• Title/Summary/Keyword: plasma source ion implantation

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Investigation of Adhesion Mechanism at the Metal-Organic Interface Modified by Plasma - Part I

  • Sun, Yong-Bin
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2002.11a
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    • pp.123-126
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    • 2002
  • For the mold die sticking mechanism, the major explanation is that EMC filler of silica wears die surface roughened, which results in increase of adhesion strength. As big differences in experimental results from semiconductor manufacturers are dependent on EMC models, however, chemisorptions or acid-base interaction is apt to be also functioning as major mechanisms. In this investigation, the plasma source ion implantation (PSII) using $O_2$, $N_2$, and $CF_4$ modifies sample surface to form a new dense layer and improve surface hardness, and change metal surface condition from hydrophilic to hydrophobic and vice versa. Through surface energy quantification by measuring contact angle and surface ion coupling state analysis by Auger, major governing mechanism for sticking issue was figured out to be a complex of mechanical and chemical factors.

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Magnetic Properties and Production of Fe-N Phases by Plasma Source Ion Implantation (플라즈마 이온주입 방법에 의한 질화철 제조 및 자기적 성질)

  • 김정기;김곤호;김용현;한승희;김철성
    • Journal of the Korean Magnetics Society
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    • v.8 no.1
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    • pp.6-12
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    • 1998
  • Fe-N(iron-nitrogen) crystal phases were prepared by nitrogen ion implantation into $\alpha$-Fe foil with Plasma Source Ion Implantation (PSII). Ion implantation time of sample is treated 15 minutes(FeN15) and 30 minutes (FeN30). The nitrogen depth profiles measured by Auger electron spectroscopy (AES) were determined to be about 12000 $\AA$ and 4000 $\AA$ for the samples of FeN15 and FeN30, respectively. The results of vibrating sample magnetometer (VSM) show that the saturation magnetization of the samples of as-implanted FeN15 and FeN30 was higher than that of pure $\alpha$-Fe foil, which may be owing to $\alpha$'-$Fe_8N$ or $\alpha$"-$Fe_{16}N_2$ phases. Accordingly this study shows the possibility of the partial formation of $\alpha$' or $\alpha$" phase in iron nitrogen produced by PSII method.II method.

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Ion composition analysis of plasma sources for PSII (플라즈마 소스 이온주입용 플라즈마원의 이온 분석)

  • Kim, G.H.;Nikiforov, S.A.;Lee, H.S.;Rim, G.H.
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.2044-2046
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    • 2000
  • A system to monitor the ion mass and charge-state as well as plasma potential value during plasma source ion implantation (PSII) has been developed. It was tested with 30-kV PI3D setup using alternatively hot cathode do (HC) and inductively coupled RF (ICP) discharge sources. The design and performance of the system will be described, and experimental results in nitrogen and argon plasmas produced by modular HC-ICP source will be discussed.

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Development of a Circuit Model for the Dynamic Plasma Load in a PSII Pulse System (PSII 펄스 시스템의 동적 플라즈마 부하 회로 모델 개발)

  • Chung, K.J.;Choe, J.M.;Hwang, H.D.;Kim, G.H.;Ko, K.C.;Hwang, Y.S.
    • Journal of the Korean Vacuum Society
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    • v.15 no.3
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    • pp.246-258
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    • 2006
  • A circuit model has been developed to analyze characteristics of the PSII(plasma source ion implantation) pulse system with dynamic plasma load. The plasma sheath in front of the immersed planar target biased with a negative-high voltage pulse is assumed to be governed by the dynamic Child-Langmuir sheath model. Target current is self-consistently varied with the applied voltage by using the voltage-controlled current source in the circuit model. Circuit simulations are conducted with Pspice circuit simulator, and simulated pulse currents and voltages on the target are compared and confirmed with experimental results for various voltage pulses and plasma conditions.

A Study on the friction and Wear Characteristics of C-N Coated SCM415 Steel (C-N코팅 SCM415강의 마찰$\cdot$마모 특성에 관한 연구)

  • Lyu Sung-ki;Lu Long;Jin Tai-yu;Lian Zhe-Man;Cao Xing-Jin;Cho Sung-Min
    • Journal of the Korean Society of Safety
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    • v.20 no.1 s.69
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    • pp.18-23
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    • 2005
  • This study deals with the friction and wear characteristics of C-N coated SCM415 steel. The PSII(plasma source ion implantation) apparatus was built and a SCM415 test piece with steel substrate was treated with carbon nitrogen by this apparatus. The composition and structure of the surface layer were analyzed and compared with that of PVD(physical vapor decomposition) coated TiN layer. It was found that both of friction coefficient of C-N coating and TiN coating decreased with increasing load, however, C-N coating showed relatively lower faction coefficient than that of TiN coating. The micro-vickers hardness of C-N film is 3200 Hv, which is $32\~43\%$ higher than that of TiN film. The critical load of C-N film is 52N, which is $25\%$ higher than that of TiN film. The hardness of C-N film fabricated by Plasma ion implantation is $61\~70\%$ higher than that of base material, and faction coefficient is $14\~50\%$ lower than that of base material. It is also interesting to note that the friction was changed from adhesive wear mode to light oxidizing wear mode.

Removal Torque of Mg-ion Implanted Clinical Implants with Plasma Source Ion Implantation Method (마그네슘 이온주입 임플란트의 뒤틀림 제거력에 관한 연구)

  • Kim, Bo-Hyoun;Kim, Dae-Gon;Park, Chan-Jin;Cho, Lee-Ra
    • Journal of Dental Rehabilitation and Applied Science
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    • v.25 no.1
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    • pp.41-52
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    • 2009
  • The surface treatment of titanium implant could bring out the biochemical bonding between bone and implant. The purpose of this study was to evaluate the biomechanical bone response of Mg-ion implanted implants with plasma source ion implantation method. Twelve New Zealand white rabbits were included in this study. Each rabbit received one control fixture (blasted with resorbable blasting media, RBM) and three types of Mg ion implanted fixtures in tibiae. The implants were left in place for 6 weeks before the rabbits were sacrificed. Removal torque value and resonance frequency analysis (ISQ) were compared. The repeated measured analysis of variance was used with $P{\leq}0.05$ as level of statistical significance. ISQ was not different among all groups. However, the ISQ was increased after 6 weeks healing. The group had lowest ISQ value showed the greatest increment. Mg-1 implants with 9.4% retained ion dose showed significantly higher removal torque value than that of the other implants. From this results, it is concluded that the Mg-1 implants has stronger bone response than control RBM surface implant.

Hydrocarbon Plasma of a Low-Pressure Arc Discharge for Deposition of Highly-Adhesive Hydrogenated DLC Films

  • Chun, Hui-Gon;Oskomov, Konstantin V.;Sochugov, Nikolay S.;Lee, Jing-Hyuk;You, Yong-Zoo;Cho, Tong-Yul
    • Journal of the Semiconductor & Display Technology
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    • v.2 no.1
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    • pp.1-5
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    • 2003
  • Plasma generator based on non-self-sustained low-pressure arc discharge has been examined as a tool for deposition of highly-adhesive hydrogenated amorphous diamond-like carbon(DLC) films. Since the discharge is stable in wide range of gas pressures and currents, this plasma source makes possible to realize both plasma-immersion ion implantation(PIII) and plasma-immersion ion deposition(PIID) in a unified vacuum cycle. The plasma parameters were measured as functions of discharge current. Discharge and substrate bias voltage parameters have been determined for the PIII and PIID modes. For PIID it has been demonstrated that hard and well-adherent DLC coating are produced at 200-500 eV energies per deposited carbon atom. The growth rates of DLC films in this case are about 200-300 nm/h. It was also shown that short(∼60$\mu\textrm{s}$) high-voltage(> 1kV) substrate bias pulses are the most favorable for achieving high hardness and good adhesion of DLC, as well as for reducing of residual intrinsic stress are.

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A Study on the Friction and Wear Characteristics of Nitrogen Ions Coated SCM415 Steel (질소이온 코팅 SCM415강의 마찰.마모특성에 관한 연구)

  • Lyu, Sung-Ki;He, Hei-bo;Son, Yu-Sun
    • Tribology and Lubricants
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    • v.23 no.1
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    • pp.14-18
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    • 2007
  • SCM415 alloy was implanted with nitrogen ions using plasma source ion implantation (PSII), at a dose range of $1{\times}10^{17}\;to\;6{\times}10^{17}N^{+}cm^{-2}$. Auger electron spectrometry (AES) was used to investigate the depth profile of the implanted layer. Friction and wear tests were carried out on a block-on-ring wear tester. Scanning electron microscopy (SEM) was used to observe the micro-morphology of the worn surface. The results revealed that after being implanted with nitrogen ions, the frictional coefficient of the surface layer decreased, and the wear resistance increased with the nitrogen dose. The tribological mechanism was mainly adhesive, and the adhesive wear tended to become weaker oxidative wear with the increase in the nitrogen dose. The effects were mainly attributed to the formation of a hard nitride precipitate and a supersaturated solid solution of nitrogen in the surface layer.

Measurement of time-dependent sheath for the negative voltage pulse with a finite rise time (유한 오름 시간을 갖는 음전위 펄스에서 시변환 플라즈마 덮개의 거동 연구)

  • 김곤호;김영우;김건우;한승희;홍문표
    • Journal of the Korean Vacuum Society
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    • v.8 no.3B
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    • pp.361-367
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    • 1999
  • It was observed that the time-dependent sheath which was formed around the planar target biased by negatively voltage pulse with a finite rise time in the plasma source ion implantation. F\Results show that the time-dependent sheath consisted of two parts: the ion matrix sheath development during the pulse rise time and the dynamic sheath motion after attaining the full pulse. The ion matrix sheath development which is in proportion to square root of the pulse time and the pulse rise rate over the plasma density but independent of the ion mass. The dynamic sheath propagates with approximately the ion sound speed.

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