• 제목/요약/키워드: physical vapor transport

검색결과 92건 처리시간 0.022초

Structure and Physical Properties of $YSe_{1.83}$

  • 김성진;오훈정
    • Bulletin of the Korean Chemical Society
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    • 제16권6호
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    • pp.515-518
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    • 1995
  • YSe1.83 was synthesized by vapor transport technique and its crystal structure was determined. The structure was isostructure of LaTe2-x, which was layered structure consisting of two-atom thick layers of YSe with distorted NaCl-type structure and one-atom thick layer of Se. The substructure of YSe1.83 was tetragonal with space group of P4/nmm and a=4.011(2) and c=8.261(3) Å with final R/Rw=6.4/6.9 %. The superstructure with asuper=2a, bsuper=6b and csuper=2c was found. The measurements of electronic and magnetic properties of this compound indicate that it is an electronic insulator and diamagnet.

Effects of Solutally Dominant Convection on Physical Vapor Transport for a Mixture of Hg2Br2 and Br2 under Microgravity Environments

  • Kim, Geug-Tae;Kwon, Moo Hyun
    • Korean Chemical Engineering Research
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    • 제52권1호
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    • pp.75-80
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    • 2014
  • The convective flow structures in the vapor phase on earth are shown to be single unicellular, indicating the solutally dominant convection is important. These findings reflect that the total molar fluxes show asymmetrical patterns in a viewpoint of interfacial distributions. With decreasing the gravitational level form $1g_0$ down to $1.0{\times}10^{-4}g_0$, the total molar fluxes decay first order exponentially. It is also found that the total molar fluxes decay first order exponentially with increasing the partial pressure of component B, PB (Torr) form 5 Torr up to 400 Torr. Under microgravity environments less than $1g_0$, a diffusive-convection mode is dominant and, results in much uniformity in front of the crystal regions in comparisons with a normal gravity acceleration of $1g_0$.

수평원관군상(水平圓管群上)의 이원흡수용액유동(二元吸收溶液流動)에 의(依)한 전달흡수특성(傳達吸收特性) (Absorption of Water Vapor into an Absorbing Binary Liquid Film Falling over a Horizontal Tube Bank)

  • 김석현;김영인;서석청;황동곤
    • 대한설비공학회지:설비저널
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    • 제17권5호
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    • pp.583-589
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    • 1988
  • Condensation of water vapor into an absorbent liquid of LiBr-water solution falling over a bank of water cooled horizontal tubes was investigated theoretically. The governing conservation equation for a re-defined physical transport phenomena were solved numerically using a finite difference method. Raw parameters were used in this study, since reliable experimental data is required prior to a dimensionless parametric study. The average values of wall heat transfer coefficient and interfacial absorption rate were defined to see the system performance. Other parameters include tube diameter, streamwise coordinate (and number of tubes in row), mass flow rate, and the wall temperature. The effects of these quantities on the absorption processes and suggestions for a rational system design have been presented.

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HPCVD 방법으로 성장된 $MgB_2$ 박막의 수송 특성 (Transport Properties of $MgB_2$ Films Grown by Hybrid Physical Chemical Vapor Deposition Method)

  • 김혜영;황태종;김동호;성원경;강원남
    • Progress in Superconductivity
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    • 제9권1호
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    • pp.5-10
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    • 2007
  • We prepared four different $MgB_2$ films on $Al_2O_3$ by hybrid physical chemical vapor deposition method with thicknesses ranging from $0.65\;{\mu}m$ to $1.2\;{\mu}m$. X-ray diffraction patterns confirm that all the $MgB_2$ films are c-axis oriented perpendicular to $Al_2O_3$ substrates. The superconducting onset temperature of $MgB_2$ films were between 39.39K and 40.72K. The residual resistivity ratio of the $MgB_2$ films was in the range between 3.13 and 37.3. We measured the angle dependence of critical current density ($J_c$) and resistivity, and determined the upper critical field ($H_{c2}$) from the temperature dependence of the resistivity curves. The anisotropy ratios defined as the ratio of the $H_{c2}$ parallel to the ab-plane to that perpendicular to the ab-plane were in the range of 2.13 to 4.5 and were increased as the temperature was decreased. Some samples showed increase of $J_c$ and decrease of resistivity when a magnetic field in applied parallel to the c-axis. We interpret this angle dependence in terms of enhanced flux pinning due to columnar growth of $MgB_2$ along the c-axis.

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Lead bromide crystal growth from the melt and characterization: the effects of nonlinear thermal boundary conditions on convection during physical vapor crystal growth of mercurous bromide

  • Geug-Tae Kim;Moo Hyun Kwon
    • 한국결정성장학회지
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    • 제14권4호
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    • pp.160-168
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    • 2004
  • We investigate the effects of solutal convection on the crystal growth rate in a horizontal configuration for diffusive-convection conditions and purely diffusion conditions achievable in a low gravity environment for a nonlinear thermal gradient. It is concluded that the solutally-driven convection due to the disparity in the molecular weights of the component A $(Hg_2Br_2)$ and B (CO) is stronger than thermally-driven convection for both the nonlinear and the linear thermal profiles, corresponding to $Gr_t= 8.5{\times}10^3,\; Gr_s = 1.05{\times}10^5$. For both solutal and thermal convection processes, the growth rates for the linear thermal profile (conducting walls) are greater than for the nonlinear case. With the temperature humps, there are found to be observed in undersaturation for diffusive-convection processes ranging from $D_{AB}$ = 0.087 to 0.87. For the vertical configurations, the diffusion mode is so much dominated that the growth rate and interfacial distribution is nearly regardless of the gravitational accelerations. Also, the diffusion mode is predominant over the convection for the gravity levels less than 0.1 $g_0$ for the horizontally oriented configuration.

AlN 단결정 성장에 관한 도가니 형태의 의존성에 관한 연구 (A study on the dependance of crucible dimension on AlN single crystal growth)

  • 인경필;강승민
    • 한국결정성장학회지
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    • 제25권1호
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    • pp.1-5
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    • 2015
  • AlN 단결정의 특별한 용도로 이를 개발하기 위한 노력이 전 세계적으로 매우 활발하게 이루어지고 있다. 이러한 AlN을 기반으로 하는 자외선 LED는 생활, 의학, 자동자 등에 유용한 용도로서 살균, 정화, 경화 및 분석 등 분야에 이용된다. 이에 실험을 통해 PVT법으로 카본 도가니를 사용하여 AlN 단결정을 성장시켰으며 실험 중 3가지 형태의 도가니를 이용하여 성장에 미치는 영향을 분석하였으며, 그 온도 조건은 $1900{\sim}2100^{\circ}C$이고 실험 압력으로는 1~200 Torr였다. 그 결과, 높이가 높은 형태의 도가니를 사용할 경우 증발량은 기준 형태보다 증가 하는데 그쳤다. 반면, 넓은 형태의 도가니는 더욱 많은 증발양의 증가를 보였으며, 기준 형태에 비하여 훨씬 안정하다는 것을 알았다. 또한, 제한된 크기의 도가니를 이용한 PVT법에서의 도가니 형태의 변화에 따른 결과는 성장률에 따른 최적 조건, 성장 결정의 품질변화 및 성장 조건 안정성에 영향을 주는 것을 알았다.

NbC 코팅된 도가니를 사용한 고품질의 SiC 단결정 성장 (High quality SiC single crystal growth by using NbC-coated crucible)

  • 김정희;김우연;박미선;장연숙;이원재
    • 한국결정성장학회지
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    • 제31권2호
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    • pp.63-68
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    • 2021
  • 본 연구에서는 NbC 코팅된 도가니가 SiC 단결정 품질에 미치는 영향을 조사하였다. 실험은 흑연 도가니와 NbC 코팅된 도가니를 사용하였으며, 두 실험의 결과를 체계적으로 비교 분석하였다. SiC 결정 성장은 Ar 분위기에서 2300℃ 이상의 온도와 5 Torr의 압력조건에서 PVT 법을 사용하여 진행하였다. 성장된 SiC 결정은 양면 그라인딩과 연마 가공 후 Raman 분석을 통해 결정상 분석, HR-XRD 분석으로 결정성을 분석하였다. 또한 KOH 에칭 후 광학현미경 분석과 SIMS 분석으로 결함 밀도 및 불순물 농도를 분석하여 두 웨이퍼의 품질을 비교하였다.

Experimental Observations of Boiling and Flow Evolution in a Coiled Tube

  • Ye, P.;Peng, X.F.;Wu, H.L.;Meng, M.;Gong, Y. Eric
    • International Journal of Air-Conditioning and Refrigeration
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    • 제16권1호
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    • pp.22-29
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    • 2008
  • A sequence of visually experimental observations was conducted to investigate the flow boiling and two-phase flow in a coiled tube. Different boiling modes and bubble dynamical evolutions were identified for better recognizing the phenomena and understanding the two-phase flow evolution and heat transfer mechanisms. The dissolved gases and remained vapor would serve as foreign nucleation sites, and together with the effect of buoyancy, centrifugal force and liquid flow, these also induce very different flow boiling nucleation, boiling modes, bubble dynamical behavior, and further the boiling heat transfer performance. Bubbly flow, plug flow, slug flow, stratified/wavy flow and annular flow were observed during the boiling process in the coiled tube. Particularly the effects of flow reconstructing and thermal non-equilibrium release in the bends were noted and discussed with the physical understanding. Coupled with the effects of the buoyancy, centrifugal force and inertia or momentum ratio of the two fluids, the flow reconstructing and thermal non-equilibrium release effects have critical importance for flow pattern in the bends and flow evolution in next straight sections.

브로민화수은(I)(Hg2Br2) 증착공정에서 자체확산 연구 (Study on self-diffusion transport phenomena during mercurous bromide (Hg2Br2) vapor processes)

  • 김남일;김극태
    • 한국결정성장학회지
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    • 제34권2호
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    • pp.48-54
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    • 2024
  • 브로민화 수은(I)(Hg2Br2) 자체 확산 물리적 증착법 공정에서 자체 확산 전달현상 연구에서 얻어진 결론은 10-3g0 ≤ g ≤ 1g0 영역에서는 열 대류현상이 지배적이며, g = 10-4g0 영역에서는 대류에서 확산영역으로 전이되는 영역이며, 10-6g0 ≤ g ≤ 10-5g0 영역에서는 확산모드가 지배적이다. Hg2Br2의 총 몰플럭스는 중력가속도의 레벌(level)이 1/10 크기로 감소함에 따라 기하급수적으로 감소함을 나타내고 있다는 것이다. 10℃ ≤ ΔT ≤ 50℃의 온도차 범위에서는 온도차(ΔT)와 Hg2Br2의 총 몰플럭스에 대한 관계식은 선형적으로 직선적 비례관계성을 보여주고 있다.

의류직물의 구성조건에 따른 열저항 특성 연구 (A Study on the Thermal Resistance of Wool Fabric Constructions)

  • 김태훈;전병익
    • 한국의류산업학회지
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    • 제3권1호
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    • pp.15-19
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    • 2001
  • The purpose of this study was to determine the thermal characteristics of men's suits ensembles and their fabrics. For the study, 100% wool fabrics were woven with various fabric structure, fabric density and yam count and With the use of these, 12 men's suits were made with the same design. Physical characteristics that affect thermal transport properties, including drapery, cover factor; bulk density, keeping warmth ratio, vapor permeability, air permeability and porosity of the fabrics were measured. In addition, thermal resistance of men's suit ensembles, including Y-shirts, inner wear and socks was measured on the thermal manikin in the environmental chamber. The result of the study was as follows: 1. In terms of fabric structure, keeping warmth ratio of plain woven fabrics was higher than those of twill and satin woven fabrics and also, vapor and air permeability and porosity of plain woven fabrics were higher than those of twill and satin woven fabrics. 2. The result showed that thermal resistance of 12 ensembles were in the range of 0.77clo~0.97clo. 3. There was little correlation between woven condition such as, including structure, fabric density and yam count and thermal resistance of ensembles.

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