• Title/Summary/Keyword: phase transitions

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Brassinosteroids-mediated regulation of ABI3 is involved in high-temperature induced early flowering in plants

  • Hong, Jeongeui;Sung, Jwakyung;Ryu, Hojin
    • Journal of Plant Biotechnology
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    • v.45 no.2
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    • pp.83-89
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    • 2018
  • The interplay of plant hormones is one of the essential mechanisms for plant growth and development. A recent study reported that Brassinosteroids (BR) and ABSCISIC ACID (ABA) interact antagonistically in early seedling developments through the BR-mediated epigenetic repression of ABSCISIC ACID-INSENSITIVE 3 (ABI3). However, the other physiological roles of the BR-mediated regulation of ABI3 and ABA responses beyond early seedling developments remain largely unknown. Here, we showed that the activation of BR signaling by high temperatures promotes flowering time through the suppression of ABI3 expressions. Elevated ambient temperature induced early flowering in wild type Col-0 plants, but not in BR-defective bri1-116 mutant plants. Conversely, a hyper BR biosynthetic dwf4-D mutant displayed more sensitive thermomorphic long shoot elongation and early flowering. Both expression patterns and physiological responses supported the biological roles of ABI3 in the regulation of floral transition and reproduction under high temperature conditions. Finally, we confirmed that the lowered expressions of the transcript and protein levels of ABI3 brought on by elevated temperature were correlated with warmth-induced early flowering phenotypes. In conclusion, our data suggest that the BR- and warmth-mediated regulation of ABI3 are important in thermomorphic reproductive phase transitions in plants.

A Petri Net based Disassembly Sequence Planning Model with Precedence Operations (분해우선작업을 가지는 페트리 넷 기반의 분해순서계획모델)

  • Seo, Kwang-Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.5
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    • pp.1392-1398
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    • 2008
  • This paper presents a Petri Net (PN) based disassembly sequence planning model with precedence operations. All feasible disassembly sequences are generated by a disassembly tree and a disassembly sequence is determined using the disassembly precedence and disassembly value matrix, The precedence of disassembly operations is determined through a disassembly tree and the value of disassembly is induced by economic analysis in the end-of-life phase. To solve the disassembly sequence planning model with precedence operations, a heuristic algorithm based on PNs is developed. The developed algorithm generates and searches a partial reachability graph to arrive at an optimal or near-optimal disassembly sequence based on the firing sequence of transitions of the PN model. A refrigerator is shown as an example to demonstrate the effectiveness of proposed model.

Phase Transitions Mechanisms of Ru Based Thick Film Resistors (Ru 계 후막저항계의 상전이 기구)

  • 강병돈
    • Journal of the Microelectronics and Packaging Society
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    • v.1 no.2
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    • pp.125-134
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    • 1994
  • 저항범위가 다른 두종류의 Ru계 후막저항계(1Kohm/sq. 100kohm/sq.)를 선택하여 도전상의 상전이 기구를 반응조건을 변화시켜 연구하였다. 저저항체의 경우 도전상으로는 RuO2였으며 700-100$0^{\circ}C$에서 1시간 반응한 경우 반응온도에 따른 구성상의 변화는 없었다 반응온도 90$0^{\circ}C$에서 반응시간이 경과함에 따라 도전상은 RuO2가 Glass의 구성성분인 Pb와 반응하여 Rb2(Ru1.69 Pb0.31)O6.5로 변하고 시간이 36시간 경과한 후에는 도전상이 Pb4Al2Si2O10인 결정으로 둘러 쌓이는 반응인 peritectic reaction이 일어났다. 고전항체의 경 우 도전상으로는 Pb2(Ru1.69 Pb0.31)O6.5로 변하고 시간이 36시간 경과한 후에는 더전상이 Pb4Al2Si2O10인 결정으로 둘러쌓이는 반응인 peritectic reaction 이 일어났다. 고저항체의 경 우 도전상으로는 Pb2(Ru1.69 Pb0.31)O6.5인 pyrochrole 상이였다. 100$0^{\circ}C$에서 1시간 반응시킬 경 우 도전상이 RuO2로 변하였다. 반응온도를 90$0^{\circ}C$로 하고 반응시간을 변화시키면 도전상인 Pb2(Ru1.69 Pb0.31)O6.5가 (Ru1.69Pb0.31)O4x로 변하면서 공존하였다.

Magnetic Properties of Thin Films of a Magnetocaloric Material FeRh

  • Jekal, Soyoung;Kwon, Oryong;Hong, Soon Cheol
    • Proceedings of the Korean Magnestics Society Conference
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    • 2013.05a
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    • pp.18-18
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    • 2013
  • A FeRh alloy is a well-known efficient magnetocaloric material and some experimental and theoretical studies of bulk FeRh have been reported already by several groups. In this study we report first-principles calculations on magnetic properties of different thickness FeRh thin films in order to investigate the possibility to enhance further the magnetocaloric efficiency. We used Vienna Ab-initio Simulation Package (VASP) code. We found that the FeRh thin films have quite different magnetic properties from the bulk when the thickness is thinner than 6-atomic-layers. While bulk FeRh has a G-type antiferromagnetic (AFM) state, thin films which are thinner than 6-atomic-layers have an A-type AFM state or a ferromagnetic(FM) state. We will discuss possibility of magnetic phase transitions of the FeRh thin films in the view point of a magnetocaloric effect. And we found 4-, 5-, 6-layers films with Fe surface and 7-layers film with Rh surface are FM and they have dozens eV magnetocrystalline anisotropy (MCA) energy. MCA energy leads to determine energy barrier when magnetic states are changed by external magnetic field.

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Presteady State Kinetics of ATP Hydrolysis by Escherichia coli Rho Protein Monitors the Initiation Process

  • Jeong, Yong-Ju;Kim, Dong-Eun
    • Bulletin of the Korean Chemical Society
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    • v.27 no.2
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    • pp.224-230
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    • 2006
  • Escherichia coli transcription termination factor Rho catalyzes the unwinding of RNA/DNA duplex in reactions that are coupled to ATP binding and hydrolysis. We report here the kinetic mechanism of presteady state ATP binding and hydrolysis by the Rho-RNA complex. Presteady state chemical quenched-flow technique under multiple turnover condition was used to probe the kinetics of ATP binding and hydrolysis by the Rho-RNA complex. The quenched-flow presteady state kinetics of ATP hydrolysis studies show that three ATPs are bound to the Rho-RNA complex with a rate of $4.4\;{\times}\;10^5M^{-1}s^{-1}$, which are subsequently hydrolyzed at a rate of $88s^{-1}$ and released during the initiation process. Global fit of the presteady state ATP hydrolysis kinetic data suggests that a rapid-equilibrium binding of ATP to Rho-RNA complex occurs prior to the first turnover and the chemistry step is not reversible. The initial burst of three ATPs hydrolysis was proposed to be involved in the initialization step that accompanies proper complex formation of Rho-RNA. Based on these results a kinetic model for initiation process for Rho-RNA complex was proposed relating the mechanism of ATP binding and hydrolysis by Rho to the structural transitions of Rho-RNA complex to reach the steady state phase, which is implicated during translocation along the RNA.

Mn Thin Film on $BaTiO_3$ Substrate: Modified Electrical and Magnetic Properties

  • Tuan, Duong Anh;Cuong, Tran Viet;Shin, Yooleemi;Cho, Sunglae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.162-162
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    • 2013
  • Magnetic properties of 3d transition metals were determined by exchange interaction between magnetic ions that was characterized by the exchange integral. Bulk Mn material is one of transition metals that have been well known as an anti-ferromagnetic material due to an anti-parallel spin with negative exchange integral. Here we report on the MBE growth of Mn on $BaTiO_3$ (001) substrate and induced ferromagnetism. The bcc ${\alpha}$-Mn single crystal film has been grown on $BaTiO_3$ (100) substrate. The XRD and Raman results indicated that the structural phase transitions of $BaTiO_3$ substrate induced a lattice distortion at the interface. Consequently, the grown Mn film exhibits ferromagnetism with strong saturation magnetization of 495 emu/$cm^3$ at 320 K. The electrical resistivity of the Mn film strongly depended on the crystal structure of $BaTiO_3$ substrate.

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Time monitoring observations of H2O and SiO masers toward semi-regular variable star R Crateris

  • Kim, Dong-Jin;Cho, Se-Hyung;Yun, Young-Joo;Kim, JaeHeon;Choi, Yoon Kyung;Yoon, Dong-Whan;Yoon, Suk-Jin
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.43.1-43.1
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    • 2016
  • With the Korean VLBI Network (KVN), both single dish and VLBI monitoring observations of H2O and SiO masers were performed toward the semi-regular variable star R Crateris. In the case of 11 VLBI monitoring observations from Jan. 5, 2014 to Jan. 7, 2016, successful superposed maps of H2O and SiO masers were obtained at 7 epochs by adopting the Source Frequency Phase Referencing (SFPR) method. These results enable us to investigate the development of outflow and asymmetric motions from SiO maser to H2O maser regions according to stellar pulsation which are closely related with a mass-loss process. Single dish monitoring observations of H2O and SiO masers were also carried out from 2009 June to 2016 Feb. Intensity variations between H2O and SiO masers were investigated according to stellar optical phases together with peak velocity variations with respect to the stellar velocity. We will compare the VLBI results among different maser transitions with those of single dish.

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Superconducting transitions of LuBa2Cu3O7-z heated under various atmospheres

  • Lee, M.S.;Lee, H.K.
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.1
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    • pp.6-8
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    • 2014
  • The influence of quenching temperature, heating atmosphere and annealing time on superconducting characteristics has been studied for $LuBa_2Cu_3O_{7-z}$ compound which has been recently synthesized in a nearly phase-pure form. Resistivity measurements for the as-prepared sample heated at $300^{\circ}C$ in oxygen and subsequently quenched into liquid nitrogen revealed that there is no significant change in $T_c$. On the other hand, $T_c$ of the sample slightly increased when the sample was heated at $300^{\circ}C$ either in air or in $N_2$ atmosphere. It was also found that $T_c$ of the sample decreased when the annealing temperature in $N_2$ atmosphere increased above $400^{\circ}C$. The experimental results indicated that the as-prepared sample is under overdoped state. The enhanced superconducting transition observed in the samples after heating at $300^{\circ}C$ in air or $N_2$ atmosphere was discussed in conjunction with a slight removal of oxygen and ordering of oxygen atoms in the as-prepared sample.

Raman and Fluorescence Studies of Thermotropic Liquid-Crystalline Oligomers with Different Type of Coils

  • Chae, Jong-Bok;Yu, Soo-Chang;Lee, Youn-Sik
    • Bulletin of the Korean Chemical Society
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    • v.28 no.2
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    • pp.193-199
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    • 2007
  • Raman and fluorescence spectroscopies were employed to study the coil effects on the intermolecular structure of a rod-coil liquid crystalline (LC) oligomer, the esterification products of ethyl 4-[4'-oxy-4-biphenylcarbonyloxy]- 4'-biphenylcarboxylate with poly(propylene)oxides (PPO) (DP=12) and poly(ethylene oxide)s (PEO) (DP=12). Three different vibrational modes (carbonyl, aromatic C-H, and aromatic C=C) obtained from the Raman experiment at variable temperature indicate that PPO and PEO coils induce the hydrogen bonding in a different manner. Further information about the micro-environment around the mesogenic unit obtained by fluorescence excitation spectra of P12-4 (LC with PPO coil) and 12-4 (LC with PEO coil) suggests that the mesogenic unit of P12-4 is quite different from that of 12-4 in intermolecular structure. This study supports the results obtained only from Raman spectroscopy, providing more accurate information about the intermolecular structural changes of liquid crystalline polymers at a molecular level during the phase transitions.

Magnetic properties of thin films of a magnetocaloric material FeRh

  • Jekal, Soyoung;Kwon, Oryong
    • Proceeding of EDISON Challenge
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    • 2013.04a
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    • pp.294-298
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    • 2013
  • A FeRh alloy is a well-known efficient magnetocaloric material and some experimental and theoretical studies of bulk FeRh have been reported already by several groups. In this study we report first-principles calculations on magnetic properties of different thickness FeRh thin films in order to investigate the possibility to enhance further the magnetocaloric efficiency. We used two methods of a Vienna Ab-initio Simulation Package (VASP) code and SIESTA package. We found that the FeRh thin films have quite different magnetic properties from the bulk when the thickness is thinner than 6-atomic-layers. While bulk FeRh has a G-type antiferromagnetic(AFM) state, thin films which are thinner than 6-atomic-layers have an A-type AFM state or a ferromagnetic (FM) state. We will discuss possibility of magnetic phase transitions of the FeRh thin films in the view point of a magnetocaloric effect. And we found 4-, 5-, 6-layers films with Fe surface and 7-layers film with Rh surface are FM and they have relatively small magnetocrystalline anisotropy (MCA) energy about less than 70 meV. The small MCA energy leads to reduction of the strength of magnetic field in operating a magnetic refrigerator.

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