• Title/Summary/Keyword: phosphorus acid

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Effects of Benzoic Acid and Dietary Calcium:Phosphorus Ratio on Performance and Mineral Metabolism of Weanling Pigs

  • Gutzwiller, A.;Schlegel, P.;Guggisberg, D.;Stoll, P.
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.4
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    • pp.530-536
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    • 2014
  • In a $2{\times}2$ factorial experiment the hypotheses tested were that the metabolic acid load caused by benzoic acid (BA) added to the feed affects bone mineralization of weanling pigs, and that a wide dietary calcium (Ca) to phosphorus (P) ratio in phytase-supplemented feeds with a marginal P concentration has a positive effect on bone mineralization. The four experimental diets, which contained 0.4% P and were supplemented with 1,000 FTU phytase/kg, contained either 5 g BA/kg or no BA and either 0.77% Ca or 0.57% Ca. The 68 four-week-old Large White pigs were fed the experimental diets ad libitum for six weeks and were then slaughtered. Benzoic acid increased feed intake (p = 0.009) and growth rate (p = 0.051), but did not influence the feed conversion ratio (p>0.10). Benzoic acid decreased the pH of the urine (p = 0.031), but did not affect breaking strength and mineralization of the tibia (p>0.10). The wide Ca:P ratio decreased feed intake (p = 0.034) and growth rate (p = 0.007) and impaired feed the conversion ratio (p = 0.027), but increased the mineral concentration in the fat-free DM of the tibia (p = 0.013) without influencing its breaking strength (p>0.10). The observed positive effect of the wide Ca:P ratio on bone mineralization may be attributed, at least in part, to the impaired feed conversion ratio, i.e. to the higher feed intake and consequently to the higher mineral intake per kg BW gain. The negative impact on animal performance of the wide dietary Ca:P ratio outweighs its potentially positive effect on bone mineralization, precluding its implementation under practical feeding conditions.

Effect of catalyst poison agents on the hydrogenation of soybean oil (촉매독이 대두유의 경화에 미치는 영향)

  • Lee, Sur-Koo;Kim, Chang-Sik
    • Applied Biological Chemistry
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    • v.36 no.2
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    • pp.93-98
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    • 1993
  • The purpose of this study is to determine the physicochemical properties in soybean oil during the hydrogenation by addition of phosphorus compounds and sulfur compounds is increased in soybean oil, decreased oleic acid and increased linoleic acid and stearic acid contents were found. When the sulfur compounds content is increased, solid fat content is increased at $10.0^{\circ}C$ and $21.1^{\circ}C$ and gradually decreased at $33.3^{\circ}C$ and $37.8^{\circ}C$. Higher melting point in hydrogenated soybean oil is observed on addition of phosphorus compounds compared to addition of sulfur compounds. When the sulfur compounds content is increased, conditions of selective hydrogenation are observed. Lead and arsenic are detected at a concentration of 0.01 ppm in a few kinds at each step of the refining process of soybean oil.

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Effects of Dietary Lysine and Microbial Phytase on Growth Performance and Nutrient Utilisation of Broiler Chickens

  • Selle, P.H.;Ravindran, V.;Ravindran, G.;Bryden, W.L.
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.7
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    • pp.1100-1107
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    • 2007
  • The effects of offering broilers phosphorus-adequate diets containing 10.0 and 11.8 g/kg lysine, without and with 500 FTU/kg exogenous phytase, on growth performance and nutrient utilisation were determined. Each of the four experimental diets was offered to 6 replicates of 10 birds from 7 to 28 days of age. Effects of treatment on performance, apparent metabolisable energy, apparent ileal digestibility of amino acids and bone mineralisation were examined. Both additional lysine and phytase supplementation improved (p<0.05) weight gain and feed efficiency, with interactions (p<0.05), as phytase responses were more pronounced in lysine-deficient diets. Phytase improved (p<0.05) apparent metabolisable energy, which was independent of the dietary lysine status. Bone mineralisation, as determined by percentage toe ash, was not affected by treatment, which confirms the phosphorus-adequate status of the diets. Phytase increased (p<0.05) the apparent ileal digestibility of the sixteen amino acids assessed. Unexpectedly, however, the dietary addition of 1.8 g/kg lysine, as lysine monohydrochloride, increased (p<0.05) the ileal digestibility of lysine per se and also that of isoleucine, methionine, phenylalanine, valine, aspartic acid, glutamic acid and tyrosine. In addition, there were significant interactions (p<0.05) between additional lysine and phytase supplementation for arginine, lysine, phenylalanine, aspartic acid, glutamic acid, glycine and serine digestibilities, with the effects of phytase being more pronounced in lysine-deficient diets. The possible mechanisms underlying the increases in amino acid digestibility in response to additional lysine and the interactions between lysine and microbial phytase in this regard are discussed. Also, consideration is given to the way in which phytate and phytase may influence ileal digestibility of amino acids.

Evaluation of Laver Growth Rate using Pyroligneous Acid (목초액유기산을 사용한 김의 성장률 평가)

  • Kim, U-Hang;Jo, Seong-Taek
    • Proceedings of KOSOMES biannual meeting
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    • 2004.11a
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    • pp.105-108
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    • 2004
  • Organic acid is made with carbonized organic acid that is produced from charcoal burning process. It is evaluated whether carbonized organic acid is able to removed Enteromorpha in the laboratory and Porphra aquaculture farm test. The optimum condition for Enteromorpha removal are revealed ten times dilution and ten second immersion. The mortality rate of Enteromorpha is $95\%$ and diatom-detaching rate is $100\%$ by the organic acid treatment. On the other hand, the mortality rate of Porphra is lower than $5%\$. It was measured that nitrogen was 0.175 mg/l and phosphorus was 0.0158 mg/l. Therefore, Concentration of nutrients were lower than being necessary to Porphra growth. Growth rate of Porphra was $12\%$ increased by organic acid treatment with carbonized organic acid added nutrient.

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New Synthetic Method of Aminophosphonic Acid via Amination of Organoboranes (유기 붕소 화합물의 아민화 반응을 이용한 Aminophosphonic Acid의 새로운 합성방법)

  • Kim, Sang Beom;Jo, Gyeong Yeon;Hong, Seok In
    • Journal of the Korean Chemical Society
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    • v.38 no.9
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    • pp.682-686
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    • 1994
  • New synthetic method of aminophosphonic acids by the amination of organoboranes containing phosphorus was developed. Thus, the hydroboration of diethyl 2-propenylphosphonate, diethyl 2-methyl-2-propenyl-phosphonate, diethyl 3-butenylphosphonate with borane-THF, followed by amination of the resulting organoboranes with hydroxylamine-O-sulfonic acid gave diethyl 3-aminopropylphosphonate, diethyl 3-amino-2-methyl-2-propylphosphonate and diethyl 4-aminobutylphosphonate, respectively. 3-Aminopropylphosphonic acid and 4-aminobutylphosphonic, acid were obtained by the hydrolysis of the corresponding esters, respectively.

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Application of Modified Polyesters Containing Phosphorus/Chlorine to PU Flame-Retardant Coatings (인과 염소 함유 변성폴리에스테르의 PU 난연도료에의 적용)

  • Park, Hong-Soo;Kim, Song-Hyoung;Hong, Seok-Young;Yoo, Gyu-Yeol;Ahn, Sung-Hwan;Hahm, Hyun-Sik;Kim, Seung-Jin;Kim, Young-Geun
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.1
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    • pp.31-46
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    • 2007
  • This study was focused on the maximization of flame-retardancy of polyesters by a synergism of simultaneously introduced chlorine and phosphorus into polymer chains of modified polyesters. To prepare modified polyesters, reaction intermediates, TD-adduct (prepared from trimethylolpropane/2,4-dichlorobenzoic acid (2,4-DCBA)) and TMBO (prepared from tetramethylene bis(orthophosphate)), were prepared first, then condensation polymerization of the prepared intermediates, adipic acid, and 1,4-butanediol were carried out. In the condensation polymerization, the content of phosphorus was fixed to be 2%, and the content of 2,4-DCBA that provides chlorine component was varied to be 10, 20, and 30wt%, and we designated the prepared modified polyesters containing chlorine and phosphorus as ABTT-10C, -20C, -30C. Two-component PU flame-retardant coatings (ABTTC, ABTTC-10C, ABTTC-20C, ABTTC-30C) were prepared by the curing of synthesized ABTTs with a curing agent of allophanate/trimer at room temperature. To examine the film properties of the prepared PU flame-retardant coatings, film specimens were prepared with the prepared coatings. The film properties of ABTTC, ABTTC-10C and ABTTC-20C, which contain 0, 10 and 20wt% 2,4-DCBA, respectively, were proved to be good, whereas the film properties of ABTTC-30C, which contains 30wt% 2,4-DCBA, was proved to be a little bit poor. Two kinds of flame retardancy tests, $^{\circ}45Meckel$ burner method and LOI method were performed. With the $^{\circ}45Meckel$ burner method, three flame-retardant coatings except ABTTC showed less than 3.4cm of char length, and showed less than 2 seconds of afterflaming and afterglow. From this result, the prepared flame-retardant coatings were proved to have the 1st grade flame retardancy. With the LOI method, the LOI values of the coatings containing more than 10wt% 2,4-DCBA were higher than 30%, which means that the coatings possess good flame retardancy. From these results, it was found that synergistic effect in flame retardancy was taken place by the introduced phosphorus and chlorine.

Studies on Drying Method of the Powder to Utilize Deteriorated Sweet Persimmon (파찌감 이용을 위한 분말화의 건조방법에 관한 연구)

  • 김성규;이용재;권오창;박윤문;김태춘;조영수
    • Food Science and Preservation
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    • v.7 no.4
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    • pp.389-394
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    • 2000
  • To utilize deteriorated sweet persimmon(Diospyros kaki T.) effectively, this study was investigated about the effective (Dying method of the powder. Chemical components, minerals, fatty acids and amino acids of hot-air dried and freeze dried conditions were determined Sample conditions used on analysis as follow; pretreatments of hot-air dry and freeze dry were soft, soft+peel, mixer, mixer+peel. The contents of crude protein, crude lipid, crude ash of hot-air dry were 0.9-1.1%,15.0-39.0% and 2.3-3.3%, respectively. And those of freeze dry were 1.3-2.2%, 27.-49.0% and 2.5%, respectively. Potassium, magnesium, phosphorus, calcium and sodium content in hot-air dry and freeze dry were high. Other minerals were less than 3.00ppm in all conditions. The major fatty acid contents were detected capric acid(C$\^$10:0/), lauric acid(C$\_$l2:0)/, tridecanoic acid(C$\_$13:00/), palmitic acid(C$\_$l6:00/), palmitoleic acid(C$\_$l6:1/), oleic acid(C$\_$18:1), linoleic acid(C$\_$18:2/), linolenic acid(C$\_$18:3/). The essential amino acids such as aspartic acid, threonine, serine, glutamic acid, glycine, alanine, valine, methirmine, isoleucine, leucine, tryosine, phenylalanine, histidine, lysine, arginine in freeze dry were contained richly. On the basis of chemical analysis, hot-air dry method will have to supply the additional different method, because simple hot-air dry method was shorten the dry time but had many problems. Therefore, the effective drying method considering changed color and nutrition was shown freeze dry method.

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Changes in components and sensory attribute of the oil extracted from perilla seed roasted at different roasting conditions (들깨의 볶음 조건에 따른 들기름의 성분 및 관능적 특성 변화)

  • Kim, In-Hwan;Jung, Sook-Young;Jo, Jae-Sun;Kim, Young-Eon
    • Applied Biological Chemistry
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    • v.39 no.2
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    • pp.118-122
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    • 1996
  • The main objectives of this study was to characterize physicochemical properties, oxidative stability and sensory property of perilla oil obtained by various roasting temperature and time. Roasting temperature of perilla seed was conducted from $150^{\circ}C\;to\;210^{\circ}C$ at the increment of $20^{\circ}C$, and roasting time was 10, 20 and 30 min. Yield of perilla oil was increased as the roasting temperature and time were increased. The content of linolenic acid, a major fatty acid in perilla oil, was 60%. There was no differences in fatty acid composition upon the roasting conditions. Unsaturated fatty acid was contained more than 88% of the total fatty acids. Contents of phosphorus in perilla oils were decreased as the roasting temperature and time were increased. Phosphorus contents were significantly decreased at $190^{\circ}C$ for 30 min and $210^{\circ}C\;for\;20{\sim}30$ min. Tocopherol contents were unchanged at the roasting conditions of present study and gamma-tocopherol was shown to be the major tocopherol. Sensory evaluation of perilla oil roasted in various conditions showed significant differences in taste, color, flavor and palatability. The perilla oil roasted at $190^{\circ}C$ for 20 min had the best palatability.

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Chemical Composition of Special Poultry (Pheasant, Chungdung Wild Duck, and Ogol Fowl) Meatp (특수가금(꿩, 청둥오리, 오골계)육의 영양성분)

  • Kim, Ki Jun;Oh, Hong Rock;Oh, Man Jin
    • Korean Journal of Agricultural Science
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    • v.23 no.1
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    • pp.90-98
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    • 1996
  • In order to obtain the basic information for new food product development from pheasant, wild duck(chhungdung), and Ogol fowl, which are called as special poultry, general components,fatty acid amino acid and minerals composition were analyzed. 1). The general compositions were 71.2-74.1% of water, 23.3-26.4% of protein, 1.0-2.4% fat, and 1.1-1.4% of ash in the pheasant, 73.8-76.4% of water, 18.6-19.6% of protein, 2.7-6.8% of fat, and 0.8-1.6% of ash in the wild duck, and 71.4-72.3% of water, 20.8-22.7% of protein, 1.9-6.3% of fat, and 1.0-1.2% of ash in the Ogol fowl, repectively. 2).In the pheasant and wild duck meat, the composition of unsaturated and saturated fatty acid were 60-64%,36-40%, respectively, and olec, palmitic, linolec, and stearic acid were most abundant in this order. But, in Ogol fowl, 72-76% and 24-28% were belong to the unsaturated fatty acid, respectively. 3). Amino acid contents in its order of relative amount were glutamic acid, alanine, aspatic acid, and glycine for the pheasant, glutamic acid, glycine, alanine, and aspatic acid for the wild duck, and lysine, glutamic acid, and aspatic acid for the Ogol fowl, repectively. 4).The mineral composition in the pheasant and wild duck were potassium, phosphorus, sodium, magnesium, and calcium, but in the Ogol fowl, potassium, sodium, magnesium, phosphorus, calcium were the most abundant in this order, repectively.

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Nutritional characteristics of horsemeat in comparison with those of beef and pork

  • Lee, Chong-Eon;Seong, Pil-Nam;Oh, Woon-Young;Ko, Moon-Suck;Kim, Kyu-Il;Jeong, Jae-Hong
    • Nutrition Research and Practice
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    • v.1 no.1
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    • pp.70-73
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    • 2007
  • This study was conducted to determine the nutritional characteristics of horsemeat and bone meal in comparison with those of beef and pork presented by Dietary Reference Intakes For Koreans. Longissimus muscle and large metacarpal bone samples were collected from 20 fattened Jeju horses. Muscle samples were subjected to proximate analysis, assays for fatty acid profile and minerals, and bone samples to mineral assays. Horsemeal had similar levels of protein (21.1 vs 21.0 or 21.1%) and lower levels of fat (6.0 vs 14.1 or 16.1%) compared with beef or pork, respectively. Horsemeat had much higher levels of palmitoleic (8.2 vs 4.4 or 3.3%) and $\alpha-linolenic$ (1.4 vs 0.1 or 0.6%) acids than beef or pork, respectively. Linoleic acid was much higher in horsemeat (11.1%) and pork (10.1%) than in beef (1.6%). PUFA:SFA and n-6:n-3 ratios in horsemeat were 0.29 and 10.2, respectively. There were no big differences in mineral contents between horsemeat, beef and pork. For daily recommended mineral intakes of male adults (Dietary Reference Intakes For Koreans), phosphorus, sodium, potassium, iron, zinc and copper can be provided up to 24, 2.5, 6.7, 21, 26 and 40%, respectively, by 100 g raw horsemeat, but calcium and manganese levels are negligible. Horse cannon bone had much higher mineral contents especially in calcium (10,193 mg/100 g), phosphorus (5,874 mg/100 g) and copper (0.79 mg/100 g). Thiamin, riboflavin, niacin and retinol contents were 0.20, 0.21, 1.65 mg/100 g and $30{\mu}g/100g$, respectively. But ascorbic acid and beta-carotene were not detected. Our data demonstrated that higher levels of palmitoleic and $\alpha-linolenic$ acid in horsemeat than in beef and pork may be beneficial for human health. Horsemeat and bone meal are a good source of some minerals and vitamins.