• Title/Summary/Keyword: phase shifts

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Effect of Shock Wave Exposure on Structural, Optical and Magnetic Properties of Lead Sulfide Nanoparticles (충격파 유동노출에 따른 황화납 나노소재의 미세구조 및 자기광학적 특성 분석에 관한 실험적 연구)

  • Kiwon Kim;Surendhar Sakthivel;J. Sahadevan;P. Sivaprakash;Ikhyun Kim
    • Journal of the Korean Society of Visualization
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    • v.22 no.1
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    • pp.18-27
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    • 2024
  • A series of shock wave pulses with Mach number 2.2 of 100, 200, and 300 shocks were applied to lead sulfide (PbS) nanomaterials at intervals of 5 sec per shock pulse. To investigate the crystallographic, electronic, and magnetic phase stabilities, powder X-ray diffractometry (XRD), diffused reflectance spectroscopy (DRS), and vibrating-sample magnetometry (VSM) were employed. The material exhibited a rock salt structure (NaCl-type structure); XRD results indicated that material is monoclinic with space group C121 (5). Further, XRD results showed shifts due to lattice contraction and expansion when material was subjected to shock wave pulses, indicating stable material structure. Based on the data obtained, we believe that the PbS material is a good choice for high-pressure, high-temperature, and aerospace applications due to its superior shock resistance characteristics.

Formal Verification of Twin Clutch Gear Control System

  • Muhammad Zaman;Amina Mahmood;Muhammad Atif;Muhammad Adnan Hashmi;Muhammad Kashif;Mudassar Naseer
    • International Journal of Computer Science & Network Security
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    • v.24 no.3
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    • pp.151-159
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    • 2024
  • Twin clutch model enables the power-shifts as conventional planetary automatic transmission and eradicates the disadvantages of single clutch trans- mission. The automatic control of the dual clutches is a problem. Particularly to control the clutching component that engages when running in one direction of revolution and disengages when running the other direction, which exchange the torque smoothly during torque phase of the gearshifts on planetary-type automatic transmissions, seemed for quite a while hard to compensate through clutch control. Another problem is to skip gears during multiple gearshifts. However, the twin clutch gear control described in ["M Goetz, M C Levesley and D A Crolla. Dynamics and control of gearshifts on twin clutch transmissions, Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering 2005"], a significant improvement in twin clutch gear control system is discussed. In this research our objective is to formally specify the twin clutch gear control system and verify it with the help of formal methods. Formal methods have a high potential to give correctness estimating techniques. We use UPPAAL for formal specification and verification. Our results show that the twin clutch gear control model partially fulfills its functional requirements.

Mechanical Analysis of golf driving stroke motion (골프드라이빙 스트로크시 역학적 분석)

  • Park, Kwang-Dong
    • Korean Journal of Applied Biomechanics
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    • v.12 no.1
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    • pp.205-219
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    • 2002
  • This research seeks to identify the plantar pressure distribution graph and change in force in connection with effective golf drive strokes and thus to help ordinary golfers have appropriate understanding on the moving of the center of weight and learn desirable drive swing movements. To this end, we conducted surveys on five excellent golfers to analyze the plantar pressure applied when performing golf drive strokes, and suggested dynamic variables quantitatively. 1) Our research presents the desire movements as follows. For the time change in connection with the whole movement, as a golfer raises the club head horizontally low above ground from the address to the top swing, he makes a semicircle using the left elbow joint and shaft and slowly turns his body, thus lengthening the time. And, as the golfer twists the right waist from the middle swing to the impact with the head taking address movement, and does a quick movement, thus shortening the time. 2) For the change in pressure distribution by phase, to strike a strong shot with his weight imposed from the middle swing to the impact, a golfer uses centrifugal force, fixes his left foot, and makes impact. This showed greater pressure distribution on the left sole than on the right sole. 3) For the force distribution graph by phase, the force in the sole from the address to halfway swing movements is distributed to the left foot with 46% and to the right foot with 54%. And, with the starting of down swing, as the weight shifts to the left foot, the force is distributed to the left sole with 58%. Thus, during the impact and follow through movements, it is desirable for a golfer to allow his left foot to take the weight with the right foot balancing the body. 4) The maximum pressure distribution and average of the maximum force in connection with the whole movement changed as the left (foot) and right (foot) supported opposing force, and the maximum pressure distribution also showed much greater on the left sole.

The Effect of Spatial Dimension Shifts in Rotated Target Position Search (차원 변환이 회전하는 목표 자극의 위치 탐색에 미치는 영향)

  • Park, Woon-Ju;Jung, Il-Yung;Park, Jeong-Ho;Bae, Sang-Won;Chong, Sang-Chul
    • Korean Journal of Cognitive Science
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    • v.22 no.2
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    • pp.103-121
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    • 2011
  • This study investigated how spatial dimension information and dimensional consistency between learning and testing phase would influence the target search performance. The participants learned spatial layouts of Lego blocks shown in either two- (2D) or three-dimension (3D) and were tested with the rotated stimuli ($0^{\circ}$, $90^{\circ}$, $180^{\circ}$, or $270^{\circ}$ from the initial view) in consistent or inconsistent dimension. Significantly better performance was observed when initial learning display appeared in 2D than in 3D. Particularly, the participants showed difficulties in flexible usage of spatial information presented in 3D especially if the dimensional information in the testing phase also was 3D and required mental rotation. The present study indicates that spatial map presented in 2D may be more useful than 3D in driving situations in which acquired spatial information from navigating device, such as GPS, and location of driver continuously changes.

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[ $^1H$ ] Nuclear Magnetic Resonance Study of Ferroelectric $(NH_4)_3H(SO_4)_2$

  • Choi, S.H.;Han, K.S.;Kwon, S.K.;Nam, S.K.;Choi, H.H.;Lee, Moo-Hee;Lim, Ae-Ran
    • Journal of the Korean Magnetic Resonance Society
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    • v.11 no.2
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    • pp.64-72
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    • 2007
  • [ $^1H$ ] nuclear magnetic resonance (NMR) experiments have been performed at 30 - 300 K and 7 T to investigate dynamics of hydrogen bond network in the single crystal $(NH_4)_3H(SO_4)_2$. The two proton sites, ammonium proton and hydrogen-bond proton, are identified from the $^1H$ NMR MAS spectrum at 340 K. As temperature decreases, the $^1H$ NMR spectrum shifts to the higher frequency side with a larger linewidth. The spectrum at 65 K shows a distinctive change in line shape toward the ferroelectric transition at 63 K. The measured values of $T_1$ for ammonium and hydrogen-bond protons are similar in the whole range of temperature. $T_1$ of $^1H$ NMR shows a gradual decrease down to 120 K and starts to steeply increase below 100 K. Then $T_1$ shows abrupt decrease below 70 K with a sharp minimum at 63 K, where the ferroelectric transition occurs. This temperature dependence of spectrum and $T_1$ clearly prove that the large change in the dynamics of hydrogen bond network is associated with the ferroelectric phase transition at 63 K.

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A New Driving Method for High Resolution AC PDP (고해상도 AC PDP를 위한 새로운 구동방식)

  • Cho, Young-Wan;Kwon, Oh-Kyong
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.38 no.4
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    • pp.45-53
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    • 2001
  • We have proposed a new driving method of AC PDP for both high resolution over HDTV and high luminance. The new driving method can reduce data and scan pulse width to 0.85${\mu}s$ by utilizing both rising and falling edges of sustain pulse and can provide high resolution AC PDP with high luminance by increasing the number of addressing discharge using sustain pulses with phase shifts. As a result, the proposed driving scheme makes it possible to drive 2080 horizontal resolution panel with high luminance. The experimental results using 4-inch color AC PDP with $30{\times}58$ pixels indicate that the luminance can achieved up to 850 $cd/m^2$ without image noise when we employ the four phase shifted sustain pulses with the amplitude of 140V and the frequency of 125KHz.

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Study on the micellization of cetyltrimethyl ammonium bromide in 4-biphenyl acetate solution (4-biphenyl acetate 수용액에서 Cetyltrimethyl Ammonium Bromide의 미셀화에 관한 연구)

  • Oh, Jung Hee
    • Analytical Science and Technology
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    • v.8 no.2
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    • pp.107-116
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    • 1995
  • The critical micelle concentration(CMC) of CTAB was determined with changes in absorbance at 202nm band of 4-biphenyl acetate($BPA^-$). With $BPA^-$ as a probe, the effect of temperature on CMC of CTAB has been observed between $30^{\circ}C{\sim}70^{\circ}C$. In this range of temperature the values of CMC are $1.18{\times}10^{-4}{\sim}2.02{\times}10^{-4}M$. The free energy(${\Delta}G^{\circ}m$) and enthalpy(${\Delta}H^{\circ}m$)for the micellization of CTAB was negative and the entropy(${\Delta}S^{\circ}m$) was a large positive value. The micellization of CTAB is considered as a spontaneous process and to involve a phase transition. The orientational binding of 4-biphenyl acetate anion to the CTAB micelle interface has been studied with $300MHz\;H^1-NMR$ data. The change in chemical shift of proton in CTAB as well as those of the protons in $BPA^-$ have been investigated by increasing the mole fraction of the anion in the mixed solutions. The changes in chemical shift with increasing mole fraction of anion($BPA^-$) indicate the formation of mixed micelle between CTAB and $BPA^-$. The changes in chemical shifts of methylene protons in CTAB, demonstrate the penetration of $BPA^-$ into the palisade layer of the CTAB micelle.

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Fluorescence Behavior of Benzo[f]Quinoline Doped In Lpd Silica Thin Films

  • Mabuchi, Toshiaki;Suzuki, Satoshi;Nakajima, Tsuyoshi;Ino, Juichi;Takemura, Kazuo;Shimizu, Etsuro
    • Journal of Photoscience
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    • v.5 no.3
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    • pp.105-109
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    • 1998
  • By using the liquid -phase-deposition (LPD) process, which has a potetnial of preparing organic inorganic composite materials, samples doped with benzo[f]quinoline (BfQ)into silica thia films wre prepared. We observed the fluorescene and fluorescene excitation spectra of the samples, as well as the fluorescence lifetimes and time-resoluved fluorescence spectra. The comparison of thefluorescence spectra in pH-controlled buffer solutions yields the results that the dominant species of BfQ in the LPD silica films is a protonated one. The fluorescence band assigned to a hydrogen-bonded species was observed on the samples prepared from the dipping solutions of 3 and 2 M hexafluorosilicic acid. The band assignment was confirmed by the fluorescence lifetime measurement. The FT-IR M hexaflurosilicic acid. The band assignment was confirmed by the flurescence lifetime meausurement. The FT-IR data proved the existence of included water in silica films prepared from the LPD process. The appearance of the band corresponding to the hydrogen-bonded species within LPD silica phases was explained by the proesence of included water. Depending on the preparation conditions of LPD silica films, the band assigned to protonated species shows bad shifts in a wavenumber region between the peak of hydrogen-bonded and typical protonated species. This implies that there is some distribution of steric conformation of protonated species of BfQ interacting with adsorbing sites of LPD silica. The time -resolved fluorescence spectra suggest that some relaxation process is involved in the conformation of BfQ doped into the solid phase of LPD silica.

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Quantitative Structure Determination of Ni(111)(2×2)-O/CO: temperature Dependent Study (광전자회절을 이용한 Ni(111)(2×2)-O/CO의 표면 흡착 구조: 시편준비의 온도 의존성)

  • Kang J.H.
    • Journal of the Korean Magnetics Society
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    • v.16 no.1
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    • pp.92-97
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    • 2006
  • A study of the adsorption site of CO in the Ni(111)$(2\times2)$-O/CO coadsorbed phase over different sample preparation temperatures revealed that the atop site is favoured. The Ni-C spacing is given by $1.77\pm0.01\;{\AA}$. A study of the adsorption site of Co in the Ni(111)$(2\times2)$-O/CO coadsorbed phase over different sample preparation temperatures revealed that the atop site is favoured. The Ni-C spacing is given by $1.77\pm0.01\;{\AA}$. The data from the sample prepared at 265 K showed atop sites, which is well consistent with vibrational spectroscopy, whilst the data from the low temperature preparation appears the mixture of atop and hop $(35\%)$. The occupation of hop hollow sites is probably due to an incorrect pre-coverage of atomic oxygen (different from 0.25ml). Similar observation of site mixture also found in recent high resolution XPS measurements using C 1s and O 1s chemical shifts.

Magnetic and Magnetostrictive Properties of Amorphous Tb-Fe- and Tb-Fe-B Thin Films

  • Park, Y. S.;Lee, S. R.;S. H. Han;Kim, H. J.;S. H. Lim
    • Journal of Magnetics
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    • v.2 no.3
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    • pp.76-85
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    • 1997
  • Magnetic and magnetostrictive properties of Tb-Fe and Tb-Fe-B thin films are systematically investigated over a wide composition range from 40.2 to 68.1 at. % Tb. The films were fabricated by rf magnetron sputtering using a composite target which consists of an Fe plate and Tb chips. The microstructure, examined by X-ray diffraction, mainly consists of an amorphous phase and, at high Tb contents, a pure Tb phase also exists. A progressive change in the direction of anisotropy from the perpendicular to in-plane occurs as the Tb content increases and the boundary at which the anisotropy change occurs shifts significantly towards to higher Tb contents with the addition of B. The saturation magnetization exhibits maxima at the Tb contents of 42 and 48 at. % for Tb-Fe and Tb-Fe-B thin films, respectively, and it is decreased by the addition of B. The coercive force, measured in the easy direction, decreases monotonically with the Tb content. Excellent magnetostrictive characteristics, particularly at low magnetic fields, are achieved in both Tb-Fe and Tb-Fe-B thin films; for example, a magnetostriction of 138 ppm is obtained in a Tb-Fe-B thin film at a magnetic field as low as 30 Oe. The excellent magnetostrictive properties of the present thin films are supported by the equally excellent magnetic softness, the coercivity below 10 Oe and a typical squared-loop shape with the saturation field as low as 1 kOe. Due to the excellent low field magnetostrictive characteristics, the present Tb-Fe based thin films are thought to be suitable for Si based microdevices.

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