• 콘크리트학회논문집
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• 제29권3호
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• pp.275-281
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• 2017

본 연구는 물-결합재비(water-to-binder ratio, W/B) 및 인산염-결합재비(phosphate-to-binder ratio, P/B)가 마그네시아-인산칼륨 시멘트(magnesium-potassium phosphate cement, MKPC) 모르타르의 플로, 응결시간, 압축강도발현 및 pH 변화에 미치는 영향성에 대한 평가이다. MKPC 모르타르의 P/B가 0.3 및 0.5일 때 W/B 범위 20~40%에 대하여 10 배합의 모르타르 실험을 실시하였으며, X-선 회절 분석(X-ray diffraction, XRD), 전자현미경(scanning electron microscope, SEM) 및 수은압입법(mercury intrusion porosimetry, MIP) 분석을 위해 MKPC의 반응생성물 및 미세공극분포를 평가하였다. 실험결과, MKPC 모르타르의 플로 및 응결시간은 P/B의 증가에 따라 감소하였으며, P/B가 0.3에서 0.5로 증가함에 따라 종결시간은 약 24% 감소하였다. MKPC 모르타르의 초기 압축강도 발현 기울기의 경우 콘크리트 구조기준에서 제시하는 시멘트 콘크리트 대비 높은 수준에 있었다. 재령 28일의 압축강도 30 MPa 이상 및 pH 9.0 이하를 만족하기 위해 MKPC 모르타르의 P/B 및 W/B는 각각 0.5이상 및 30% 이하가 추천된다. MKPC의 반응생성물인 스트루바이트(struvite)-K의 결정은 MKPC의 P/B 및 W/B가 높을수록 증가하였는데, 이로 인해 거대 모세관 공극은 감소하였다.

• 한국토양비료학회지
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• 제35권5호
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• pp.290-295
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• 2002

조립 복합비료의 증량제를 점토광물 대신 인광석분말로 대체하여 연초용 복합비료(10-0-30)조립시험을 수행했다. 황산칼리 60%, 요소 22%, 인광석 18%로 조성된 분말에 10% 인산액을 점결제로 조립한 결과 소량의 점결제로서 양호하게 조립되었으며 입자분포, 입자경도, 수중 붕괴도, 흡습성 등 물리성이 매우 이상적인 입자로 조사되었다. 담배직물을 묘상기, 본포기로 나누어 폿트 비효실험 결과 생육기간이 짧은 묘상에서는 시제품의 생육이 부진하였고 본포기 폿트 재배시험에서도 인산축적이 없는 개간지 토양에서는 생육이 부진하였으나 인산이 축적된 숙전에서는 정상적으로 생육하였다.

• 한국세라믹학회지
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• 제18권4호
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• pp.229-236
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• 1981

This study deals with the high temperature (600-135$0^{\circ}C$) properties of Kaolin-Phosphate-Water systems. Phosphoric acid, mono aluminum phosphate, mono ammonium phosphate, the mixture of phosphoric acid and mono aluminum phosphate, and the mixture of phosphoric acid and mono ammonium phosphate were used to characterize the M.O.R of the systems with to quantity of phosphates and firing temperature. Firing shrinkage, creeptest, DTA, TGA, and X-ray diffraction patterns were also measured in order to investigate the factors of strengthening. The resules of the experiments are as follows: 1. Linear shrinkage of kaolin-phosphate systems become larger as the firing temperature rise, and generally in the firing temperature of $600^{\circ}C$ and 100$0^{\circ}C$ the test pieces with phosphate binder show larger then Kaolin-Water system in linear shrinkage and reversed trends were found at 120$0^{\circ}C$ and 135$0^{\circ}C$. 2. Cold M.O.R. of kaolin-phosphate systems show higher trends in strength as the firing temperature rise. Comparing M.O.R. of test pieces after firing at 135$0^{\circ}C$, the mixture of phosphoric acid-mono aluminum phosphate, and phosphoric acid mono ammonium phosphate systems show higher strength than kaolin-mono aluminum phosphate system which widely used, and it shows highest strength when the mole ratio of phosphoric acid and mono ammonium phosphate is 1:1 among the test pieces of kaolin-phosphate systems. 3. The refractoriness of kaolin-phosphate systems are more deteriorated than Kaolin-Water system, and generally, the more addition of phosphate, the lower the refractoriness, however in the range of 4-8% phosphate addition, the difference of the fusion temperature is about 7$0^{\circ}C$. 4. The test pieces of T1 and T2 in creep test were same or even higher than kaolin-water system when 6% of phosphoric acid-mono ammonium phosphate was added to kaolin. 5. In case where the phosphoric acid-mono ammonium phosphate was added to kaolin in mole ratio 1:1 the cold M.O.R., after firing at 135$0^{\circ}C$, refractoriness and $T_2$ in creep test show better results than kaolin-mono-aluminum phosphate system which is widely used. 6. Phosphoric acid and mono ammonium phosphate react with kaolin in temperature over 100$0^{\circ}C$, and it forms aluminum phosphate.

• 한국구조물진단유지관리공학회 논문집
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• 제23권3호
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• pp.103-110
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• 2019

다양한 원인에 의한 포장체에 손상이 발생하면 신속한 통행재개를 위한 급속보수가 필요하게 된다. 산화마그네슘인산염복합체의는 경화시간이 짧고, 조기 강도발현이 가능하여 급속보수재료로 적합한 특성을 갖고 있다. 연구에서는 경소마그네시아와 제1인산칼륨을 결합하여 보수재료로 개발하기 위하여 물-결합재(W/B)비, 마그네슘-인산염(M/P)비 등의 배합비를 조정하면서 경화와 강도특성을 평가하고자 하였다. 그리고 현장 적용시의 작업성을 확보하기 위하여 표준사와 일반모래에 따른 거동차이와 지연제별 특성을 평가하였다. 실험결과 물-결합재비는 35%내외와 마그네슘-인산염비는 1.0~1.2 내외가 강도측면에서 가장 적합한 것으로 분석되었다. W/B비 0.35, M/P비 1.2 변수에서 1일 강도 25.0MPa 이상 발현되어 조기 보수재료로서 활용가능성이 충분한 것으로 분석되었다. 작업시간 확보를 위해서는 붕산을 지연제로 사용하는 것이 적합한 것으로 나타났으며, 산화마그네슘의 순도는 90~95%내외가 경화시간 확보를 위해 효과적인 것으로 나타났다.

• 한국구조물진단유지관리공학회 논문집
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• 제20권5호
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• pp.85-92
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• 2016

본 연구에서는 경량기포 콘크리트를 이용한 육성용 토양골재의 적용성을 평가하기 위해서 고로슬래그 기반 기포콘크리트의 총 8배합과 인공토양골재를 제조하였다. 고로슬래그 기반 기포콘크리트 배합의 주요변수는 단위결합재량으로서 100에서 $800kg/m^3$으로 변화하였다. 경량기포콘크리트는 플로우, 슬러리 및 절건 밀도와 재령별 압축강도를 측정하였으며, 파쇄된 인공토양골재는 pH, 입도분포, 투수계수, 양이온치환용량(CEC), 유기물함유량(C/N비)을 측정하였다. 측정결과 경량기포콘크리트의 플로우, 슬러리 및 절건밀도와 재령별 압축강도는 단위결합재량이 증가함에 따라 증가하였다. 경량기포콘크리트의 단위결합재량이 $500kg/m^3$ 이상인 배합의 28일 압축강도는 4 MPa 이상이었다. 인공토양골재에 3일 이상의 15% 희석된 제1인산암모늄의 수용액침지는 pH를 저감시키는데 효과적이었다. 또한 제조된 인공토양골재는 양이온 치환용량(CEC) 측면에서 상급으로 평가되었지만 C/N비 측면에서는 조경시방서를 만족시키지 못하였다.

• 한국주조공학회지
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• 제19권5호
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• pp.419-426
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• 1999

Hardening behavior and metal-mold reaction of phosphate bonded investments for titanium and titanium alloys were investigated. Alumina and $Y_2O_3-stabilized$ zirconia, which are thermodynamically more stable than Titania, were used as major filler materials. $NH_4H_2PO_4$ was used as binder, and MgO was used as hardening acceleration material. A different composition ratio of binder and hardening acceleration material had effected on general hardening behavior and castings. And adding $YO_3-stabilized$ zirconia to alumina, metal-mold reaction characteristics for castings was evaluated. Considering working conditions and effects on castings, the best composition ratio conditions were both 10:10 and 12:8($NH_4H_2PO_4vs.\;MgO$). On the other hand, increasing the contents of $Y_2O_3-stabilized$ zirconia for filler material, metal-mold reaction layer of titanium castings was greatly decreased.

• 한국주조공학회지
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• 제5권2호
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• pp.85-96
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• 1985

In order to investigate the effect of particle size and distribution of silica sand on the characteristics of investment, W/P ratio, setting time, temperature change during setting, setting expansion, thermal expansion and compressive strength of the investments were measured. In this experiment, magnesia clinker and mono ammonium phosphate were used as binder, and particle size and distribution of silica sand were classified for convinence into 10 categories. The main results obtained from this investigation were summerized as follows. 1. W/P ratio decreased with increase of particle size and evenness in distribution of sand grain. 2. Setting time decreased with increase of evenness in distribution of sand grain, and temperature during setting increased with evenness in distribution of sand grain. 3. Setting expansion decreased with increase of particle size, while it increased with evenness in distribution of sand grain. 4. Thermal expansion decreased with increase of particle size. 5. Compressive strength increased with increase of particle size and evenness in distribution of sand grain. From above results, G.F.N. 250 sand which contains 30% of 50-100 mesh could be recommended for investment casting.

• 대한치과보철학회지
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• 제28권1호
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• pp.137-163
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• 1990

The properties of a investment material can be described by the consistency at the slurry state, the setting time, the compressive strength and the thermal expansion during the casting. In this study the effect of the production parameters which are included the ratio of quartz and cristobalite, the content of binder, the water powder ratio and the content and concentration of additives on the Properties of the gypsum-bonded investments has been investigated with help of the consistency test, the vicat needle test, the compressive strength test, the thermal expansion test, x-ray diffraction and DTA thermal differential test. The experimental results showed that the constitution of a investment with W/P ratio of 0.34, 30% of gypsum, 0.8% aluminium sulfate, 2% magnesium sulfate, 0.6% sodium phosphate was adapted for the properties of the KDA Spec. No. 13 type I investment. The important experimental results are summarized as follows. 1. The consistency of the investment decreased with increasing amount of aluminium sulfate and decreasing amount of sodium phosphate. An addition of magnesium sulfate up to 2% an increase of the consistency was shown. But 3% magnesium sulfate in investment showed a decrease of the consistency. The consistency did not vary significantly with a variation of the content of gypsum and cristobalite and the W/P ratio. 2. Aluminium sulfate and the magnesium sulfate promoted the hardening and the aluminium phosphate delayed the hardening. The setting time increased with amount of gypsum. The effect of the matrix on the setting time was insignificant. With the W/P ratio of 0.34 the setting time was 14 min. 3. The compressive strength decreased with the amount of aluminium sulfate up to 0.25% and increased with the amount of aluminium sulfate greater than 3%. The compressive strength decreased as decreasing the amount of magnesium sulfate and gypsum and as increasing the W/P ratio. The effect of the refractory on the compressive strength was also not significant. With the W/P ratio of 0.34 the compressive strength was $34Kg/mm^2$. 4. The 1st thermal expansion was found at the temperature near and the steady state or the contraction stage was found at the temperature between $250^{\circ}C$ and $500^{\circ}C$. After this stage the 2nd thermal expansion took place at the temperature near $500^{\circ}C$. The amount of thermal expansion increased with decreasing the content of magnesium sulfate, aluminium sulfate and gypsum and the W/P ratio. And the amount of thermal expansion increased as the content of sodium phosphate and cristobalite. With the W/P ratio of 0.34 the amount of total expansion was 1.2%.

• 한국산학기술학회논문지
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• 제18권7호
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• pp.357-364
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• 2017

본 논문에서는 생물학적 판넬의 모재로써 마그네시아-인산칼륨 복합체의 품질을 제어하기 위하여 마그네시아-인산칼륨 복합체의 혼합비와 물-결합재비(W/B)에 대한 유동 및 압축강도의 영향을 고찰하고자 하였다. MPPC는 W/B 7수준(30, 35, 40, 45, 50, 55 and 60 vol. %) 및 인산칼륨 및 마그네시아 비율(P:M) 4수준(1;0.5, 1;1.0, 1;2.0 and 1;3.0)으로 제조하였으며, 실험결과, MPPC의 유동 및 압축강도는 P:M비 및W/B에 크게 의존하는 것을 확인할 수 있었다. MPPC의 플로우는 P:M이 증가할수록 반응을 위한 배합수의 부족으로 혼합이 되지 않는 것으로 나타났으며, 이러한 원인은 P의 밀도와 M의 밀도가 크기 때문인 것으로 나타났다. 또한 MPPC의 압축강도는 P:M이 증가함에 따라 강도가 감소하는 경향이 나타났으나 W/B에 따라서는 비례적인 변화가 나타나지 않아 모순된 결과가 나타났다. 이러한 결과는 MPPC의 경우 W/B에 따라 최적의 배합비율이 존재함을 확인할 수 있었다. 본 논문의 이러한 결과를 통하여 생물학적 판넬 설계시 재료적 측면에서 모재 재료의 유동성 및 압축강도에 대한품질 제어를 위한 기반자료로써 활용하고자 한다.

• 대한치과보철학회지
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• 제29권1호
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• pp.139-165
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• 1991

The properties of a investment material can be described by the consistency at the slurry state, the setting time, the compressive strength and the thermal expansion during the casting. In this study the effect of the production parameters which are included the ratio of quartz and cristobalite, the content of binder, the water powder ratio and the content and concentration of additives on the properties of the gypsum-bonded investments has been investigated with help of the consistency test, the vicat needle test, the compressive strength test, the thermal expansion test, x-ray diffraction and DTA thermal differential test. The experimental results showed that the constitution of a investment with W/P ratio of 0.34, 30% of gypsum, 0.8% aluminium sulfate, 2% magnesium sulfate, 0.6% sodium phosphate was adapted for the properties of the KDA Spec. No. 13 type I investment. The important experimental results are summarized as follows. 1. The consistency of the investment decreased with increasing amount of aluminium sulfate and decreasing amount of sodium phosphate. An addition of magnesium sulfate up to 2% an increase of the consistency was shown. But 3% magnesium sulfate in investment showed a decrease of consistency. The consistency did not vary significantly with a variation of the content of gypsum and cristobalite and the W/P ratio. 2. Aluminium sulfata and the magnesium sulfate promoted the hardening and the aluminium phoshpate delayed the hardening. The setting time increased with amount of gypsum. The effect of the matrix on the setting time was insignificant. With the W/P ratio of 0.34 the setting time was 14 min. 3. The compressive strength decreased with the amount of aluminium sulfate up to 0.25% and increased with the amount of aluminium sulfate greater than 3%. The compressive strength decreased as decreasing the amount of magnesium sulfate and gypsum and as increasing the W/P ratio. The effect fo the refractory on the compressive strength was also not significant. With the W/P ratio of 0.34 the compressive strength was $34Kg/mm^2$. 4. The 1st thermal expansion was found at the temperature near $250^{\circ}C$ and the steady state or the contraction stage was found at the temperature between $250^{\circ}C$ and $500^{\circ}C$. After this stage the 2nd thermal expansion took place at the temperature near $500^{\circ}C$. The amount of thermal expansion increased with decreasing the content of magnesium sulfate, aluminium sulfate and gypsum and the W/P ratio. And the amount of thermal expansion increased as the content of sodium phosphate ad cristobalite. With the W/P ratio of 0.34 the amount of total expansion was 1.2%.