• Title/Summary/Keyword: petroleum product

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An Application of GIS Technique to Analyze the Sales Area of Petroleum Products Distribution Facilities (GIS를 활용한 석유제품 유통기관의 판매권역 분석)

  • Kim, Min
    • Journal of the Korean Geographical Society
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    • v.39 no.3
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    • pp.360-373
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    • 2004
  • The purpose of this study is establishing how to build the area of local agents and regional offices in the oil company using GIS technique by reviewing on the spatial distribution pattern and characteristics of the sales area of oil products. Location-allocation and spatial interaction model are cooperated in order to establish sales area of petroleum products distribution system. Location-allocation model is used in the capital region where local agents are concentrated on like Kyoung-gi local agent. Spatial interaction model is used in the rest of the area in Korea to analyze the sales range of the regional offices in oil company. Each office made a big difference in registered cars and population because of the level of petroleum consumption in each sales area.

Difference of the Chemical Compositions Between Petroleum Ether Extract and its Tall Oil in Pitch Pine, Pinus Rigida Mill (리기다소나무재(材)의 유기용매(有機溶媒) 추출물(抽出物)과 그 tall oil 간의 조성(組成)의 차이(差異))

  • Ko, Sang-Woon;Ahn, Won-Yung
    • Journal of the Korean Wood Science and Technology
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    • v.16 no.2
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    • pp.79-89
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    • 1988
  • This experiment was carried out to investigate the difference of compositions between petroleum ether extract and its tall oil in Pinus rigida Mill. xylem and to obtain the basic data on effective extraction and its utilization of by-product, resin and fatty acid, when pulp making. After both petroleum ether extract from wood meal and its tall oil in pitch pine were separated to the resin and fatty acid by using DEAE-Sephadex and aluminum oxide column, these were analyzed with gas chromatograph. The results obtained were as follows: 1. Fatty acids contained as ester form in living trees were varied by peroxide of organic solvent in petroleum ehter extraction and cooking chemicals in cooking. 2. Pimaric-type acid was eluted earlier than abietic-type acid in resin acids and the fewer the carbons, the earlier the elution in fatty acids. 3. The retention time of SE-30 column was even smaller than that of OV-101 column but the relative retention time obtained by using methyl pimarate and methyl stearate as internal standard was nearly identical. 4. Both petroleum ether extract and tall oil mainly consisted of resin acids, expecially abietic-type acid. 5. Tall oil had more fatty acid but less resin acid than petroleum ether extract. Also, the content of unidentified materials was increased owing to the isomerization and the shift of double bond position in unsaturated fatty acids by high temperature and cooking chemicals when cooking.

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Determination Method of Hydrocarbon Compounds in DME-LPG Blending Fuels by Gas Chromatography with Deans Switching (Deans Switching을 이용한 가스크로마토그래피에서 DME-LPG 혼합연료의 탄화수소 화합물 분석방법)

  • Youn, Ju Min;Park, Cheon Kyu;Yim, Eui Soon;Jung, Choong Sub
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.353-357
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    • 2012
  • The new qualitative and quantitative analytical method for hydrocarbon compounds in DME-LPG blending fuel, mixing dimethyl ether (DME) with liquefied petroleum gas (LPG), by using gas chromatography (GC) was investigated. It is difficult to analyze all components of DME-LPG blending fuel by using single column in GC due to consisting of the non-polar LPG and the polar DME which is oxygen-containing compound. Therefore, it has been introduced the Deans switching system, which are useful for analyzing mixtures of a very different nature and/or target analytes in very complex matrix. This technique is to control the pressure between two columns and to selectively change the path of effluent flows to either one of two columns. As a result, we found that DME and LPG can be completely separated at the different columns and the determination of all hydrocarbon compounds in DME-LPG blending fuel can be achieved to this method qualitatively and quantitatively during the operation of one injection. In addition, this method can be applied to the determination of trace components of by-product, such as methanol, methyl formate and ethyl methyl ether, which will be derived from DME synthesis process.

Effects of reaction conditions on composition of the organic liquid product during the deoxygenation process of palm oil (팜유(Plam Oil)의 탈산소 공정 중 운전 조건이 생성물의 조성에 미치는 영향)

  • Kim, Sungtak;Jang, Jeong Hee;Ahn, Minhwei;Kwak, Yeonsu;Han, Gi Bo;Jeong, Byung Hun;Han, Jeong Sik;Kim, Jae-Kon
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.865-875
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    • 2018
  • Selection of optimum reaction conditions during deoxygenation process of palm oil is essential factor to obtain the maximum yield of bio-jet fuel. In this context, the deoxygenation of palm oil was carried out in a fixed bed reactor with an internal diameter of 1 inch loaded with a 1 wt.% $Pt/Al_2O_3$ catalyst. The composition of the organic liquid product(OLP), which can be utilized as a transportation fuel through the upgrading process, was analyzed by a gas chromatography method. The palm oil/hydrogen ratio and hydrogen pressure in the feed affected the decarboxylation(DCB) and hydrodeoxygenation(HDO) reactions, resulting in a change in the composition of the OLP. As the reaction temperature increased, the continuous cracking reaction of the deoxygenation product was promoted and the product composition in the $C_5{\sim}C_{14}$ region was increased. Thus, the results can help to understand the characteristics of deoxidation reaction of palm oil as well as the subsequent process, hydro-upgrading, to obtain the maximum yield of bio-jet fuel.

Chlorosmaridione; A Novel Chlorinated Diterpene Quinone Methide from Rosemarinus officinalis L.

  • El-Lakany, Abdalla M.
    • Natural Product Sciences
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    • v.10 no.2
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    • pp.59-62
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    • 2004
  • A novel chlorinated diterpene quinone methide; chlorosmaridione (7-chloro-11-hydroxy-abeita-7,9(11),13-triene-6,12-diode) was isolated from petroleum ether extract of the stems of Rosemarinus officinalis L. growing in Egypt. In addition, ${\beta}-sitosterol$, stigmasterol, lupeol acetate, ${\alpha}-amyrin,\;{\beta}-amyrin$, lupeol, acetyloleanolic acid, acetylursolic acid taxodione, horminone, and cryptotanshinone were also identified. Chemical structures of the isolated compounds have been elucidated on the bases of physical, chemical, and spectral data including IR, UV, MS, 1D-and 2D-NMR spectra.

New Rearranged Abietane Diterpenoids from the Roots of Salvia aegyptiaca L. Growing in Egypt

  • El-Lakany, Abdalla M.
    • Natural Product Sciences
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    • v.9 no.4
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    • pp.220-222
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    • 2003
  • Two new abietane diterpenes with rearranged skeleton; aegyptinol and aegyptinone C; have been isolated and identified for the first time from the anti-microbial petroleum ether extract of the roots of Salvia aegyptiaca L. Their chemical structures have been elucidated by interpretation of the detailed 1D-and 2D-NMR spectra, as well as other spectroscopic tools. In addition, full assignment of $^{13}C-NMR$ of aegyptinone B was also conducted for the first time.

Metabolism and Fermentation of Clostridium acetobutylicum (Clostridium acetobutylicum의 대사와 발효)

  • 이상엽
    • KSBB Journal
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    • v.8 no.1
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    • pp.1-9
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    • 1993
  • The acetone-butanol fermentation by C. acetobutylicum has gained increasing attention for the following reasons. First, the finite supply of petrochemical resources, combined with increasing concern over global environmental effects and the unstable nature of the price of petroleum has renewed interest in the development of fermentation technology that allows utilzation of biomass wastes for the production of alcohol. Second, it serves as excellent model system for understading the regulation and molecular biology of tightly regulated complex primary metabolism, and for applications of metabolic engineering. In this review various aspects of acetone-butanol fermentation by C. acetobutylicm including strain and fermentation characteristics, enzyme regulation, and solvent formation mechanism, and product recovery and summarized.

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Pervaporative Butanol Fermentation Using a New Bacterial Strain

  • Park, Chang-Ho
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.1 no.1
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    • pp.1-8
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    • 1996
  • Fermentation processes for the production of butanol had an economic importance in the first part of this century. Today butanol is commercially produced from the Oxo reaction of propylene because relatively low priced propylene during the cracking of petroleum. Efforts have been made during the past decade or two to improve the productivity of butanol fermentation processes. It includes strain improvements, continuous fermentation processes, cell immobilization and simultaneous product separation. This review introduces a new butanol fermentation process using pervaporative product separation and a new bacterial strain producing less amount of organic acids. This review also compares the new process with chemical processes. This kind of new fermentation process may be able to compete with the chemical synthesis of butanol and revitalize the butanol fermentation process.

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RINGS IN WHICH EVERY IDEAL CONTAINED IN THE SET OF ZERO-DIVISORS IS A D-IDEAL

  • Anebri, Adam;Mahdou, Najib;Mimouni, Abdeslam
    • Communications of the Korean Mathematical Society
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    • v.37 no.1
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    • pp.45-56
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    • 2022
  • In this paper, we introduce and study the class of rings in which every ideal consisting entirely of zero divisors is a d-ideal, considered as a generalization of strongly duo rings. Some results including the characterization of AA-rings are given in the first section. Further, we examine the stability of these rings in localization and study the possible transfer to direct product and trivial ring extension. In addition, we define the class of dE-ideals which allows us to characterize von Neumann regular rings.