• Bulletin of the Korean Chemical Society
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• v.33 no.12
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• pp.4109-4116
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• 2012

An efficient solid-phase methodology has been developed for the synthesis of 2-amino and 2-amidobenzo[d]-oxazole derivatives. The key step in this procedure involves the preparation of polymer-bound 2-aminobenzo-[d]oxazole resins 4 by cyclization reaction of 2-hydroxy-phenylthiourea resin 3. The resin-bound 2-hydroxyphenylthiourea 3 is produced by the addition of 2-aminophenol to the isothiocyanate-terminated resin 2 and serve as a key intermediate for the linker resin. This core skeleton 2-aminobenzo[d]oxazole resin 4 undergoes functionalization reaction with various electrophiles, such as alkylhalides and acid chlorides to generate 2-amino and 2-amidobenzo[d]oxazole resins 5 and 6 respectively. Finally, 2-amino and 2-amidobenzo[d]oxazole derivatives 7 and 8 are then generated in good yields and purities by cleavage of the respective resins 5 and 6 under trifluoroacetic acid (TFA) in dichloromethane ($CH_2Cl_2$).

• Journal of Surface Science and Engineering
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• v.49 no.2
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• pp.135-140
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• 2016

In this study, we prepared magnesium ion containing oxide films formed on the Ti-6Al-4V using plasma electrolytic oxidation (PEO) treatment. Ti-6Al-4V surface was treated using PEO in Mg containing electrolytes at 270V for 5 min. The phase, composition and morphology of the Mg ion containing oxide films were evaluated with X-ray diffraction (XRD), Attenuated total reflectance Fourier transform infrared (ATR-FTIR) and filed-emission scanning electron microscopy (FE-SEM) with energy dispersive X-ray spectrometer (EDS). The biocompatibility of Mg ion containing oxide films was evaluated by immersing in simulated body fluid (SBF). According to surface properties of PEO films, the optimum condition was formed when the applied was 270 V. The PEO films formed in the condition contained the properties of porosity, anatase phase, and near 1.7 Ca(Mg)/P ratio in the oxide film. Our experimental results demonstrate that Mg ion containing oxide promotes bone like apatite nucleation and growth from SBF. The phase and morphologies of bone like apatite were influenced by the Mg ion concentration.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.16 no.6
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• pp.109-118
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• 2002

As Information society has expanded in large scale. In order to improve the reliability and Qos(Quality of service), domestic IDC(Internet Data Center) has adopted or will adopt the SLAs(Service Level Agreements). The power quality of internet hosting server unit, power system and UPS is very important for better internet service. Therefore, the higher reliability or power system is imperative for satisfying SLAs. This paper presents the status measurement of domestic IDCs harmonics and illustrates the reduction effect of harmonics through the multi-phase.

• Journal of Institute of Convergence Technology
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• v.2 no.1
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• pp.1-6
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• 2012

The cold chain system in South-East Asia is requiring to maintain freshness of refrigerated or frozen food. In this study, Thermal storage system using Phase change material (PCM) was developed and evaluated its performance about temperature and cold keeping time. For various application of cold chain system, we developed portable cold box, cold roll container and freezing station. Keeping time on laboratory tests of portable cold box in case of refrigeration and freezing were 6 hours and 4 hours, respectively. Cold container was developed to 2.5 ton scale. Evaluation in Indonesia, it was showed to keep the setting temperature of $-10^{\circ}C$ over 40 hours at $30^{\circ}C$ of ambient air. Freezing station using PCM was kept over 24 hours under $-20^{\circ}C$.

• Journal of Surface Science and Engineering
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• v.55 no.6
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• pp.376-382
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• 2022

Yb₂Si₂O₇ has a coefficient of thermal expansion similar to that of the base material of SiC and has excellent corrosion resistance in a high-temperature oxidizing atmosphere including water vapor, so it is being studied as one of the materials for environmental barrier coatings (EBCs). In this study, Yb₂Si₂O₇ powder granule is deposited using atmospheric plasma spraying (APS) with different Ar/He ratios. Phase formation and microstructural characteristics are investigated with the coated specimens. In the coating layer, the crystallinity decreased, and the amorphous content increased from an increase in the ratio of Ar. In addition, the various types of particles involved by local volatilization of Si according to the Ar/He ratios were identified.

• Journal of Microbiology and Biotechnology
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• v.31 no.1
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• pp.70-78
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• 2021

Identifying the extracellular metabolites of microorganisms in fresh vegetables is industrially useful for assessing the quality of processed foods. Pectobacterium carotovorum subsp. carotovorum (PCC) is a plant pathogenic bacterium that causes soft rot disease in cabbages. This microbial species in plant tissues can emit specific volatile molecules with odors that are characteristic of the host cell tissues and PCC species. In this study, we used headspace solid-phase microextraction followed by gas chromatography coupled with mass spectrometry (HS-SPME-GC-MS) to identify volatile compounds (VCs) in PCC-inoculated cabbage at different storage temperatures. HS-SPME-GC-MS allowed for recognition of extracellular metabolites in PCC-infected cabbages by identifying specific volatile metabolic markers. We identified 4-ethyl-5-methylthiazole and 3-butenyl isothiocyanate as markers of fresh cabbages, whereas 2,3-butanediol and ethyl acetate were identified as markers of soft rot in PCC-infected cabbages. These analytical results demonstrate a suitable approach for establishing non-destructive plant pathogen-diagnosis techniques as alternatives to standard methods, within the framework of developing rapid and efficient analytical techniques for monitoring plant-borne bacterial pathogens. Moreover, our techniques could have promising applications in managing the freshness and quality control of cabbages.

• Journal of Positioning, Navigation, and Timing
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• v.11 no.2
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• pp.83-89
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• 2022

For precise GNSS applications, the antenna phase center correction (PCC) is absolutely required. The PCC magnitude can reach the centimeter level with the antenna structure. In the present study, we first investigate the phase center offset (PCO) and phase center variation (PCO) of three different antenna models in two different reference frames, IGS08/igs08.atx and IGS14/igs14.atx. Clear L1 and L2 PCO differences were found between IGS08 and IGS14. In addition, the PCV showed characteristics that is dependent upon the signal direction (azimuth and elevation angle). The remarkable thing is that the changes of a Dorne Margolin choke-ring antenna model (AOAD/MT DOME) was very small in two reference frames. In order to analyze changes in positions according to different reference systems, GNSS data obtained from DAEJ, SUWN, and TSKB stations were processed by the precise point positioning (PPP) method. We suggest that an antenna PCO/PCV can affect the precise GNSS positioning on the order of several millimeters in two different reference frames.

• Macromolecular Research
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• v.17 no.5
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• pp.313-318
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• 2009

The side chain liquid crystal triblock copolymers (TBCs), which underwent phase transitions below their decomposition temperature, were prepared by copolymerization of poly(n-butyl acrylate) and a comonomer containing the mesogenic azobenzene group. The physical properties of TBCs in the distinctive transition temperature ranges were investigated in terms of the liquid crystal (LC) content in the copolymers. The phase transition temperatures traced optically, thermally and rheologically were well coincided one another and clearly exhibited the phase transition of smectic-nematic-isotropic with increasing temperature. In the smectic phase, increasing temperature made the liquid crystal system more elastic, but viscosity (${\eta}'$) remained almost constant. In the nematic phase, increasing temperature abruptly decreased ${\eta}'$ and G', ultimately leading to isotropic phase. Both smectic and nematic phases exhibited Bingham viscosity behavior but the former gave much greater yield stress at the same LC content.

• Journal of IKEEE
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• v.28 no.2
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• pp.187-198
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• 2024

Estimating the phase boundary in two-phase flow is crucial for designing and optimizing industrial processes. Electrical impedance tomography (EIT) is a promising technique for imaging phase distribution in such flows. This paper proposes using a cuckoo search (CS) optimization algorithm to estimate the phase boundary with EIT. The boundary is parameterized using the Fourier series, and the coefficients are determined by the CS algorithm. The CS algorithm iteratively seeks the phase boundary configuration by minimizing a cost function. Computer simulations and phantom experiments demonstrate the effectiveness of this method in estimating phase boundaries in two-phase flow.

• Proceedings of the KIPE Conference
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• 2012.07a
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• pp.335-336
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• 2012

본 논문에서는 출력 인덕터 전류의 리플을 저감할 수 있는 새로운 방식의 위상천이 풀 브리지 컨버터를 제안한다. 제안된 회로는 2개의 풀 브리지 인버터가 연결된 구조로 되어 있으며 하나의 풀 브리지 인버터가 고정 위상($0^{\circ}$)으로 동작할 때, 다른 풀 브리지 인버터의 위상을 조절하여 출력 전압을 제어하는 방식이다. 정상 동작 시, 제안회로는 기존 위상천이 풀 브리지 컨버터에 비해 출력 인덕터 전류 리플이 매우 작고, 2차 측 정류기의 공진 전압도 작아져 출력 LC 필터의 소형화 및 고효율화가 가능하여 대전류 사양에 매우 적합한 장점을 갖는다. 본 논문에서는 제안된 회로의 이론적인 특성을 분석하고, 450W 전원장치를 시작품으로 제작하여 그 우수성을 확인하였다.