• 한국정보디스플레이학회:학술대회논문집
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• 2008.10a
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• pp.989-992
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• 2008

X-ray lithography is one of the most powerful processes in the fabrication of nano/micro structures with a high aspect ratio. This process enables the fabrication of ultra-thin barrier ribs for PDP using X-ray sensitive paste. In this paper, organic material including photo-monomers, photo-oligomers, binder polymer and additives as well as inorganic powders with different size were optimized to fabricate high aspect ratio barrier rib pattern for PDP.

• Polymer(Korea)
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• v.35 no.5
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• pp.493-498
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• 2011

Reactive mesogens were used to prepare photo-cured liquid crystal films in which orientations of liquid crystal molecules were preserved by crosslinked networks of cured reactive mesogens. The molecular orientations of liquid crystal mixtures of photo-reative mesogens and non-reactive nematic liquid crystals were studied and compared before and after curing reactions. The effects of temperature and the amount of the non-reactive nematic liquid crystal in the mixture on birefringence of the liquid crystal films were investigated. It was found that optical compensation films with different birefringence could be prepared by controlling the amount of the nematic liquid crystals in the reactive mesogen mixtures.

• Macromolecular Research
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• v.12 no.2
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• pp.195-205
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• 2004

We have synthesized new aromatic polyesters (DiPEG-HQ and DiPEG-BP) by condensation polymerization of a terephthalic acid derivative bearing a pendant oligo(oxyethylene) (DP = 7, MW = 350), which has a methoxy terminal group, and two different aromatic diols, hydroquinone and 4,4'-biphenoI. The synthesized polymers were characterized by differential scanning calorimetry (DSC), polarizing microscopy, and X-ray diffractometry for their liquid crystallinity (LC), thermal transitions, and structural morphologies in mesophases. The morphology of the LC phases depends strongly on the length of the rigid backbone repeating unit. The DiPEG-BP polymer having a longer repeating unit exhibits both layered and nematic structures before isotropization, whereas the DiPEG-HQ polymer having a shorter repeating unit shows only the layered structure in the mesophase. We found that the layer spacing for DiPEG-HQ is larger than that for DiPEG-BP. Both polymers easily form complexes with LiCF$_3$SO$_3$; we studied this complex formation by FT-IR spectroscopy. The layer spacing of the polymer-electrolyte composites increases upon increasing the amount of the lithium salt. The polymer/salt electrolyte mixtures we investigated at molar ratios of EO:salt in the range of 5-20 exhibit electrical conductivity values at 40$^{\circ}C$ of 2.4${\times}$10$\^$5/ and 1.1${\times}$10$\^$－5/ S/cm for DiPEG-HQ/LiCF$_3$SO$_3$ and DiPEG-BP/LiCF$_3$SO$_3$, respectively. At 80 $^{\circ}C$, these values are higher: 4.6${\times}$10$\^$－3/ and 1.1${\times}$10$\^$－4/ S/cm, respectively. The activation energy of conductivity depends strongly on the salt concentration.

• Journal of Adhesion and Interface
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• v.13 no.1
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• pp.31-37
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• 2012

In this study, we investigated the curing properties of UV-LED curable color coating. Specially, the effects of UV-LED wavelength (365, 395, and 405 nm), inert gas, the concentration of photosensitizer, and dual curing on the curing behavior of UV-LED coating systems were studied. The photopolymerization behaviors and the unreacted acrylate groups at Film-air (FA) interface and Film-substrate (FS) interface were investigated by photo differential scanning calorimetry (Photo-DSC) and Fourier-transform infrared spectroscopy with attenuated total reflection (FT-IR/ATR), respectively. Photo-DSC results showed that the heat flow and the ultimate conversion for coating system cured by 405 nm UV-LED were higher than the corresponding values for coating systems cured by 395 and 365 nm UV-LED. FT-IR/ATR results showed that the UV-LED curing systems improved interior and through curing of the coating film, but significantly are affected by oxygen inhibition at FA-interface. The inert environment such as nitrogen purging and the dual curing improved the surface and interior curing of the coating films.

• Proceedings of the Optical Society of Korea Conference
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• 1997.08a
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• pp.90-90
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• 1997

• Polymer(Korea)
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• v.37 no.5
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• pp.638-641
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• 2013

GNS/PVDF composites were prepared using graphite nanosheets (GNS) and poly(vinylidene fluoride) (PVDF) for flexible thermoelectric application. We measured the electrical conductivity, thermal conductivity and Seebeck coefficient of GNS/PVDF composites with different contents of GNS and then evaluated the thermoelectric properties of GNS/PVDF composites. The electrical conductivity of GNS/PVDF composites increased from 389 to 1512 S/m with increasing the content of GNS from 10 to 70 wt%. While the electrical conductivity dramatically increased, Seebeck coefficient and thermal conductivity did not show any big difference as the content of GNS increases. In this study, we demonstrated that GNS/PVDF composites improved the thermoelectric properties by decreasing the thermal conductivity due to the phonon scattering at the interfaces between polymer and GNS nanoplatelets.

• Proceedings of the KIEE Conference
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• 1998.07d
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• pp.1385-1387
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• 1998

In this paper, we studied the electro-optical(EO) performance of photo-aligned twisted nematic(TN)-liquid crystal display(LCD) with oblique non-polarized ultraviolet (UV) light irradiation on polyimide (PI) surface. The monodomain alignment of photo-aligned TN-LCD is obtained with an angle of incidence of $85^{\circ}$ on PI surface. Also, we observed that the voltage transmittance and response time characteristics of photo-aligned TN-LCD is almost same compared to rubbing treated TN-LCD. Finally, we measured that the voltage-holding-ratio(VHR) of photo-aligned TN-LCD is almost same compared to rubbing treated TN-LCD.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.13 no.1
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• pp.75-79
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• 2000

In this study, we investigated the pretilt angle generation and liquid crystal (LC) alignment by ultravi-olet (UV) light irradiation during imidization of polymide. The generated pretilt angle of nematic (N) LC by using the in-situ photo-alignment method was smaller than that of the conventional UV photo-alignment method. Also, generated pretilt angle of NLC tends to increase by annealing. In case of using the polymer(AL-3046), we found that the in-situ Uv photo-alignment method has higher thermal stability of LC alignment, but it has a disadvantage to control pretilt angle.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.11 no.10
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• pp.911-917
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• 1998

In this paper, we have investigated the generation of pretilt angle for nematic liquid crystal (NLC) in a cell with oblique non-polarized ultraviolet(UV) light irradiation polyimide (PI) surface. It was found that the monodomain alignment of the NLC is obtained with an angle of incidence of 70∼85。 on PI surface. It is considered that the monodomain alignment of NLC is attributed to anisotropic of NLC is about 3。 with and angle of incidence of 70∼75。. Finally, we observed that the voltage-transmittance, response time, and voltage-holding-ratio(VHR) characteristics of photo-aligned twisted nematic(TN)-LCD with and angle of incidence of 85。 on PI surface were almost same compared to rubbing -treated TN-LCD.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.13 no.11
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• pp.950-953
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• 2000

Aligning capabilities of nematic liquid crystal(NLC) using an in-situ photo-alignment method with obliquely polarized UV exposure on a polyimide (PI) surface for homeotropic alignment were studied. The high angle for NLC can be measured by obliquely UV exposure of 30°on the PI surface for 10∼20 min. The pretilt angle of NLC generated using the in-situ photo-alignment was higher than that of a conventional photo-alignment method. Finally, we suggest that the control of pretilt angle in NLC with obliquely polarized UV exposure during imidization of the polymer for homeotropic alignment is promising method to generate high pretilt angle.