• 제목/요약/키워드: phosphor materials

검색결과 531건 처리시간 0.023초

Eu 도핑 SrAl2O4 형광체의 광 여기 전류 특성에 대한 Dy 코-도핑 효과 (Dy co-doping effect on photo-induced current properties of Eu-doped SrAl2O4 phosphor)

  • 김세기
    • 센서학회지
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    • 제18권1호
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    • pp.48-53
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    • 2009
  • $Eu^{2+}$-doped ${SrAl_2}{O_4}$ and $Eu^{2+}$, $Dy^{3+}$ co-doped ${SrAl_2}{O_4}$ phosphors have been synthesized by conventional solid state method. Photocurrent properties of $Eu^{2+}$ doped ${SrAl_2}{O_4}$ and $Eu^{2+}$, $Dy^{3+}$ co-doped ${SrAl_2}{O_4}$ phosphors, in order to elucidate $Dy^{3+}$ co-doping effect, during and after ceasing ultraviolet-ray (UV) irradiation have been investigated. The photocurrent of $Eu^{2+}$, $Dy^{3+}$ co-doped ${SrAl_2}{O_4}$ phosphors during UV irradiation was 4-times lower than that of $Eu^{2+}$-doped ${SrAl_2}{O_4}$ during UV irradiation, and 7-times higher than that of $Eu^{2+}$-doped ${SrAl_2}{O_4}$ after ceasing UV irradiation. The photocurrent results indicated that holes of charge carriers captured in hole trapping center during the UV irradiation and liberated after-glow process, and made clear that $Dy^{3+}$ of co-dopant acted as a hole trap. The photocurrent of ${SrAl_2}{O_4}$ showed a good proportional relationship to UV intensity in the range of $1{\sim}5mW/cm^2$, and $Eu^{2+}$-doped ${SrAl_2}{O_4}$ was confirmed to be a possible UV sensor.

ZnSe:Eu 양자점의 표면결함이 광학특성에 미치는 영향 (The Effect of Surface Defects on the Optical Properties of ZnSe:Eu Quantum Dots)

  • 정다운;박지영;서한욱;임경묵;성태연;김범성
    • 한국분말재료학회지
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    • 제23권5호
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    • pp.348-352
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    • 2016
  • Quantum dots (QDs) are capable of controlling the typical emission and absorption wavelengths because of the bandgap widening effect of nanometer-sized particles. These phosphor particles have been used in optical devices, photovoltaic devices, advanced display devices, and several biomedical complexes. In this study, we synthesize ZnSe QDs with controlled surface defects by a heating-up method. The optical properties of the synthesized particles are analyzed using UV-visible and photoluminescence (PL) measurements. Calculations indicate nearly monodisperse particles with a size of about 5.1 nm at $260^{\circ}C$ (full width at half maximum = 27.7 nm). Furthermore, the study results confirm that successful doping is achieved by adding $Eu^{3+}$ preparing the growth phase of the ZnSe:Eu QDs when heating-up method. Further, we investigate the correlation between the surface defects and the luminescent properties of the QDs.

The use of digital periapical radiographs to study the prevalence of alveolar domes

  • Xambre, Pedro Augusto Oliveira Santos;Valerio, Claudia Scigliano;Cardoso, Claudia Assuncao e Alves;Custodio, Antonio Luis Neto;Manzi, Flavio Ricardo
    • Imaging Science in Dentistry
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    • 제46권3호
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    • pp.179-184
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    • 2016
  • Purpose: In the present study, we coined the term 'alveolar dome' and aimed to demonstrate the prevalence of alveolar domes through digital periapical radiographs. Materials and Methods: This study examined 800 digital periapical radiographs in regard to the presence of alveolar domes. The periapical radiographs were acquired by a digital system using a photostimulable phosphor (PSP) plate. The ${\chi}^2$ test, with a significance level of 5%, was used to compare the prevalence of alveolar domes in the maxillary posterior teeth and, considering the same teeth, to verify the difference in the prevalence of dome-shaped phenomena between the roots. Results: The prevalence of alveolar domes present in the first pre-molars was statistically lower as compared to the other maxillary posterior teeth (p<0.05). No statistically significant difference was observed in the prevalence of alveolar domes between the maxillary first and second molars. Considering the maxillary first and second molars, it was observed that the palatal root presented a lower prevalence of alveolar domes when compared to the distobuccal and mesiobuccal roots (p<0.05). Conclusion: The present study coined the term 'alveolar dome', referring to the anatomical projection of the root into the floor of the maxillary sinus. The maxillary first and second molars presented a greater prevalence of alveolar domes, especially in the buccal roots, followed by the third molars and second pre-molars. Although the periapical radiograph is a two-dimensional method, it can provide dentists with the auxiliary information necessary to identify alveolar domes, thus improving diagnosis, planning, and treatment.

Research and Development of High Performance 50-inch HD Plasma Display Panel

  • Choi, Kwang-Yeol;Min, Woong-Kee;Rhee, Byung-Joon;Ahn, Byung-Nam;Kim, Je-Seok;Moon, Won-Seok;Park, Min-Soo;Ryu, Byung-Gil;Kim, Sung-Tae;Ahn, Young-Joon;Yang, Sung-Soo;Kim, Kyung-Tae;Lee, Kyu-Sung
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.1547-1550
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    • 2008
  • We are suggesting a new index to represent the performance of PDP, such as Specific Performance Index (SPI) that includes luminous efficacy and panel reflectance. High Xe gas mixture and low panel capacitance are well known as key factors to improve luminous efficacy of PDP [1]. However, higher driving voltage and longer discharge time lag is an obstacle when applying these technologies. Modified cell design, new materials and driving waveform enable us to overcome these obstacles. High efficient phosphor is also a key material to improve luminous efficacy. Phosphors coated with pigment are used to reduce panel reflectance. High performance 50-inch HD PDP with luminous efficacy of 2.3 lm/W has been developed.

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CuCl 농도에 따른 SrS:CuCl 박막 전계발광소자의 발광특성 (Luminescent Characteristics of SrS:CuCl Thin-Film Electroluminescent(TFEL) Devices on CuCl Concentrations)

  • 이순석;임성규
    • 대한전자공학회논문지SD
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    • 제39권8호
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    • pp.17-23
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    • 2002
  • 전자빔 증착 장비를 이용하여 SrS:CuCl TFEL 소자를 제작한 후, 발광특성을 조사하였다. 형광체 모체는 SrS 분말을 사용하였고, 발광중심체로는 CuCl 분말을 0.05 ~ 0.6 at% 범위에서 첨가하였다. 증착 온도 500℃, 전자빔 전류 20 ~ 40 mA 및 증착율 5 ~ 10 /sec의 조건에서 형광층 두께를 6000 으로 증착시켰다. CuCl 농도가 낮을 때에는 monomer, dimer, trimer 및 tetramer 발광센터에 의한 청색 발광을 확인할 수 있었으나 휘도가 낮았다. CuCl 농도가 높을 때에는 dimer와 trimer 발광센터에 의한 밝은 녹청색 빛을 방출하였다. 최적의 발광특성은 CuCl 농도를 0.2 at% 첨가한 SrS:CuCl TFEL 소자에서 관찰되었으며, 문턱전압, 휘도(L/sub 40/), 효율(η/sub 20/) 및 CIE 색좌표는 각각 55 V, 728 cd/㎡, 0.49 lm/W 및 (0.21, 0.33)을 나타내었다.

고상반응법에 의한 LiBaPO4:Eu2+ 계 형광체의 제조 및 광 발광 특성 (Preparation and Photoluminescence Properties of LiBaPO4:Eu2+ Phosphors by Solid State Reaction Method)

  • 박인용
    • 마이크로전자및패키징학회지
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    • 제26권4호
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    • pp.83-88
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    • 2019
  • 화학양론적 조성과 비화학양론적 조성을 갖는 LiBaPO4:Eu2+ 계 형광체를 고상반응으로 제조한 후 환원 분위기에서 열처리한 다음 분말의 결정구조와 광 특성을 X선 회절 분석과 발광 분석을 통하여 조사하였다. XRD 분석 결과, 900℃에서 중간상으로서 Ba3(PO4)2 상이 주 결정상 LiBaPO4와 함께 나타났다. 1,100℃에서 낮은 농도의 유로피움이 도핑된 조성의 결정구조는 삼방정(trigonal) 구조에 속하는 반면, 4 mol% Eu2+ 이상의 조성에서는 단사정(monoclinic) 계를 나타내었다. 4 mol% 이상의 Eu2+이 첨가된 비화학양론적 조성에서는 단일상의 LiBaPO4가 형성되었다. 단일상의 LiBaPO4:Eu2+ 계 형광체는 480nm에서의 청록색 발광스펙트럼을 나타내었다.

Preparation of SrGd2(MoO4)4:Er3+/Yb3+ Phosphors by the Microwave-Modified Sol-Gel Method and Their Upconversion Photoluminescence Properties

  • Lim, Chang Sung
    • 한국세라믹학회지
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    • 제51권6호
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    • pp.605-611
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    • 2014
  • $SrGd_{2-x}(MoO_4)_4:Er^{3+}/Yb^3$ phosphors with doping concentrations of $Er^{3+}$+ and $Yb^{3+}$ ($x=Er^{3+}+Yb^{3+}$, $Er^{3+}=0.05$, 0.1, 0.2, and $Yb^{3+}=0.2$, 0.45) were successfully synthesized by the cyclic microwave-modified sol-gel method, and their upconversion mechanism and spectroscopic properties have been investigated in detail. Well-crystallized particles showed a fine and homogeneous morphology with grain sizes of $2-5{\mu}m$. Under excitation at 980 nm, $SrGd_{1.7}(MoO_4)_4:Er_{0.1}Yb_{0.2}$ and $SrGd_{1.5}(MoO_4)_4:Er_{0.05}Yb_{0.45}$ particles exhibited a strong 525-nm emission band, a weak 550-nm emission band in the green region, and a very weak 655-nm emission band in the red region. The Raman spectra of the doped particles indicated the domination of strong peaks at higher frequencies of 1023, 1092, and $1325cm^{-1}$ and at lower frequencies of 223, 2932, 365, 428, 538, and $594cm^{-1}$ induced by the incorporation of the $Er^{3+}$+ and $Yb^{3+}$+ elements into the $Gd^{3+}$ site in the crystal lattice, which resulted in the unit cell shrinkage accompanying a new phase formation of the $[MoO_4]^{2-}$ groups.

Nb/Ni Clad 전극을 이용한 고효율 CCFL 개발 (Development of CCFL with Nb/Ni Gad Electrode for high efficiency)

  • 박기덕;양승수;박두성;김서윤;임영진
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.441-443
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    • 2005
  • According as CCFL(Cold Cathode Fluorescent lamp) of light source in Backlight unit for Note PC (Personal computer) is presently needed to low power consumption and long life time, the development focus of CCFL is going on the discharge gas, phosphor and electrode material. First of all, discharge voltage characteristic of CCFL is closely connected with electrode material For low discharge voltage, the characteristic of electrode material is needed to low work function, low sputtering ratio and superior manufacturing property. We developed new CCFL with Nb/Ni Clad electrode superior to conventional CCFL. Because Nb/Ni Clad electrode with Ni material and Nb material, the electrical characteristic is superior to other electrode materials. The electrode of Nb/Ni Clad is composed that Ni of outside material has superior manufacturing property and Nb of inside material has low work function. Nb/Ni Clad of new electrode material is made by process of Rolling mill at high pressure and heat treatment. We compared electrical characteristic of Nb/Ni clad electrode with conventional Mo electrode by measurement. Mo electrode and Nb/Ni Clad electrode of cup type with diameter 1.1 mm and length 3.0mm are used to this experiment. Material content of Mo electrode is Mo 100%. But, Nb/Ni Clad electrode is composed by content of Nb 40% and Ni 60%. The result of comparison measurement between new CCFL with Nb/Ni Clad electrode and conventional CCFL was appeared that CCFL with Nb/Ni Clad electrode had superior characteristic than conventional CCFL. As a result of experiment, we completed Note PC with low power consumption and long life time by application of new CCFL with Nb/Ni Clad electrode.

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The influence of different scan resolutions on the detection of proximal caries lesions

  • Ferreira, Liana Matos;Queiroz, Polyane Mazucatto;Santaella, Gustavo Machado;Wenzel, Ann;Groppo, Francisco Carlos;Haiter-Neto, Francisco
    • Imaging Science in Dentistry
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    • 제49권2호
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    • pp.97-102
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    • 2019
  • Purpose: This study was conducted to evaluate the effect of different spatial resolutions of a photostimulable phosphor plate (PSP) radiography system on the detection of proximal caries lesions. Materials and Methods: Forty-five extracted human permanent teeth were radiographed using a PSP system (VistaScan Perio Plus) and scanned at the 4 resolutions (10 lp/mm, 20 lp/mm, 25 lp/mm, and 40 lp/mm) available in the system. Three independent examiners scored the images for the presence and absence of proximal caries lesions using a 5-point scale. The presence or absence of caries was confirmed by histological sections of the examined teeth (defined as the gold standard). Intra- and inter-observer reproducibility was calculated by the weighted kappa test. One-way analysis of variance with the post hoc Tukey test was used to compare the area under the receiver operating characteristic curve for the classifications made with each resolution. Results: For the detection of enamel lesions, the spatial resolution of 10 lp/mm was significantly superior to the other resolutions. However, the spatial resolution did not affect the detection of caries lesions in dentin (P>0.05). Conclusion: Spatial resolution may influence the accuracy of the detection of incipient caries lesions in radiographs with PSP plates. Images with low spatial resolution seem to be more appropriate for this purpose.

BaWO4:Dy3+,Eu3+ 백색광 형광체의 발광 특성과 에너지 전달 효율 (Luminescent Properties and Energy Transfer Efficiency of BaWO4:Dy3+, Eu3+ White Light-Emitting Phosphors)

  • 조신호
    • 한국표면공학회지
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    • 제54권3호
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    • pp.112-118
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    • 2021
  • Dy3+- and Eu3+-codoped BaWO4 phosphors for white light-emitting diode were synthesized with different activator ions via a solid-state reaction process. The structural, morphological, and optical properties of the BaWO4:Dy3+,Eu3+ phosphors were investigated as a function of Eu3+ concentration at a fixed concentration of Dy3+ ions. XRD patterns exhibited that all the synthesized phosphors had a tetragonal system, irrespective of the concentrations of Dy3+ and Eu3+ ions. The excitation spectra of the synthesized phosphors were composed of three intense bands centered at 251, 355, and 393 nm and several weak peaks. For the BaWO4:Dy3+,Eu3+ phosphors synthesized with 1 mol% of Eu3+, the emission spectra under ultraviolet excitation at 393 nm showed two strong blue and yellow bands at 485 and 577 nm corresponding to the 4F9/26H15/2 and 4F9/26H13/2 transitions of Dy3+ ions, respectively and several weak bands in the range of 600-700 nm resulting from the 4f transitions of Eu3+ ions. As the concentration of Eu3+ ions increased, intensities of the blue and yellow emission bands gradually decreased while those of the red emissions increased rapidly and the energy transfer efficiency from Dy3+ to Eu3+ ions was 95.3% at 20 mol% of Eu3+. The optimum white light emission with x=0.363, y=0.357 CIE 1931 chromaticity coordinates was obtained for the sample doped with 5 mol% Dy3+ and 1 mol% of Eu3+.