• Title/Summary/Keyword: photocatalytic cement

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Strength Properties of Fine Dust Adsorption Matrix using Photocatalyst TiO2 Rutile Replacement Ratio (광촉매 TiO2 루타일 타입 치환율에 따른 미세먼지 흡착형 경화체의 강도 특성)

  • Kyoung, In-Soo;Lee, Won-Gyu;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.174-175
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    • 2019
  • Recently, due to air pollution caused by fine dust, it is considered as a social problem. Increasing fine dust has intensified air pollution, causing many diseases and damages. This year, Seoul, South Korea, reached a severe level of fine dust pollution worldwide. The Ministry of Environment has strengthened the environmental standard for fine dust (PM2.5) from $50{\mu}g/m^3$ to $35{\mu}g/m^3$ since March 2018. When fine dust enters the human body, it causes bronchial or skin elongation such as respiratory allergies, irritable pneumonia, asthma and atopy. In this study, $TiO_2$ rutile with photocatalytic activity was used, and materials prepared by rutile sulfuric acid method were used. The photocatalytic activity rate is 95% or more and the density is $4.1g/cm^3$. The matrix was based on cement, and the substitution rate of $TiO_2$ was 0, 5, 10, 15, 20 (%). The test item is flexural strength and compressive strength.

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Improvement of Nitrogen Oxide Removal of Concrete Sidewalk Block Using by Conductive Photocatalyst (전도성 광촉매를 이용한 콘크리트 블록의 대기중 질소산화물 저감에 관한 연구)

  • Geun-Guk Bae;In-Sook Cho;Yong-Sik Ahn
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.493-500
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    • 2023
  • The use of TiO2 photocatalyst in the production of concrete blocks for the purpose of nitrogen oxide reduction is an issue of controversy due to the conflicting evidence on its effectiveness. Efforts have been made to reduce the level of nitrogen oxides in the environment by using of titanium dioxide (TiO2). This study examined the effect of incorporating activated carbon into concrete blocks on the reduction of nitrogen oxides released into the atmosphere and the durability of the blocks. The efficiency of photocatalyst was enhanced through the addition of a surrounding conductive substance. The addition of activated carbon resulted in a significant increase in the electrical conductivity of photocatalytic blocks and improved durability. The cement mixture using 5 % TiO2 and 15 % activated carbon exhibited the optimal mixing ratio for the purpose of nitrogen oxide removal. The effect of the addition of conductive carbon to the photocatalytic blocks was discussed with the results of conductivity, flexural and comprssive strength and nitrogen oxide removal test. The relationship between the addition of conductive carbon to the photocatalytic blocks and its resulting effects have been studied by several tests, including conductivity, flexural and compressive strength, and nitrogen oxide removal.

A Study on The Air Pollution Reduction Performance of Mortar Coated with Photocatalyst (광촉매를 코팅한 모르타르의 미세먼지 저감 성능 연구)

  • Seung-Jin Lee;Min-Ki Jeon;Seung-Tae Jeong;In-Hwan Yang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.1
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    • pp.94-101
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    • 2024
  • In this paper, the performance of air pollution reduction by coating the photocatalyst solution on the mortar surface was analyzed to ensure the possibility of applying the photocatalyst to structures with a large specific surface area. The photocatalytic concentrations of the coating solution were set to 1.5 % and 3.0 %, and the types of binders were considered as experimental variables, such as ultra-high performance concrete (UHPC), ordinary portland cement (OPC), and blast furnace slag. As the photocatalyst concentration increases, the air pollution reduction performance increases. In addition, as a result of the air pollution reduction performance, the NOx concentration reduction rate was the highest for UHPC, and the air pollution reduction performance increased as the blast furnace slag was replaced. Therefore, the amount of TiO2 remaining on the surface varies depending on the density of the tissue due to the difference in particles caused by the difference in the amount of TiO2 remaining on the surface.

Evaluation of NOx Reduction Performance by Photocatalytic (TiO2) Coating of Cement Mortar Mixed with Zeolite and Activate Hwangtoh (제올라이트와 활성 황토를 혼입한 시멘트 모르타르의 광촉매(TiO2) 코팅에 따른 NOx 저감성능평가)

  • Park, Jang-Hyun;Kim, Hyeok-Jung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.483-489
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    • 2020
  • Particulate matter is divided into PM10 (particle diameter of 10 ㎛ or less) and PM2.5 (particle diameter of 2.5 ㎛ or less), which are approximately 1/5 of the thickness of the hair. Due to its effect on the human body, lung disease, arteriosclerosis and heart It is known as a carcinogen that causes various diseases such as diseases. It is known that the main cause of such fine dust is nitrogen dioxide (NOx), which is emitted from automobiles in about 57.3% of urban roadsides. Therefore, in this study, as part of the development of functional construction materials to reduce NOx generated from road transport pollutants, comparative evaluation of NOx reduction performance was conducted according to the replacement rate of cement mortar in which cement was replaced with a porous material. In addition, the NOx reduction performance of cement mortar according to the photocatalyst application method and the number of applications was compared an d evaluated. As a result of the experiment, when activated ocher was substituted by 30%, it showed a reduction effect of about 32.7%, showing the best reduction performance.

A Study on the Reduced Rebound Method of Surface Finishing Spray Photocatalytic Mortar (표면 마감 광촉매 스프레이 모르타르의 리바운드량 저감 방안 연구)

  • Baek, Hyo-Seon;Park, Jeong-Hwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.9
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    • pp.604-609
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    • 2020
  • There are various methods of finishing concrete surfaces, and when considering workability, the spray method is effective, but rebound occurs. The allocation of rebound occurrence control should be adjusted according to the materials used. Thus, a basic study was conducted on multiple techniques for reducing the rebound incidence that are suitable for surface finishing materials containing a photocatalyst. A prior study derived the reduction effect and optimal mix ratio for photocatalytic performance. Based on that study, the rebound reduction was verified according to the specifications of the content and the mechanical durability characteristics of the mixed materials. Rebound, compressive strength, flexural rigidity, and table flow tests were done. The flow was fixed at 170±10 mm considering the workability of the mortar spray equipment. For the experimental variables, the rebound number was adjusted to the silica sand variables relative to the cement weight, and silica sands No. 5 and No. 7 were used. The results show the highest compression strength in the final S-1 variable, and the amount of rebound was minimized. These results were sufficiently filled with the bindings of the silica pores, which increased the binding force between the aggregates, resulting in a lower amount of rebound.

An Overview on the Physicochemical Properties and Photocatalytic Pollutant Removal Performances of TiO2-incorporated Cementitious Composites (TiO2 혼입 시멘트 복합체의 물리·화학적 특성 및 광촉매 반응을 이용한 오염물 제거 성능에 대한 개요)

  • Seo, J.H.;Yoon, H.N.;Kim, S.H.;Bae, S.J.;Jang, D.I.;Kil, T.G.;Park, S.M.;Lee, H.K.
    • Composites Research
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    • v.33 no.2
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    • pp.68-75
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    • 2020
  • Recently, the use of TiO2 as a phtocatalyst has been diversely investigated due to its excellent durability performance and high photocatalytic reaction efficiency. Active researches have particularly focused on the development of TiO2-incorporated cementitious composites in order to remove the atmospheric pollutants. Furthermore, the potential utilization of TiO2-incorporated cementitious composites as road accessories such as tunnels, road median separators and soundproof walls in the form of tiles, blocks and structural components has been widely examined. In this regard, a thorough understanding on the material characteristics of TiO2-incorporated cementitious composites should be preceded. The present overview article, therefore, revisits previous studies of TiO2-incorporated cementitious composites and summarizes their various physicochemical properties and atmospheric pollutants removal performance.

Sensitivity of NOx Removal on Recycled TiO2 in Cement Mortar (재생 이산화티탄을 혼입한 모르타르의 NOx 저감률 민감도 분석)

  • Rhee, Inkyu;Kim, Jin-Hee;Kim, Jong-Ho;Roh, Young-Sook
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.388-395
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    • 2016
  • This paper explores the photocatalytic sensitivity of cement mortar incorporated with recycled $TiO_2$ from waste water sludge. Basically, $TiO_2$ cluster sank down slowly to the bottom of cement mortar specimen before setting and hardening process. This leads the mismatch of $TiO_2$ concentration on the top and the bottom faces of a specimen. This poorly dispersed $TiO_2$-cement mortar naturally exhibits poor NOx removal efficiency especially on the top of cementitious structure. In architectural engineering application such as building or housing structures, one can simply filp over from the bottom so that more $TiO_2$ concentrated surface can be placed outward into the air. However, in highway pavement case, this could not be applicable due to in-situ installation of concrete pavement. Hence, the dispersion of $TiO_2$ cluster inside the cementitous material is getting important issue onto road construction application. To elaborate this issue, according to our results, silica fume, high-ranged water reducer, viscosity agent, blast furnace slag were not enhanced much of dispersion characteristics of $TiO_2$ cluster. The combination of foaming agent and accelerator of hardening with viscosity agent and small grain size of fine aggregate may help the dispersion of $TiO_2$ inside cementitious materials. Even though the enhanced dispersion were applied to the specimen, NOx removal efficiency doest not change much for the top surface of the specimen. This concurrently affected by the presence of tiny air voids and the dispersion of $TiO_2$ in that these voids could easily adsorbed NOx gas with the aid of large surface area.