• Title/Summary/Keyword: physical and chemistry properties

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The Calculation of Physical Properties of Amino Acids using Molecular Modeling Techniques

  • Ui-Rak Kim;Kyung-Sub Min;Bong-Jin Jeong
    • Bulletin of the Korean Chemical Society
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    • v.15 no.2
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    • pp.106-112
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    • 1994
  • Six physical properties (molecular weight, heat capacity, side chain weight, side chain volume, standard entropy and partial molar volume) of amino acids, peptides and their derivatives were examined by molecular modeling techniques. The molecular connectivity index, Wiener distance index and ad hoc descriptor are employed as structural parameters to encode information about branching, size, cyclization, unsaturation, heteroatom content and polarizability. This paper examines the correlation of the molecular modeling techique's parameters and the physicochemical properties of amino acids and their derivatives. As a result, calculated values were in agreement with experimental data in the above six physical properties of amino acids, peptides and their derivatives and the molecular connectivity index was superior to the other indices in fitting the calculated data.

Soil Physical and Hydraulic Properties over Terrace Adjacent Four Major Rivers

  • Lee, Kyo Suk;Lee, Jae Bong;Lee, Myoung Yun;Joo, Ri Na;Lee, Dong Sung;Chung, Doug Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.3
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    • pp.235-241
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    • 2016
  • The soil does not only serve as a medium for plant growth but also for engineering construction purposes. It is very weak in tension, very strong in compression and fails only by shearing. The behaviour of the soil under any form of loading and the interactions of the earth materials during and after any engineering construction work has a major influence on the success, economy and the safety of the work. Soils and their management have therefore become a broad social concern. A limitless variety of soil materials are encountered in both agronomy and engineering problems, varying from hard, dense, large pieces of rock through gravel, sand, silt and clay to organic deposits of soft compressible peat. All these materials may occur over a range of physical properties, such as water contents, texture, bulk density and strength of soils. Therefore, to deal properly with soils and soil materials in any case requires knowledge and understanding of these physical properties. The desired value of bulk density varies with the degree of stability required in construction. Bulk density is also used as an indicator of problems of root penetration,soil aeration and also water infiltration. This property is also used in foundation engineering problems. While not conforming to standard test procedures, this work attempts to add to the basic information on such important soil parameters as water content, bulk density.

The Calculation of Physical Properties of Amino Acids Using Molecular Modeling Techniques (II)

  • Lee, Myung-Jae;Kim, Ui-Rak
    • Bulletin of the Korean Chemical Society
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    • v.25 no.7
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    • pp.1046-1050
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    • 2004
  • Six physical properties (enthalpy, density, decomposition temperature, solubility in water, pKa values, and hydronium potential) were examined by molecular modeling techniques. The molecular connectivity index, Wiener distance index, and Ad hoc descriptor are employed as structural parameters to encode information about branching, size, cyclization, unsaturation, heteroatom content, and polarizability. This paper examines the correlation of the molecular modeling techniques parameters and the physicochemical properties of amino acids. As a results, calculated values were in agreement with experimental data in the above six physical properties of amino acids and the molecular connectivity index was superior to the other indices in fitting the calculated data.

A Study on the Manufacturing of Cellurar Rubber Products with NR, NBR and EPDM (NR, NBR 및 EPDM 발포(發泡)고무의 제조(製造) 연구(硏究))

  • Kim, Hong-Seon;Choi, Sei-Young
    • Elastomers and Composites
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    • v.29 no.3
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    • pp.213-225
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    • 1994
  • The Purpose of this dissertation is to study the preparation technique and physical properties of expanded rubber. The respective samples of NR, NBR and the standard compounds of EPDM rubber were prepared by mixing plasticizer DOP and LCR in various ratio. And their vulcanization characteristics, physical properties and foaming states were studied. Vulcanization characteristics were investigated using cure curve that had been obtained from Oscillating Disk Rheometer study, and the microscopic photographs of foaming states were obtained using electron microscope. The vulcanization characteristics of the samples, DOP 30phr and LCR 30phr, were found to be suitable. The tests, like hardness test and resilience, tensile test on the physical properties of each sample showed that plasticizing efficiencies of DOP and LCR were almost the same. Oil resistance test exhibited DOP was better than LCR and compression set test showed LCR was excellent plasticizer. The foaming states of NR, EPDM compounds were uniform, but those of NBR compounds were not uniform. Consequently vulcanization characteristics, physical properties and foaming states of all the samples satisfied the SAE requirements.

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Monitoring physical and chemical properties of soil in Chungcheongbuk-do

  • Yun-Gu Kang;Jae-Han Lee;Taek-Keun Oh
    • Korean Journal of Agricultural Science
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    • v.49 no.4
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    • pp.719-727
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    • 2022
  • The soil physical and chemical properties are the main factors that influence plant productivity and soil fertility. Since 1999, South Korea has been conducting a survey on changes in the agricultural environment survey every four years. The purpose of the present study is to monitor the physical and chemical properties of soil in Chungcheongbuk-do. Soil samples were collected from the exact sites of the aforementioned environment survey, and land use and cultivated crops were also investigated. From a Pearson correlation analysis, it was found that the total carbon contents were most negatively affected by the soil depth. The bulk density of soil increased up to a depth of 40 cm but decreased to a depth of 60 cm. The porosity and moisture of soil generally decreased, but the porosity increased at a depth of 50 - 60 cm. Chemical properties of soil gradually decreased with an increase of the soil depth from 0 to 70 cm, but little change was observed in soil pH with soil depth. In addition, the organic matter contents of the soil at a depth of 30 cm or more were below the optimal range. The soil of Chungcheongbuk-do thus requires organic matter application as a whole, and correction of items that are partially out of the optimal range is necessary.

Doped Sol-gel TiO2 Films for Biological Applications

  • Gartner, M.;Trapalis, C.;Todorova, N.;Giannakopoulou, T.;Dobrescu, G.;Anastasescu, M.;Osiceanu, P.;Ghita, A.;Enache, M.;Dumitru, L.;Stoica, T.;Zaharescu, M.;Bae, J.Y.;Suh, S.H.
    • Bulletin of the Korean Chemical Society
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    • v.29 no.5
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    • pp.1038-1042
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    • 2008
  • Mono and multilayer TiO2(Fe, $PEG_{600}$) films were deposited by the dip-coating on $SiO_2$/glass substrate using sol-gel method. In an attempt to improve the antibacterial properties of doped $TiO_2$ films, the influence of the iron oxides and polyethilenglycol ($PEG_{600}$) on the morphological, optical, surface chemical composition and biological properties of nanostructured layers was studied. Complementary measurements were performed including Spectroscopic Ellipsometry (SE), Scanning Electron Microscopy (SEM) coupled with the fractal analysis, X-Ray Photoelectron Spectroscopy (XPS) and antibacterial tests. It was found that different concentrations of Fe and $PEG_{600}$ added to coating solution strongly influence the porosity and morphology at nanometric scale related to fractal behaviour and the elemental and chemical states of the surfaces as well. The thermal treatment under oxidative atmosphere leads to films densification and oxides phase stabilization. The antibacterial activity of coatings against Escherichia Coli bacteria was examined by specific antibacterial tests.

Preparation of Tantalum Anodic Oxide Film in Citric Acid Solution - Evidence and Effects of Citrate Anion Incorporation

  • Kim, Young-Ho;Uosaki, Kohei
    • Journal of Electrochemical Science and Technology
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    • v.4 no.4
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    • pp.163-170
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    • 2013
  • Tantalum anodic oxide film was prepared in citric acid solution of various concentrations and the prepared Ta anodic oxide film was characterized by various electrochemical techniques and X-ray photoelectron spectroscopy (XPS). The prepared Ta anodic oxide film showed typical n-type semiconducting properties and the dielectric properties were strongly dependent on the citric acid concentration. The variation of electrochemical and electronic properties was explained in terms of electrolyte anion incorporation into the anodic oxide film, which was supported by XPS measurements.

Effects of A-Site and B-Site Vacancies on Structural and Dielectric Properties of PLZT Ceramics

  • Jeong, Cheol-Su;Park, Hyu-Bum;Hong, Young-Sik;Kim, Si-Joong
    • The Korean Journal of Ceramics
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    • v.2 no.2
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    • pp.76-82
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    • 1996
  • PLZT ceramics having two nominal compositions, $Pb_{1-3x/2}La_xV_{x/2}(Zr_{03}Ti_{03})O_3$ and $Pb_{1-x}La_x(Zr_{0.2}Ti_{0.5})_{1-x/4}V_{x/4}O_3$ (V: vacancy) with x=0.00~0.30, were prepared. The physical, structural, and dielectric properties were investigated by X-ray diffraction, scanning electron microscopy, Raman spectroscopy, and measurements of bulk density and dielectric constant. The two series with A-stie and B-site vacancies showed different physical, structural, dielectric properties, and, specially, Curie temperature. In comparison to PLZT with B-site vacancies, PLZT with A-site vacancies showed high Curie temperatures and low maxima of dielectric constant. Consequently, it is evident that the properties of PLZT ceramics depend on the vacancy formula adopted as a batch composition in preparation.

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Physical properties of mungbean starch/PVA bionanocomposites added nano-ZnS particles and its photocatalytic activity

  • Yun, Yeon-Hum;Kim, Eun-Sik;Shim, Wang-Geun;Yoon, Soon-Do
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.57-68
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    • 2018
  • The main objective of this study is to prepare the bionanocomposite films using mungbean starch (MBS), PVA, ZnS, and plasticizers, and to evaluate the physical properties, thermal stability, and photocatalytic activity. The bionanocomposite films were cross-linked by heat-curing process. The ZnS and bionanocomposite films were characterized by FT-IR, XRD, and SEM. The results indicated that the mechanical properties and water resistance enhanced up to 1.2-1.5 times by the addition of nano-ZnS particles, and the thermal stability was improved by the addition of nano-ZnS particles. The photocatalytic activity of the bionanocomposite films added nano-ZnS particles was examined using bisphenol A (BPA) and methyl orange (MO). In addition, the photodegradation efficiency of BPA and MO was evaluated using the pseudo-first order kinetic model (PFOK).

Inorganic Components and Some Physical Properties of Sap from Sponge-gourd(Luffa cylindrica L.) as Affected by Collection Time (채취시기(採取時期)에 따른 수세미오이(Sponge-gourd; Luffa cylindrica L.) 수액(樹液)의 무기성분(無機成分) 및 물리적(物理的) 성질(性質)의 특성(特性))

  • Park, Jong-Sang;Lee, Jin-Il;Chang, Ki-Woon
    • Applied Biological Chemistry
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    • v.39 no.1
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    • pp.67-69
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    • 1996
  • Some physical properties and inorganic components of sap from sponge-gourd(Luffa cylindrica L.) were investigated for their changes affected as collection time. Huter valves, pH, turbidity and viscosity of the sap were not different. pH value was indicated at slightly alkalinity and decreased by culturing period. Potassium, calcium and magnesium were major inorganic components of the sap and podium, zinc and iron were minor components. Copper was not detected in open culturing and also manganes way not detected in all samples.

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