• 전기학회논문지
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• 제60권4호
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• pp.801-804
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• 2011

Electrical properties and microstructure were investigated on the effects of $MnO_2$ and the lead-free $(Na_{0.44}K_{0.52}Li_{0.04})(Nb_{0.83}Sb_{0.07}Ta_{0.1})O_3$ ceramics with the addition of $MnO_2$ were fabricated by a conventional mixed oxide method. A gradual change in the crystal and microstructure was observed with the increase of $MnO_2$ addition. For the NKN-LST-xmol%$MnO_2$ sintered at $1100^{\circ}C$, bulk density increased with the addition of $MnO_2$ and showed maximum value at addition 1.0mol% of $MnO_2$. Curie temperature of the NKN-LST ceramics slightly decreased with adding $MnO_2$. The dielectric constant, piezoelectric constant ($d_{33}$) and electromechanical coupling factor ($k_p$) increased below 0.25mol% of $MnO_2$ addition, which might be due to the increase in density. The high piezoelectric properties = 145 pC/N, electromechanical coupling factor = 0.421 and dielectric constant = 2883 were obtained for the NKN-LST-0.25mol%$MnO_2$ sintered at $1100^{\circ}C$ for 4h.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 추계학술대회 논문집
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• pp.297-299
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• 1999

Effects of additives on the ceramic and electrical properties of Pb(Y$_{1}$2/Ta$_{1}$2/)O$_3$-PbZrO$_3$-PbTiO$_3$ceramics in a perovskite type structure were investigated. The dielectric and piezoelectric properties of the base composition were improved markedly through selection of Fe$_2$O$_3$ additives in proper amounts. The composition Pb(Y$_{1}$2/Ta$_{1}$2/)O$_3$-PbZrO$_3$-PbTiO$_3$ obtained the dielectric constant ($\varepsilon$$_{r}$=1,425). Also, electromechanical couping factors for planar(k$_{p}$) and piezoelectric constant(d$_{33}$) were obtained 0.50 and 294[pC/N] at the additives 0wt% Fe$_2$O$_3$ respectively. The mechanical quality facor(Q$_{m}$) of Pb(Y$_{1}$2/Ta$_{1}$2/)O$_3$-PbZrO$_3$-PbTiO$_3$+Fe$_2$O$_3$(0.3 wt%) is about 510.510.510.

• 한국전기전자재료학회논문지
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• 제30권11호
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• pp.688-692
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• 2017

$Pb(Zr,\;Ti)O_3$ (PZT) is a piezoelectric material applied in a typical actuator and has been actively studied. However, in order to overcome the limitations of PZT, piezoelectric ceramics comprising mixed solid solutions of PZT with various relaxer electric materials have been studied. The $Pb(Zn_{1/3}Nb_{2/3})-Pb(Ni_{1/3}Nb_{2/3})-Pb(Zr,\;Ti)O_3$ (PZN-PNN-PZT) piezoelectric ceramic, known to have high piezoelectric constant and electromechanical coupling coefficient, was studied herein. The piezoelectric characteristics with various Zr contents (Zr/Ti ratios), PZN molar ratios, and sintering temperatures were compared. The piezoelectric properties of $d_{33}=580pC/N$ and $k_P=0.68$ were obtained with the $0.1PZN-0.2PNN-0.7PbZr_{0.46}Ti_{0.54}O_3$ composition sintered at $1,290^{\circ}C$.

• E2M - 전기 전자와 첨단 소재
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• 제10권5호
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• pp.434-439
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• 1997

It this paper, the piezoelectric and electro-induced strain properties of (P $b_{1-}$2x/3/B $i_{x}$ )[N $i_{1}$3/N $b_{2}$3/)$_{0.4}$( $Ti_{0.6}$Z $r_{0.4}$)$_{0.6}$] $O_3$ceramics (x=0, 0.005, 0.02) were investigated with the substitution of B $i^{3+}$, and the feasibility of the application for bimorph actuator was evaluated by measuring the dynamic properties of the piezoelectric bimorph fabricated with above ceramics. Dielectric constant was enhanced with the increase of B $i^{3+}$ substitution, and appeared the maximum value of 5032 at x=0.01 composition. Increasing the substitution of B $i^{3+}$, the electromechanical coefficient( $k_{p}$ , $k_{31}$ ) was increased up to the substitution of 0.5 mol% B $i^{3+}$, showed the value of 0.656, 0.439, respectively. The piezoelectric constant( $d_{33}$ $d_{31}$ ) had the highest value of 344, 825 with the substitution of 0.5 mol% B $i^{3+}$. The strain, generated by 60 Hz AC electric field, had the largest value of 1200($\times$10$^{-6}$ $\Delta$1/1) in the composition with the substitution of 0.5 mol% B $i^{3+}$. The dynamic properties of the bimorph actuator, fabricated with the composition substitution of 0.5 mol% B $i^{3+}$, showed the largest value of 325 $\mu$m at $\pm$150 V square pulse. square pulse.are pulse..

• 전자공학회논문지 IE
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• 제48권2호
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• pp.40-46
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• 2011

본 연구에서는 테입-케스팅 방법을 이용하여 제작한 PZT-5A의 소결온도 변화에 따른 압전특성을 조사한 후 유한요소 해석법을 이용하여 2-2형 압전복합재료를 초음파 트랜스듀서를 설계하고 압전특성을 해석하였다. 2-2형 압전복합재료의 음향임피던스와 압전전하상수($d_{33}$)는 PZT 부피분율이 감소함에 따라 밀도의 감소로 감소하여 0.6~0.2의 범위에서 14~3 MRayl로 초음파 트랜스듀서로 사용가능한 특성을 나타내었다. 공진특성과 전기기계결합계수는 PZT부피분율이 0.6일 때 가장 우수한 특성을 나타내었으며, PZT의 부피분율이 0.2~0.6에서는 $k_t$ 값이 0.64~0.68로 거의 일정한 값을 유지하였지만 그 이상에서는 급격하게 감소하는 것을 확인할 수 있었다. 이상의 실험결과로부터 2-2형 압전복합재료는 초음파 트랜스듀서 재료로 응용 가능성을 확인 할 수 있었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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• pp.304-304
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• 2006

기계적 에너지를 전지적 에너지로 변환하는 에너지 변환소자인 압전 세라믹스는 액츄에이터, 변압기, 초음파모터, 초음파 소자 및 각종 센서로 응용되고 있으며, 그 응용분야는 크게 종가하고 있다. 최근 이러한 에너지변환 소자를 앞으로 도래하는 유비쿼터스 무선 모바일 시대의 휴대용 전자제품, 즉 Wearable 컴퓨터, MP3, GSM, Bluetooth 등의 정보통신기기, Robotics, 항공우주, 자동차, 의료, 건축, MEMS 분야 등의 대체 에너지원으로 응용하기 위한 연구가 진행되고 있다. 특히 인간의 동작등과 같은 일상적인 동작(Typing, U. limbbing, Breathing, Walking 등)으로 필요한 전력을 얻을 수 있고, 세라믹 소자를 이용하기 때문에 전자노이즈가 발생되지 않을 뿐 아니라 반영구적으로 사용할 수가 있어서, 기존 이차전지, 연료전지를 대체 또는 보완 할 수 있는 방안도 검토되고 있다. 따라서 본 연구에서는 향후 응용 가능성이 큰 압전 발전 시스템을 제작하기 위해서 압전특성이 우수한 조성시스템 설계, 바이몰프 형태의 압전액츄에이터 제작, 그리고 발전시스템의 회로설계를 수행하였다.

• The Korean Journal of Ceramics
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• 제7권1호
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• pp.30-35
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• 2001

The contribution of the non-$180^{\circ}C$ domains to the electric-field-induced strains (EFI-strains) of PZT ceramics was evaluated by an XRD method and by an interferometric method. The XRD intensity ratio of 200 and 002 diffraction peaks of tetragonal PZT was measured under strong electric fields. The amount of the $90^{\circ}$ domain reorientation was evaluated and the strain due to the domain reorientation was calculated. It was confirmed that the EFI-strain of PZT ceramics was equal to the sum of the strain calculated from the d$_33$ constant determined by the resonance-antiresonance method and the strain due to the $90^{\circ}$ domain reorientation. The amount of the $90^{\circ}$domain reorientation has a linear relation with the c/a ratio in the "soft" PZT ceramics. A Mech-Zehnder interferometer was constructed to measure the EFI-strains vs. electric-field curves of PZT ceramics as a function of frequency. The EFI-strain vs. electric-field curve showed a hysteresis due to the effect of the non-$180^{\circ}$ domain reorientation when the applied voltage was high and its frequency was low. The apparent piezoelectric constant increased from the d$_33$ value determined by the resonance-antiresonance method with decreasing frequency. This deviation was attributed to the non-$180^{\circ}$ domain contribution.tribution.

• 한국전기전자재료학회논문지
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• 제24권7호
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• pp.543-546
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• 2011

We studied sintering temperature to enhance the piezoelectric properties of $0.98(Na_{0.5}K_{0.5})NbO_3-0.02Li(Sb_{0.17}Ta_{0.83})O_3$+0.01wt%ZnO (hereafter NKN-LST+ZnO) lead free piezoelectric ceramics. The synthesis and sintering method were the conventional solid state reaction method and sintering was executed at $1,080\sim1,120^{\circ}C$. We found that NKN-LST+ZnO ceramics at optimal sintering temperature showed the improved piezoelectric properties at the optimal sintering temperature. The NKN-LST+ZnO ceramics show good performance with piezoelectric constant $d_{33}$= 153 pC/N sintered at $1,090^{\circ}C$. The results reveal that NKN-LST+ZnO ceramics are promising candidate materials for lead-free piezoelectric application.

• 센서학회지
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• 제32권4호
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• pp.238-245
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• 2023

0.75(Bi_1/2Na_1/2)TiO₃-0.25SrTiO₃ (BNT-25ST) ceramics with high densities were successfully prepared at a sintering temperature of 1,000℃ by adding a mixture of 1 mol% CuO and 0.5 mol% Na₂CO₃ or 0.5 mol% CuO and 0.25 mol% Na₂CO₃. Double polarization-electric field (P-E) hysteresis curves and sprout-shaped bipolar strain-electric field (S-E) hysteresis curves with small negative strains were observed in the pristine and CuO-added BNT-25ST ceramics whereas the Na₂CO₃-added sample showed similar P-E and S-E curves to a typical ferroelectric. The pristine BNT-25ST ceramics showed an extremely large strain and a large-signal piezoelectric strain constant (d₃₃^*): 0.287 % at 80 kV/cm and 850 pm/V at 20 kV/cm. Similar values, 0.248 % at 80 kV/cm and 655 pm/V at 20 kV/cm, were obtained in the CuO-added sample. However, the pristine and CuO-added samples showed large hysteresis in unipolar S-E curves at an electric field of less than 20 kV/cm. The Na₂CO₃-added sample showed smaller values of the strain and d₃₃^* but displayed a linear change and small hysteresis in the unipolar S-E curve. The co-added sample with CuO and Na₂CO₃ displayed intermediate P-E and S-E hysteresis curves.

• 한국세라믹학회지
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• 제41권9호
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• pp.709-714
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• 2004

우수한 압전 특성을 나타내는 것으로 알려진 Mn 첨가 PMN-PZT의 저온소결 첨가제가 실험되었다. 저온소결 첨가제로는 B$_2$O$_3$가 사용되었고 소결온도와 B$_2$O$_3$ 첨가량의 변화가 소결성과 유전 및 압전특성의 변화에 미치는 영향을 조사하였다. B$_2$O$_3$ 첨가량과 소결온도를 변화시킨 결과 B$_2$O$_3$ 첨가량 2wt% 이하 100$0^{\circ}C$이하 조건에서 소결밀도가 증가하여 B$_2$O$_3$가 저온소결재로 작용하였다. 그러나 10$50^{\circ}C$ 이상에서는 주조성인 PMN-PZT보다 낮은 소결밀도를 나타내었다. B$_2$O$_3$ 첨가에 따른 유전상수($\varepsilon$$_{33}$ $^{T}$ )의 변화를 확인할 결과 B$_2$O$_3$ 2wt% 100$0^{\circ}C$ 조건에서 1000의 유전율을 나타내었다. B$_2$O$_3$ 첨가량이 전기-기계 결합계수(k$_{p}$ )와 압전상수(d$_{33}$ )에 큰 저하를 가져오지 않는 B$_2$O$_3$ 첨가 한계는 2wt% 이하로 나타났다. 이때, k$_{p}$ 는 약 50%, d$_{33}$ 는 약 300(${\times}$$10^{-12}$ C/N) 정도의 값을 얻을 수 있었다. B$_2$O$_3$ 첨가는 기계적 품질계수(Q$_{m}$ )의 증가를 가져왔으며 0.5wt% B$_2$O$_3$ 첨가 110$0^{\circ}C$ 소결 조건에서 1700의 품질계수를 나타내었다. 유전손실은 B$_2$O$_3$ 첨가에 따라 큰 변화 없이 0.5% 이하의 값으로 나타났다.