• Title/Summary/Keyword: phase diagram

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Preparation of Regenerated Cellulose Fiber via Carbonation. I. Carbonation and Dissolution in an Aqueous NaOH Solution

  • Oh, Sang Youn;Yoo, Dong Il;Shin, Younsook;Lee, Wha Seop;Jo, Seong Mu
    • Fibers and Polymers
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    • v.3 no.1
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    • pp.1-7
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    • 2002
  • Cellulose carbonate was prepared by the reaction of cellulose pulp and $CO_2$ with treatment reagents, such as aqueous $Zncl_2$ (20-40 wt%) solution, acetone or ethyl acetate, at -5-$0^{\circ}C$ and 30-40 bar ($CO_2$) for 2 hr. Among the treatment reagents, ethyl acetate was the most effective. Cellulose carbonate was dissolved in 10% sodium hydroxide solution containing zinc oxide up to 3 wt% at -5-$0^{\circ}C$. Intrinsic viscosities of raw cellulose and cellulose carbonate were measured with an Ubbelohde viscometer using 0.5 M cupriethylenediamine hydroxide (cuen) as a solvent at $20^{\circ}C$ according to ASTM D1795 method. The molecular weight of cellulose was rarely changed by carbonation. Solubility of cellulose carbonate was tested by optical microscopic observation, UV absorbance and viscosity measurement. Phase diagram of cellulose carbonate was obtained by combining the results of solubility evaluation. Maximum concentration of cellulose carbonate for soluble zone was increased with increasing zinc oxide content. Cellulose carbonate solution in good soluble zone was transparent and showed the lowest absorbance and the highest viscosity. The cellulose carbonate and its solution were stable in refrigerator (-$5^{\circ}C$ and atmospheric pressure).

Improvement plan for Function Definition using CAFAT in the Construction VE (건설 VE에서 CAFAT을 이용한 기능정의 개선방안)

  • Choi, Chang-Hoon;Kim, Soo-Yong
    • Korean Journal of Construction Engineering and Management
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    • v.7 no.3 s.31
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    • pp.102-111
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    • 2006
  • In the analysis of function, which is the core and early phase among the procedure of construction VE Job Plan, the accuracy of function definition directly connects to VE result. However, the method of defining function, which is currently used is not accurate and comprehended or is difficult to utilize it systematically. Also, there is not a clear definition about the function for selecting VE so that many difficulties occur in the organic connection between each of functions in the summarization of function after defining function. Therefore, this study cleared the definition of function and made up any counter measured problem occurred in FAST Diagram later on and suggested CAFAT(Combined Antithetic Function Analysis Technique) in order to induce better phase in functional analysis.

Configuration of a Module for Monitoring Voltages Between Power Lines and Hull Onboard Vessels Based on the Vector Diagram at 3 Phase Ungrounded Power Distribution System (비접지 선박 3상 배전선로의 대지전압 벡터 모니터링 장치의 구성)

  • Choi, Soon-Man
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.8
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    • pp.1111-1116
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    • 2011
  • Power distribution systems onboard vessels are typically configured without any live line connected to hulls for earthing purpose, where the line to hull voltages are affected and deformed depending on the impedances consisting of insulation resistances and distributed capacitances between power lines and hull. An insulation fault at power lines causes the line to hull voltages to increase to a higher level which brings more possibilities to electric shock and deterioration of insulation material. This study focuses on how to configure a module which enables to continuously monitor the voltages between power line and hull based on the vector diagram by analyzing the neutral point of 3 phase voltages and the algorithm for plotting method on the PC monitors.

Essential Logical Model Approach in Analysis and Design for Patient Management and Accounting System : A Case Study (본질적 논리모형에 근거한 원무관리시스템의 분석과 설계)

  • 김명기
    • Health Policy and Management
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    • v.4 no.2
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    • pp.111-125
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    • 1994
  • In developing total hospital information system, large amount of time and expense are to be spent while its results are likely to lead itself to end-users' dissatisfaction. Some of the main complaints on the part of end-users come from insufficient consideration of end-users environment as well as inappropriate representation of their requirement in the system alalysis and design. This papre addresses some advantages of Essential Logical Modeling Process for better analysis and design, explaining by example the developmental process of the Patent Management and Accounting System for a tertiary care hospital. In the case, the Essential Model, suggested by McMenamin and Palmer, proved to be an effective tool for clear separation of analysis and design phase and for better communication among system developers and with end-users. The modeling process itself contributed to better program modularity as well, shown in a Structured Chart. Difficulties in learning how to identify' essential activities' for the modeling practice were experienced in the beginnins stage, which were, however, overcome by elaborating some heuristic guideling and by rdferring to necessary tools including State Transition Diagram, Control Flow Diagram, and so many. While full evaluation of the Essential Model usag remains to wait till the completion of the case project, its strengt in making clear distinction between analysis and design phase was enough to be attractive to system analysts. The model concepts are open to many further application fields, particularly such areas as business re engineering, process remodeling, office automation, and organizational restructuring.

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Effects of Wire speed Fluctuation on Arc Stability in GMA Welding (GMAW에서 와이어 송급속도의 변동이 아크안정성에 미치는 영향에 관한 연구)

  • 신현욱;최용범;성원호;장희석
    • Journal of Welding and Joining
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    • v.13 no.4
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    • pp.85-102
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    • 1995
  • Weld quality of GMA welding processes is closely related to arc stability. Although many researches on arc stability have been performed, real-time estimation of arc stability has not been attempted. For instance, Mita proposed a off-line statistical method in which short circuiting and arcing time, and voltage and current wave forms were sampled to assess arc stability. But this method is not suitable to assess arc stability for GMA welder which employ inverter power source due to its controlled current and voltage wave forms. In this paper, the relationship between are stability and wire feed rate fluctuation is analyzed to propose new criterion for inverter power source. When arc voltage and arc current and arcing time are analyzed, we can assess arc stability only for short circuit transfer mode. When wire feed rate is analyzed, we can estimate arc stability udner the condition of spray transfer mode as well. Hence, the wire feed rate is chosen for monitoring process variable to cover possible metal transfer modes in GMAW. Through this research, it has been identified that arc stability in GMA welding processes is closely related to wire fed rate. When inverter power source is used, conventional statistical method of estimating arc stability, such as Mita index, is no longer valid due to its controlled voltage and current wave forms. Arc stability has been also examined in phase plane diagram.

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Concurrent Modeling of Magnetic Field Parameters, Crystalline Structures, and Ferromagnetic Dynamic Critical Behavior Relationships: Mean-Field and Artificial Neural Network Projections

  • Laosiritaworn, Yongyut;Laosiritaworn, Wimalin
    • Journal of Magnetics
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    • v.19 no.4
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    • pp.315-322
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    • 2014
  • In this work, Artificial Neural Network (ANN) was used to model the dynamic behavior of ferromagnetic hysteresis derived from performing the mean-field analysis on the Ising model. The effect of field parameters and system structure (via coordination number) on dynamic critical points was elucidated. The Ising magnetization equation was drawn from mean-field picture where the steady hysteresis loops were extracted, and series of the dynamic critical points for constructing dynamic phase-diagram were depicted. From the dynamic critical points, the field parameters and the coordination number were treated as inputs whereas the dynamic critical temperature was considered as the output of the ANN. The input-output datasets were divided into training, validating and testing datasets. The number of neurons in hidden layer was varied in structuring ANN network with highest accuracy. The network was then used to predict dynamic critical points of the untrained input. The predicted and the targeted outputs were found to match well over an extensive range even for systems with different structures and field parameters. This therefore confirms the ANN capabilities and indicates the ANN ability in modeling the ferromagnetic dynamic hysteresis behavior for establishing the dynamic-phase-diagram.

Preparation and Characterization of Mesoporous Ni Film Made by Electroplating Method (전착법을 이용한 메조포러스 니켈 필름의 제조와 특성 분석)

  • Lee, Ji-Hoon;Baik, Young-Nam;Kim, Young-Seok;Shin, Seung-Han
    • Journal of the Korean institute of surface engineering
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    • v.40 no.1
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    • pp.16-22
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    • 2007
  • Recently, mesoporous metallic materials are becoming more and more important in various applications like catalysts, electrochemical detectors, batteries, and fuel cells because of their high surface area. Among the various methods for manufacturing mesoporous structure, surfactant templating method followed by electroplating has been tried in this study. A mesoporous metallic film was prepared by electrodeposition from electroplating solution mixed with surfactant template. Nonionic type lyotropic liquid crystalline surfactant, Brij56, and nickel acetate based solution were selected as a template material and electroplating solution, respectively. To determine the content of surfactant forming a hexagonal column structure, the phase diagram of electroplating solution and surfactant mixture has been exploited by polarized optical microscopy equipped with heating and cooling stage. Nickel films were electroplated on Cu foil by stepwise potential input method to alleviate the concentration polarization occurred during the electroplating process. TEM and XRD analyses were performed to characterize the size and shape of mesostructures in manufactured nickel films, and electrochemical characterization was also carried out using cyclic voltammetry.

DTERMINATION OF STBLE-UNSTABLE REGIONS OF THE SLOSH MOTION IN SPINNING SPACE VEHICLE BY PERTURBATION TECHNIQUE (PERTURBATION 방법을 이용한 회전안정화 우주비행체 내부 유동의 안정-불안정 영역 결정)

  • Kang, Ja-Young
    • Journal of Astronomy and Space Sciences
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    • v.22 no.4
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    • pp.513-526
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    • 2005
  • The objectives of this study are to perform extensive analysis on internal mass motion for a wider parameter space and to provide suitable design criteria for a broader applicability for the class of spinning space vehicles. In order to examine the stability criterion determined by a perturbation method, some numerical simulations will be performed and compared at various parameter points. In this paper, Ince-Strutt diagram for determination of stable-unstable regions of the internal mass motion of the spinning thrusting space vehicle in terms of design parameters will be obtained by an analytical method. Also, phase trajectories of the motion will be obtained for various parameter values and their characteristics are compared.

Environment Policy and Regional Economic Growth: Conflicting vs. Complementing (환경정책과 지역경제 : 상반관계 vs. 보완관계)

  • 김홍배;윤갑식
    • Journal of the Korean Regional Science Association
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    • v.15 no.1
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    • pp.63-73
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    • 1999
  • It is generally believed that there is a trade-off between economic growth and environmental quality since pollutants are generated in the process of production and consumption of commodities. Several researchers have shown this prevailing belief using the short-term input-output models. The literature, however, shows that there have been few attempts to investigate the relationship using long-term forecasting models. This motivates the current paper. This paper attempts to build a reginal growth model in a partial equilibrium framework taking into consideration the requirements of capital invested for pollutant abatement. Model is largely neoclassical. Labor is assumed to move a region with high utility specified in regional per capita average was income and pollution level while capital is partially mobile to a region with high returns. The regional growth is explored in a phase diagram. The paper shows that there are two stable growth equilibria which a region can converge over time and that the equilibria are distinguished by the initial threshold capital stock that a region holds. If the initial capital stock of a region is over(under) than the threshold size, the region converges to the higher (lower) growth equilibrium over time. Moreover, based on this result an environmental quality enhancing policy is analyzed in the phase diagram. It has revealed that the policy calls for the relocation of growth equilibrium points, specifically speaking, it stimulates an increase in labor stock and a decrease in capital stock. Hence the paper has suggested that the prevailing belief which the environmental policy negatively impacts on a regional economic growth is not always true.

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Solvent Extraction for the Recovery of Copper from Hydrochloric Etching Solutions by Alamine336 (염산에칭폐액으로부터 Alamine336에 의한 구리의 용매추출에 관한 연구)

  • 안재우;염재웅
    • Resources Recycling
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    • v.6 no.3
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    • pp.9-14
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    • 1997
  • A study has been made of the rccovery of copper (11) by solvent extraction with Alamine336 (Tri-n-oclylamine) as a extractant from hydrochloric etching solutions. The effect of extractant concentrations, hydrochloric acid, chloride Ion concentrations and phase ratio (organiclaqueaus) on copper extraction were studied. Experimental results showed that the concenl~atiano f extractant and the phase ratio strongly influenced the copper extraction, and the extraction percent of capper Increased at higher hydrochloric acid and chloride ion mncmhation. We proposed that the optimum extrachon stages of copper for continuous extraction process by analysidng thc McCabe-Thielc diagram. Stripping of copper from the loaded organic phases wn be accomplished by pure water (H, O) as a dripping reagent effectively. As the tcmpcrature is increased, thc stripping of copper is enhanced.

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