• Title/Summary/Keyword: photoemission spectroscopy

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Electronic and Magnetic Structures of {Ca,Sr,Ba}$Fe_2As_2$ : Dynamical Mean Field Theory Approach ({Ca,Sr,Ba}$Fe_2As_2$의 전자 및 자성 구조: 동력학적 평균장 이론 접근)

  • Lee, Geun-Sik;Shim, Ji-Hoon
    • Progress in Superconductivity
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    • v.13 no.2
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    • pp.85-89
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    • 2011
  • Using the density functional theory and its combination to the dynamical mean field theory (DMFT), we have studied the electronic and magnetic structures of Fe-based superconductors, $AFe_2As_2$ (A=Ca, Sr, Ba). Our results for the electronic structure agree well with existing angle resolved photoemission spectroscopy (ARPES) data. The temperature dependent magnetization has been calculated using DMFT, and the magnetic transition temperatures are reasonably consistent with the experimentally observed trend for three compounds.

Reverse-bias Leakage Current Mechanisms in Cu/n-type Schottky Junction Using Oxygen Plasma Treatment

  • Kim, Hogyoung
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.2
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    • pp.113-117
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    • 2016
  • Temperature dependent reverse-bias current-voltage (I-V) characteristics in Cu Schottky contacts to oxygen plasma treated n-InP were investigated. For untreated sample, current transport mechanisms at low and high temperatures were explained by thermionic emission (TE) and TE combined with barrier lowering, respectively. For plasma treated sample, experimental I-V data were explained by TE or TE combined with barrier lowering models at low and high temperatures. However, the current transport was explained by a thermionic field emission (TFE) model at intermediate temperatures. From X-ray photoemission spectroscopy (XPS) measurements, phosphorus vacancies (VP) were suggested to be generated after oxygen plasma treatment. VP possibly involves defects contributing to the current transport at intermediate temperatures. Therefore, minimizing the generation of these defects after oxygen plasma treatment is required to reduce the reverse-bias leakage current.

Surface Analysis of PZT Film Prepared by Sputting Method (SPUTTERING법에 의해 성장시킨 PZT박막의 표면 분석)

  • 김영관;박주상;추정우;손병청;이전국
    • Journal of the Korean Vacuum Society
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    • v.5 no.2
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    • pp.107-112
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    • 1996
  • Thin films of $Pb(Zr_xTi_{1-x})O_3$)PZT) were grown on $Pt/SiO_2/Si(100)$ at various temperatures by RF magnetron sputtering method. Surface morphology of these films were studied by using Atomic Force Microscopy(AFM). These films were also analyzed by using Atomic Force Microscopy(AFM). These films were also analyzed by using X-ray photoemission spectroscopy(XPS) for determining their chemical composition and their depth profile. It was found that the films grown at the substrated temperature of $300^{\circ}C$ have much more smooth surface characteristics in comparison to those films grown at room temperature, which may be explained in terms of surface mobility of ad-atoms such as Pb. It was also found that Pb enrichment in the near surface region enhanced for the films grown at higher substate temperature.

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PROPERTIES OF THE CRYSTALLINE POLYIMIDE FILM DEPOSITED BY IONIZED CLUSTER BEAM

  • Whang, Chung-Nam
    • Proceedings of the Materials Research Society of Korea Conference
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    • 1992.05a
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    • pp.6-6
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    • 1992
  • Ionized cluster beam deposition (ICBD) technique has been employed to fabricate high-purity crystalline polyimide (PI) film. The pyromellitic dianhydride (PMDA) and oxydianiline (ODA) were deposited using dual ICB sources, Fourier trans forminfraredspectroscopy (FT-IR), X-ray photoemission spectroscopy (XPS), and Transmission electron microscopy (TEM)study show that the bulk and surface chemical properties and the crystalline structure are very sensitive to the ICBD conditions such as cluster ion acceleration voltage and ionization voltage, At optimum ICBD conditions, the PI films have a maximum imidization, negligible impurities(∼1% isoimide), and a good crystalline structure probably due to the high surface migration energy and surface cleaning effect. These characteristics are superior to those of films deposited by other techniques such as colvent cast, vapowr deposition, or sputtering techniques.

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Interfacial Properties in Cu-phthalocyanine-based Hybrid Inorganic/Organic Multilayers

  • Lee, Nyun Jong;Ito, Eisuke;Bae, Yu Jeong;Kim, Tae Hee
    • Journal of Magnetics
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    • v.17 no.4
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    • pp.261-264
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    • 2012
  • Interfacial properties of 5 nm MgO(001)/7 nm Fe(001)/1.8 nm MgO(001)/t nm Cu-phthalocyanine (CuPc) hybrid multilayers with t = 0, 1, 7, and 10 were investigated by using x-ray photoemission spectroscopy (XPS). Rather sharp interfacial properties were observed in the CuPc films grown on an epitaxial MgO/Fe/MgO(001) trilayer than a MgO/Fe(001) bilayer. This work suggests a new way to improve device performance of organic spintronic devices by utilizing an artificially grown MgO(001) thin layer.

Chemical Doping of Graphene by Altretamine(2,4,6-Tris [dimethylamino]-1,3,5-Triazine)

  • Park, Sun-Min;Yang, Se-Na;Lim, Hee-Seon;Lee, Han-Gil
    • Bulletin of the Korean Chemical Society
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    • v.32 no.7
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    • pp.2199-2202
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    • 2011
  • The electronic properties of altretamine(2,4,6-tris [dimethylamino]-1,3,5-triazine) adsorbed on epitaxial graphene (EG) were investigated by core-level photoemission spectroscopy (CLPES) in conjunction with low energy electron diffraction (LEED). We found that altretamine molecule adsorbed onto interface layer (S1) of graphene as we confirm decrement of S1 peak using CLPES and haziness of LEED pattern. Moreover, the measured work function changes verified that increased adsorption of the altretamine on graphene layer showed n-type doping characteristics due to charge transfer from altretamine to graphene through the nitrogens. Two distinct nitrogen bonding feature associated with the N 1s peak was clearly observed in the core-level spectra indicating two different chemical environments.

Directionality of O-Phthaladehyde adsorbed on H-Si(100) Surface Using NEXAFS and HRPES

  • Kim, Gi-Jeong;Park, Seon-Min;Im, Hui-Seon;Kim, Bong-Su;Lee, Han-Gil
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.79-79
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    • 2010
  • The electronic and adsorption structure of O-Phthaladehyde (OPA) on the H-Si(100) surface was investigated by using Near Edge X-ray Fine Structure (NEXAFS) and high resolution photoemission spectroscopy (HRPES). We confirmed that the OPA grown on the H-Si(100) surface showed good dependency with about 60 degree tilting angle using NEXAFS and a single O 1s peak by using HRPES. Hydrogen atom passivated on the Si(100) surface was found to be a seed for making one dimensional organic line that uses a chain reaction as the H-Si(100) surface was compared with the hydrogen free Si(100) surface. Through the spectral analysis, we will demonstrate 1-D directional formation of OPA on H-Si(100) surface using NEXAFS and HRPES.

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Adsorption Characteristics of Furan, Thiophene, and Selenophene on Si(100) Surface

  • Park, Jinwoo;Lee, Han-Koo;Chung, J.W.;Hong, Suklyun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.202.2-202.2
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    • 2014
  • We have studied the bonding structures of five membered aromatic ring heterocyclic molecules, such as furan, thiophene, and selenophene, adsorbed on the Si(100) surface at room temperature with density functional theory. Additionally, we have investigated the evolution upon annealing of thiophene and selenophene molecules on the Si(100) surface by the core-level photoemission spectroscopy and near-edge X-ray absorption fine structure (NEXAFS). The core-level-spectra measured at different temperatures are consistently interpreted in terms of various adsorption structures suggested by theoretical calculations. In this study, we found the most suitable structures by theoretical and experimental results considering room temperature and mild thermal annealing.

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Physical ppropperties in Rare-earth Compounds

  • Takashi, Suzuki
    • Proceedings of the Korean Vacuum Society Conference
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    • 1998.02a
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    • pp.18-18
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    • 1998
  • F First I will introduce our works how to improve the crystal growth t technique for Rare earth pnictides and chalcogenides. All these substances h have hi양1 vapor pressure and high melting print up to 3$\alpha$)()C. 까len we employ m the tungsten or molybden crucibles and enclose the sample by 빼e welding of m the lid with high current electron beam. We cannot elevate the temperature up t to 3$\alpha$)()C without suitable radiation shield because rate of radiation loss r rapidly increase in such a high temperature regions. There were no good r radiation shield but we discovered that the p-BN could work as an excellent r radiation shield after checking of the many substances. S Secondly I will show several interesting and unusual 뻐ysical properties of obtained crystals under high magnetic field, hi양1 pressure and also i including angle resolve photoemission spectroscopy. I will stress the p properties of the low carrier concentration with strong correlation on C댐, U USb and Yb4As3

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Electronic and atomic structure control of epitaxial graphene

  • An, Jong-Ryeol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.53-53
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    • 2010
  • Graphene comes into the spotlight as an emergent device material on account of its high carrier mobility reflecting its massless Dirac fermion behavior. Chemical technique to control reversibly the carrier concentration of semiconducting graphene for the achievement of a large-area graphene device has been strongly required. Here we show that the adsorptions of a metal and a molecule can manipulate the carrier concentration of single-layer graphene, epitaxially grown on SiC, which was directly observed using angle-resolve photoemission spectroscopy. These results will shed light on the researches for the very large scale integration of a graphene device. Furthermore, the carrier concentration changes can be applied to a highly sensitive gas sensor or a detector for an specific binding between an antigen and an antibody.

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