Rheometer에 의한 알루미나 그린 테이프의 Complex Modulus 측정)

  • ;;;;Michael V. Swain;Bruno Pfister
    • Journal of the Korean Ceramic Society
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    • v.36 no.2
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    • pp.122-129
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    • 1999
  • Alumina tapes, having various weight ratios of alumina powder/(alumina+binder+plasticizer), X, and binder / (binder+plsticizer), Y, were prepared and their complex modulus was measured using Micro Fourier Rheometer. As the X and Y ratios increased, Transfer function(TF) magnitude and Transfer function (TF) phase increased and decreased, respectively, indicating that the elastic modulus of the tapes depends on the weight ratios. The temperature dependence of the viscosity of the tapes was visualized by the decreased TF magnitude and the increased TF phase. The Y ratio dependence of the complex modulus related to the glass transition temperature of the tapes and the moduls change by the Y ratio was higher than that by the X ratio within the comperature of the tapes and the modulus changes by the Y ratio was higher than that by the X ratio within the composition range, investigated in the present study. The measurement of the complex modulus of the alumina tapes suggested that the TF phase should be higher that 17$^{\circ}$for the tapes to be utilized for 3-dimensional shaping.

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Fabrication of Transparent Dielectric Green Sheet for Plasma Display Panel (PDP 투명유전체 형성용 Green Sheet 제조)

  • Heo, Sung-Cheol;Park, Duck-Kyun;Oh, Young-Jei
    • Journal of the Korean Ceramic Society
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    • v.41 no.4
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    • pp.277-283
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    • 2004
  • To fabricate green sheet of transparent dielectric for PDP front panel, dispersion of transparent dielectric slurry, density, and mechanical properties of green sheets have been investigated as a function of amount and composition of organic additives. Measurements of sedimentation and viscosity were employed to determine a proper dispersant and its amount for a well dispersed transparent dielectric powders in non-aqueous system. Green sheets, having various ratios of transparent dielectric powders to transparent dielectric powders+ binder+plasticizer and binder to binder+plasticizer, were fabricated. All the tape casting slurries showed shear thinning effect, that is, the apparent viscosity decreased with the increase of shear rate. It was found that the amount and composition of organic additives were main variables to affect densities and mechanical properties of transparent dielectric green sheets for PDP.

LTCC Tape Characterization as Organic formulation (유기물 조성에 따른 LTCC 테입 특성 연구)

  • Lim, W.;Kang, B.H.;Yoo, Y.S.;Lee, Y.S.;Cho, H.M.;Lee, W.S.;Kang, N.K.
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2000.11a
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    • pp.89-92
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    • 2000
  • Non-aqueous tape casting of LTCC with PVB binder has been studied in a continuous tape casting machine. The aim of the study was to evaluate this type of system in the different Binder/Plasticizer and solid content compositions. Each four slurry compositions were used in the experiments with varied binder/plasticizer and solid content. All the slurries gave good quality tapes with smooth surfaces without blisters or pinholes. The highest mechanical properties was obtained for the B/P=3.0, powder content 70vol% composition from 52 ${\mu}{\textrm}{m}$ green tapes, a tensile strength of 4.6 MPa and a linear extension of 29.5%

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Altered Gene Profiles using KISTCHIP-400 in MCF-7 cells after Exposure to Di(2-ethylhexyl) Phthalate (DEHP) and Dibutyl Phthalate (DBP)

  • Yun, Hye-Jung;Kim, Youn-Jung;Kim, Eun-Young;Ryu, Jae-Chun
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.10a
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    • pp.174-174
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    • 2003
  • There are many synthetic chemicals, such as di(2-ethylhexyl) phthalate (DEHP) and dibutyl phthalate (DBP), used in chemical reaction processes in industry. The establishment of toxicity and detection of synthetic chemicals that may pose a genetic hazard in our enviornment is subjects of great concern at present DEHP, a ubiquitous phthalate plasticizer, induces a wide range of developmental and reproductive toxicities in mammals. DEHP belongs to the large diverse class of peroxisome proliferator compounds, which include herbicides, hypolipidemic drugs. DBP is a plasticizer used to products containing nitrocellulose, polyvinyl acetate, and polyvinyl chloride such as food wraps and blood bags. DBP is also used in cosmetics as a solvent and fixative for perfumes, a suspension agent for solids, an antifoamer, a skin emollient, and hair spray The present study was performed to examine patterns of gene expression in MCF-7 cells following DEHP and DBP exposure. Changes in gene expression were determined by microarray analysis using KISTCHIP-400 including 401 endocrine related genes based on public database and research papers. Of the genes analysis, we determined that genes detected by array showed a 2-fold or greater change in their expression level(increase or decrease). The results of this study demonstrate that a number of genes were differentially expressed in MCF-7 cells but these changes were not significant. Therefore, we keep going this study using microarray analysis and future studies will examine changes of gene expression on time-course and does treatment in variable cell lines.

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