• 한국자기공명학회논문지
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• 제16권2호
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• pp.111-121
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• 2012

The spin-lattice relaxation times, $T_1$, and spin-spin relaxation times, $T_2$, of the $^{27}Al$ and $^{87}Rb$ nuclei in $RbAl(CrO_4)_2{\cdot}2H_2O$ crystals were investigated. The presence of only one resonance line for the $^{27}Al$ nuclei indicates that the results in a dynamical averaging of the crystal electric field that produces a cubic symmetry field. The changes in the temperature dependence of $T_1$ are related to variations in the symmetry of the octahedra of water molecules surrounding $Al^+$ and $Rb^+$. The $T_1$ values for the $^{27}Al$ and $^{87}Rb$ nuclei are different due to differences in the local environments of these ions. We also compared these $^{27}Al$ and $^{87}Rb$ NMR results with those obtained for $RbAl(CrO_4)_2{\cdot}2H_2O$ crystals. The relaxation mechanisms of $RbAl(XO_4)_2{\cdot}nH_2O$ (X=Cr and S) crystals are characterized by completely different NMR behaviors.

• Bulletin of the Korean Chemical Society
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• 제13권6호
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• pp.605-612
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• 1992

Chromium oxide/zirconia catalysts were prepared by dry impregnation of powdered $Zr(OH)_4$ with ($NH_4$)$_2$CrO$_4$aqueous solution. The characterization of prepared catalysts was performed using FTIR, XPS, XRD and DTA methods, and by the measurement of surface area. The addition of chromium oxide to zirconia shifted the transitions of $ZrO_2$ from amorphous to tetragonal phase and from tetragonal to monoclinic phase to higher temperature due to the strong interaction between chromium oxide and zirconia, and the specific surface area of catalysts increased in proportion to the chromium oxide content. Since the $ZrO_2$ stabilizes supported chromium oxide, chromium oxide was well dispersed on the surface of zirconia, and ${\alpha}$-$Cr_2O_3$ was observed only at the calcination temperature above 1173 K. Upon the addition of only small amount of chromium oxide (1 wt% Cr) to $ZrO_2$, both the acidity and acid strength of catalyst increased remarkably, showing the presence of two kinds of acid sites on the surface of $CrO_x$/$ZrO_4$-Bronsted and Lewis.

• Mass Spectrometry Letters
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• 제13권4호
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• pp.158-165
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• 2022

Many therapeutic class drugs such as beta-blocker, corticosteroids, NSAIDs, etc are prohibited substances in the horse racing industry. Liquid chromatography-tandem mass spectrometry (LC-MS/MS) technology makes it possible to isolate drugs from interference, enables various drug analyses in complex biological samples due to its sensitive sensitivity, and has been successfully applied to doping control. In this paper, we describe a rapid and sensitive method based on solid-phase extraction (SPE) using solid phase cartridge and LC-MS/MS to screen for different class's 35 drug targets in equine plasma. Plasma samples were pretreated by SPE with the NEXUS cartridge consisted non-polar carbon resin and minimum buffer solvent. Chromatographic separation of the analytes was performed on ACQUITY HSS C18 column (2.1 × 150 mm, 1.8 ㎛). The elution gradient was conducted with 5 mM ammonium formate (pH 3.0) in distilled water and 0.1% formic acid in acetonitrile at a flow rate of 0.25 mL/min. The selected reaction monitoring (SRM) mode was used for drug screening with multiple transitions in the positive ionization mode. The specificity, limit of detection, recovery, and stability was evaluated for validation. The method was found to be sensitive and reproducible for drug screening. The method was applied to plasma sample analysis for the proficiency test from the Association of Racing Chemist.

• 천문학회보
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• 제46권2호
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• pp.49.2-49.2
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• 2021

We present the results of long-term simultaneous monitoring observations (~ 12 years) of H²O (22 GHz) maser and several vibrationally excited lines of SiO J = 1-0, 2-1, 3-2 masers (43, 86, 129 GHz) carried out with the 21-m antennas of the Korean VLBI Network (KVN) toward a sample of three AGB stars (RT Vir, RR Aql, IRC-10151) that are believed to be semiregular variable star, Mira variable star, and OH/IR star, respectively, according to a sequential evolutionary phase of AGB star. A total 10 transitions were observed, of which we detected H²O, SiO 𝝊 = 1 and 2, J = 1-0, SiO 𝝊 = 1, J = 2-1 and J = 3-2 maser lines in all three target objects, depending on the observational epochs. In this study, we scrutinize the evolutionary traits of each target object based on the maser line profiles, flux/velocity variations, and phase lags with the optical light curves. The IRAS two color diagram and the infrared spectral energy distributions (SEDs) in the wavelength range from 1.2 to 240 ㎛ of three observed sources were also analyzed.

• 한국재료학회지
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• 제22권9호
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• pp.489-493
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• 2012

Green phosphors $K_2BaW_2O_8:Tb^{3+}$(1.0 mol%) were synthesized by solid state reaction method. Differential thermal analysis was applied to trace the reaction processes. Three endothermic values of 95, 706, and $1055^{\circ}C$ correspond to the loss of absorbed water, the release of carbon dioxide, and the beginning of the melting point, respectively. The phase purity of the powders was examined using powder X-ray diffraction(XRD). Two strong excitation bands in the wavelength region of 200-310 nm were found to be due to the ${WO_4}^{2-}$ exciton transition and the 4f-5d transition of $Tb^{3+}$ in $K_2BaW_2O_8$. The excitation spectrum presents several lines in the range of 310-380 nm; these are assigned to the 4f-4f transitions of the $Tb^{3+}$ ion. The strong emission line at around 550 nm, due to the $^5D_4{\rightarrow}^7F_5$ transition, is observed together with weak lines of the $^5D_4{\rightarrow}^7F_J$(J = 3, 4, and 6) transitions. A broad emission band peaking at 530 nm is observed at 10 K, while it disappears at room temperature. The decay times of $Tb^{3+}$ $^5D_4{\rightarrow}^7F_5$ emission are estimated to be 4.8 and 1.4 ms, respectively, at 10 and 295 K; those of the ${WO_4}^{2-}$ exciton emissions are 22 and 0.92 ${\mu}s$ at 10 and 200 K, respectively.

• 한국재료학회지
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• 제19권4호
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• pp.220-223
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• 2009

Lithium dihydrogen phosphate ($LiH_2PO_4$) powder was purchased from Aldrich Chemical Co. From the scanning electron microscope (SEM) observation, these polycrystals have dimensions in the range of $25-250{\mu}m$. The electrical conductivity was measured at a measuring frequency of 1 kHz on heating polycrystalline lithium dihydrogen phosphate ($LiH_2PO_4$) from room temperature to 493 K. Two anomalies appeared at 451 K ($T_{p1}$) and 469 K ($T_{p2}$). The electrical conductivity reached the magnitude of the superprotonic phases: $3{\times}10^{-2}{\Omega}^{-1}cm^{-1}$ at 451 K ($T_{p1}$) and $1.2{\times}10{\Omega}^{-1}cm^{-1}$ at 469 K ($T_{p2}$). It is uncertain whether the superprotonic phase transformations are due to polymorphic transitions in the bulk, surface transitions, or chemical reactions (thermal decomposition) at the surface. Considering several previous thermal studies (differential scanning calorimetry and thermogravimetry), our experimental results seem to be related to the last case: chemical reactions (thermal decomposition) at the surface with the progressive solid-state polymerization.

• Journal of Astronomy and Space Sciences
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• 제17권1호
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• pp.39-44
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• 2000

lUE 저분산 자로플 가지고 44i Boo, W UMa, AW UMa및 VW Cep에서 나오는 자외선 방출선들의 특징을 조사하였다 단파장영역과 장파장영역에서의 방출선 선세기를 구하여, 이를 자$\boxUl$선 등급으로 변환하여 광도곡선을 얻었다 단파장 영ff에서 나오는 방출선인 C I, C II, C IV, SiIV, N V에 대한 선세기를 구한 결파, C IV가 모든 별에서 가장 센 방출을 보였으며. Si IV와 NV는 비교적 작은 양의 선세기를 나타내었다. 4개의 W UMa 별 쿵에근 44i Boo가 가장 높은 선세기를 보였으며, 단과장 영역에서는 위상 0.2와 0 8부근에서 자외선 팡도가 maximup을 보이는 변광을 확인하였다 또한, 전이영역에서 나오는 C IV, Si IV, N V 방출선을 합하여 이를 극소기의 태양값과 비교하여 태양보다 최대40배의 높은 활동성을 가지고 있음을 알았다. 짧은 주기를 갖는 별,즉 44i Boo, W UMa, AW UMa순으로 전이영역의 헐동성이 감소하는 것으로 나타났다. 장 파장 영역에서는 AW UMa와 VW Cep의 Mg ll 방출선을 조사하였는데, 단파장의 방출선 보다 뚜렷한 주기적 변광을 보였으며, 이를 이응하여 두 별의 유효온도를 추정하였다..

• 한국재료학회지
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• 제8권3호
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• pp.224-228
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• 1998

비정량적 조성을 가진 비정질 산화타이타늄 박막을 반응성 스퍼터링으로 제조한후, $500^{\circ}C$~$600^{\circ}C$에서 10분-3시간 열처리후 냉각속도를 달리하였을 때의 상변태과정을 고찰하였다. 10분-30분정도의 단기간의 열처리후 급냉한 경우에는 Mageneli상이 관찰되어 비정상정 상($TiO_{2-x}$)이 산화되는 속도가 결정화속도보다 훨씬 느린 것으로 생각되었다. 그러나 열처리 유지시간이 증가하면 $500^{\circ}C$에서 부터의 느린 냉각과정에서는 Magneil가 anatase로 변화하며 변태한 anatase는 저온에서는 rutile로 변화하지 않았으나 $500^{\circ}C$~$300{\circ}C$의 온도 구간을 비교적 빠르게 냉각하면 Matneli상은 직접 rutile상으로 변화할 수 있는 것으로 고찰되었다. 또한 $600^{\circ}C$에서 냉각시에도 rutile상이 형성됨으로서 rutile상은 $500^{\circ}C$이상의 고온에서도 이 상ㅇ르 거치지 않고 변태할 수 있는 것으로 분석된다. 결정화 및 산화과정은 부피의 변화를 야기하여 박막의 표면 형상의 변화도 가져옴이 관찰되었다.

• 대한화학회지
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• 제40권9호
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• pp.607-614
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• 1996

$ABO_3$계 perovskite 구조에서 A자리의 $Pb^{2+}$ 이온이 $Na^+La^{3+}$혼합 이온 으로 0-50mol.%치환된 $Pb_{1-x}(Na_12/La_12)_x(Mg_13/Nb_23/)O_3$ 화합물의 구조변화와 유전 성질을 X-선 회절법, 작외선과 라만 분광법, LCR meter등으로 연구하였다. $Na^+La^{3+}$혼합 이온의 치환량과 소결 온도가 증가함에 따라 perovskite 상의 양이 증가하였다. 치환량이 증가할 때 1:1 질서화에 의한 초격자선을 X-선 회절법으로 발견할수 없었지만, 라만 분광법과 이완성 매개변수의 증가로부터 A자리 양이온의 크기감소가 질서화에 영향을 미침을 알 수 있었다. Pb_{1-x}(Na_12/La_12)_x(Mg_13/Nb_23/)O_3$의 유전 성질은 perovskite 상의 양과 낟알 크기 및 밀도에 의해 영향을 받았고, 치환량이 증가할 때 상전이는 확산되었으며 상전이 온도는 감소하였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 하계학술대회 논문집 D
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• pp.1980-1982
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• 1999

Conductive Langmuir-Blodgett(LB) films have recently attracted much interest from the viewpoint of ultrathin film conductors at the molecular level. The result shows that the Maxwell-displacement-current (MDC) measuring technique is useful in the detection of phase-transitions over the entire range of molecule areas. In this parer, electrical properties of PBDG Langmuir(L) films were investigated using a displacement current measuring technique with pressure stimulation. Displacement current was generated When the Spread volume $150{\mu}{\ell}$ and compression velocity was about 30, 40, 50 mm/min. In the result, it is known that current is generated of higher current peek as compression velocity become faster.