• Title/Summary/Keyword: photo-irradiation

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Electro-optical properties of photo-aligned VA-LCD by irradiation of unpolarized UV light. (비편광 UV조사에 의한 광배향 VA-LCD의 전기광학특성)

  • 박두석;서대식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.545-548
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    • 1999
  • The electro-optical characteristics of photo-aligned vertical-alignment (VA)-liquid crystal display (LCD) with non-polarized ultraviolet (UV) light irradiation of 45\`on homeotropic polyimide (Pl) surface were investigated. LC alignment on photo-aligned VA-LCD is attributed to photo-depolymerized reaction of the polymer with non-polarized UV light irradiation on PI surface. We had good voltage-transmittance (V-T) characteristics of photo-aligned VA-LCD. The response time of photo-aligned VA-LCD was slower than that of the rubbing-aligned VA-LCD. Finally, we suggest that the slow response time of photo-aligned VA-LCD depends on the LC domain.

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Electro-optical (EO) characteristics of photo-aligned TN-LCD on PM4Ch surfaces (PM4Ch 표면을 이용한 광배향 TN-LCD의 전기광학특성)

  • Hwang, Jeoung-Yeon;Park, Sang-Gun;Park, Tae-Kyu;Seo, Dae-Shik;Suh, Dong-Hack
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1765-1767
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    • 1999
  • We synthesised a photo-alignment material of PM4Ch (poly(4-methacryloylloxychalcone)). The electro-optical (EO) characteristics of photo-aligned twisted nematic (TN)-liquid crystal display (LCD) with linearly polarized ultraviolet (UV) light irradiation on PM4Ch surface were investigated. The uniform alignment of NLC with polarized UV light irradiation on PM4Ch surface was measured. Also, We had The excellent voltage-transmittance characteristics of photo-aligned TN-LCD. The low threshold voltage of photo-aligned TN-LCD was measured. Moreover, the fast response time of photo-aligned TN-LCD on PM4Ch was successfully achieved. Finally The reduction DC voltage of photo-aligned TN-LCD decreases with increasing the UV light irradiation time on photo-dimerized PM4Ch surface.

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Thermal and Photochemistry of Methyl Iodide on Ice Film Grown on Cu(111)

  • Sohn, Young-Ku;White, John M.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1470-1474
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    • 2009
  • Thermal and photochemistry of methyl iodide ($CH_3I)\;adsorbed\;on\;D_2O$ ice film on Cu(111) at 100 K were studied using temperature-programmed desorption (TPD) time-of-flight mass spectrometry (TOF-MS), X-ray and ultraviolet photoelectron spectroscopies. On the basis of TPD, multilayer and monolayer $CH_3I$ molecules desorb from $D_2O$ ice layer at 120 and 130 K, respectively. Photo-irradiation at 100 K exhibits dramatic changes in the TPD and I $3d_{5/2}\;XPS\;of\;CH_3I$ on ice film, due to a dramatic dissociation of $CH_3I$. The dissociation is likely activated by solvated electrons transferred from the metal substrate during photo-irradiation. No other photo-initiated reaction products were found within our instrumental detection limit. During photo-irradiation, the $CH_3I$, $CH_3$ and I could be trapped (or solvated) in ice film by rearrangement (and self-diffusion) of water molecules. A newly appeared parent molecular desorption peak at 145 K is attributed to trapped $CH_3I$. In addition, the $CH_3$ and I may diffuse through ice and chemisorb on Cu(111), indicated by TPD and I $d_{5/2}$ XPS taken with photo-irradiation time, respectively. No molecular ejection was found during photo-irradiation at 100 K. The work functions for $CH_3I/Cu(111),\;D_2O/Cu(111)\;and\;CH_3I/D_2$O/Cu(111) were all measured to be about 3.9 eV, 1.0 eV downward shift from that of clean Cu(111).

Liquid crystal alignment by photo-dimerization reaction of PCEMA photo polymer (PCEMA 광폴리머의 광중합 작용을 이용한 액정배향)

  • 황정연;서대식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.541-544
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    • 1999
  • We synthesised a novel photo-alignment material of PCEMA (poly(cinnamolyethyl methacrylate)) on photo-dimerization reaction. Next we investigated the electro-optical (EO) characteristics of photo-aligned twisted nematic (TN)-liquid crystal display (LCD) with linearly polarized ultraviolet (UV) light irradiation on PCEHA surface. The excellent voltage-transmittance characteristics of photo-aligned TN-LCD on PCEMA surface were obtained. The threshold voltage of photo-aligned TN-LCD decreases with increasing the UV light irradiation time on PCEMA surface. Also, the response time of photo-aligned TN-LCD on PCEMA surface is almost the same as rubbing-aligned TN-LCD.

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Electro-optical performance of TN-LCD using linearly polarized UV light irradiation on po1ymide surface (폴리이미드막에 직선편광된 자외선조사를 이용한 TN-LCD의 전기광학특성의 평가)

  • 서대식;이창훈;이정호;문학룡
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.109-112
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    • 1998
  • In this paper, we studied on electro-optical (EO) characteristics of photo-aligned twisted nematic (TN)-LCD. We obtained that uniform LC alignment in TN-LCD with linearly polarized ultraviolet (LPUV) light irradiation on polyimide (PI) surface increases according to increasing irradiation time for 10 to 60 min. The voltage-transmittance and response time characteristics of photo-aligned TN-LCD with UV light irradiation time of 60 min were almost same in comparison with conventional TN-LCD were observed. From the results, we suggest that photo-aligned TN-LCD with LPUV light irradiation on PI surface is useful in applying LCD as for rubbing-free treatment method.

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Control of the Photo-induced Discoloration of the Handmade Korean Paper with Polyethylene Glycol (Polyethylene Glycol에 의한 수록한지(手漉韓紙)의 광(光) 변색(變色) 억제(抑制))

  • Cheon, Cheol;Park, Soo-Ahn
    • Journal of Korean Society of Forest Science
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    • v.89 no.2
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    • pp.161-166
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    • 2000
  • Classified handmade Korean paper which has been commonly used as the material for the paper cultural assets divide into four classes. We irradiated xenon arc lamp, which has almost the same spectrum distribution as natural sunlight, to test photo-induced of discoloration according to PEG molecular weight and concentration. So, we reach the followings. 1) Unbleached handmade Korean paper with PEG showed rapid decrease of brightness for 10 hours after photo-irradiation, regardless of molecular weight of PEG, but, after 10 hours, it showed gradual increase of brightness. From this, it proved that there was an effect of preventing discoloration of photo-irradiation. 2) Chemical bleached handmade Korean paper showed increase of brightness after 20 hours. Though time was delayed in increase of brightness, there was also an effect of preventing discoloration of photo-irradiation in chemical bleached paper. 3) Handmade Korean paper made with abet-mosk showed the lowest of brightness when it was tested on 400-20% PEG. Before photo-irradiation, the brightness of paper, applied it, was the lowest, but it showed the least difference of brightness after photo-irradiation. From this, it proved that there was the greatest effect of preventing discoloration in this paper. 4) Preventing yellowish, the first phenomena by photo-irradiation ageing with applying PEG was proved that there was the decrease of value of $b^*$ +, and increase value of $L^*$, which could fairly prevent decrease of brightness.

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Ellipso-Microscopic Observation of Titanium Surface under UV-Light Irradiation

  • Fushimi, K.;Kurauchi, K.;Nakanishi, T.;Hasegawa, Y.;Ueda, M.;Ohtsuka, T.
    • Corrosion Science and Technology
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    • v.15 no.6
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    • pp.265-270
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    • 2016
  • The ellipso-microscopic observation of a titanium surface undergoing anodization in $0.05mol\;dm^{-3}$ of $H_2SO_4$ was conducted. During irradiation by ultra-violet (UV) light with a wavelength of 325 nm, the titanium surface allowed for the flow of a photo-induced current and showed up as a bright, patch-like image on an ellipso-microscopic view. The brightness and patch-pattern in the image changed with flowing photo-induced current. The changes in the brightness and the image corresponded to the formation and/or degradation of titanium oxide due to the photo-electrochemical reaction of the oxide. An in situ monitoring using the ellipso-microscope revealed that the film change was dependent on the irradiation light power, by UV-light increases the anodic current and results in the initiation of pitting at lower potentials as compared with the non-irradiated condition.

Hydrophilic Modification of Poly(ethylene oxide) by UV Irradiation

  • Koo, Gwang-Hoe;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.21 no.5
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    • pp.16-20
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    • 2009
  • Films of Poly(ethylene oxide), PEO, were modified to impart hydrophilicity via UV irradiation. The UV irradiation treatment produced new photo-oxidized groups of carbonyl and ether groups as indicated in ATR and ESCA analysis. It was found that water contact angle decreased from $15^{\circ}C$ to $10^{\circ}C$ and total surface energy of PEO increased from 54.2 mN/m to 76.6 mN/m with increasing UV energy, which was attributed to significant contribution of acid base interaction of the photo-oxidized PEO rather than nonpolar interaction originating from the dominant increase in Lewis acid parameter. The increased hydrophilicity and surface energy were also proved by the decreased water wetting time.

Electro-optical performance of TN-LCD wish oblique UV light irradiation on polyimide surface (경사진 자외선 조사를 이용한 TN-LCD의 전기광학 특성)

  • 서대식;박두석;한정민;황율연;박태규
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.113-116
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    • 1998
  • In this paper, we studied the electro-optical(EO) performance of photo-aligned twisted nematic(TN)-liquid crystal display(LCD) with oblique non-polarized ultraviolet(UV) light irradiation on polyimide(Pl) surface. We observed that the voltage-transmittance and response time characteristics of photo-aligned TN-LCD is almost same compared to conventional TN-LCD. Also, we observed that the voltage-holding-ratio(VHR) of photo-aligned TN-LCD is almost same compared to conventional TN-LCD.

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The improvement of characteristics for hydrogenated amorphous silicon thin films by photo-induced CVD (광 CVD에 의한 비정질 실리콘 박막 특성 향상)

  • 김용상;이성규;전명철;박진석;한민구
    • Electrical & Electronic Materials
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    • v.7 no.2
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    • pp.94-99
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    • 1994
  • The purpose of this work is to investigate the interface characteristics of hydrogenated amorphous silicon thin films prepared by PECVD and photo-induced CVD and to examine the annealing effects of ultraviolet irradiation on hydrogenated amorphous silicon thin films which were degraded by visible light illumination. The interface layer thickness of films deposited by photo-induced CVD was about 600-900.angs. while that by PECVD was about 1000-1300.angs.. These results can show that the quality of interface layer in photo induced CVD film is better than that in PECVD sample. The electrical properties are improved by ultraviolet irradiation on visible light soaked a-Si:H films using photo-CVD light sources, probably due to the fact that UV generates phonons in a-Si:H films and anneal the meta stable defects.

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