• Polymer(Korea)
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• 제34권1호
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• pp.69-73
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• 2010

Effects of reaction time and temperature on the isomerization and dehydrobromination reactions of brominated butyl rubber were investigated. The structural composition of brominated butyl rubber was determined by Fourier transform infrared spectroscopy (FT-IR) and proton nuclear magnetic resonance spectroscopy($^1H$-NMR), Density functional theory (DFT) was used to study on the isomerization and dehydrobromination mechanisms of model compounds. The geometries for model compounds of 3-bromo-5,5,7,7-tetramethyl-2(2',2',4',4'-tetramethyl)pentyl-1-octylene (3BrOE), 1-bromo-5,5,7,7-tetramethyl-2(2',2',4',4'-tetramethyl)pentyl-2-octylene (1Br2OE) and 5,5,7,7-tetramethyl-2(2',2', 4',4'-tetramethyl)pentyl-1,3-octadiene (CD) had been optimized by using density functional theory at B3LYP/3-21G and B3LYP/6-31G levels. The predicted energy of 3BrOE lies higher than that of 1Br2OE which suggests that 1Br2OE configuration is more stable than the 3BrOE configuration. Compared with the energy barrier, the pathway of dehydrobromination is less competitive than that of isomerization. This is qualitatively consistent with the experimental results.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• 제20권3호
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• pp.147-155
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• 2010

This study was conducted to investigate the benzene exposure levels in coal chemical and petrochemical refining industries during BTX turnaround (TA) processes where benzene was being produced. Three companies producing benzene were selected, one coal chemical and two petrochemical industries. TA processes were classified into three stages: shut down, maintenance, and start up. Data was analyzed by classifying the refining method into 2 groups (Petrochemistry, Coal chemistry) for 823 workers. Comparing the data from petrochemical industries with data from a coal chemical refining industry, while benzene concentration levels of long-term samples during TA were not statistically different (p> 0.05), those levels of short-term samples were significantly different (p< 0.001). About 4.79 % of data in petrochemical industries exceed the occupational exposure limits (OELs) of benzene, 1 ppm. In a coal refining methods, about 15.7% exceeded the benzene OELs. The benzene concentrations in maintenance and start up stage of TA for petrochemical refineries were higher than those in a coal chemical refinery (p <0.01). These findings suggest that the coal chemical refining site requires more stringent work practice controls compare to petrochemical refining sites during TA processes. Personal protective equipments including organic respirators should be used by TA workers to protect them from benzene overexposure.

• Journal of the Economic Geographical Society of Korea
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• 제23권3호
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• pp.349-368
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• 2020

The aim of this study is to examine the relationship between the characteristics of Korean petroleum and petrochemical industries and the change of participation in global value chains. Since 1960s, Korean petroleum and petrochemical industries have been developed under government's industrial policies. In 1980s Korean petroleum and petrochemical industries served as a key export-oriented industry) of Korea's national economic development. Based on the expansion of large-scale production facilities led by the private sectors from the end of 1980s, Korea became as a major country in the global petroleum and petrochemical industries. Under Korean domestic scale, it shows considerable spatial concentration, in Ulsan Metropolitan City, Yeosu City and Seosan City. However, the degree of spatial concentration is differentiated along the each sectors within the petroleum and petrochemical industry. To improve regional industry competitiveness, each region has adopted different strategies and shifted to structural upgrading and producting high value-added products. Changes in the structure within petroleum and the petrochemical industries at the national level caused a change in the structure of Korea's participation in GVC, but the domestic value-added is lower than that of its major competitors.

• Journal of Korean Society for Atmospheric Environment
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• 제21권1호
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• pp.83-96
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• 2005

The purposes of this study were to characterize the local levels of VOCs (volatile organic compounds), to develop source profiles of VOCs, and to quantify the source contribution of VOCs using the CMB (chemical mass balance) model. The concentration of VOCs had been measured every 6-day duration in the SRO monitoring site in the Yeosu Petrochemical Industrial Complex from September 2000 to August 2002. The total of 35 target VOCs, which were included in the TO-14 designated from the U.S. EPA, was selected to be monitored in the study area. During a 24-h period, the ambient VOCs were sampled by using canisters placing about 10 ～ 15 m above the ground level. The collected canisters were then analyzed by a GC-MS in the laboratory. Aside from ambient sampling at the SRO site, the VOCs had been intensively and massively measured from 8 direct sources and 4 general sources in the study area. The results obtained in the study were as follows; first, the annual mean concentrations of the target VOCs were widely distributed regardless of monitoring sites in the Yeosu Petrochemical Industrial Complex. In particular, the concentrations of BTX (Benzene, Toluene, Xylene), vinyl chloride were higher than other target compounds. Second, based on these source sample data, source profiles for VOCs were developed to apply a receptor model, the CMB model. Third, the results of source apportionment study for the VOCs in the SRO Site were as follows; The source of petrochemical plant was apportioned by 31.3% in terms of VOCs mass. The site was also affected by 16.7% from wastewater treatment plant, 14.0% from iron mills, 8.4% from refineries, 4.4% from oil storage, 3.8% from automobiles, 2.3% from fertilizer, 2.3% from painting, 2.2% from waste incinerator, 0.6% from graphic art, and 0.4% from gasoline vapor sources.

• Proceedings of the Polymer Society of Korea Conference
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.137-138
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• 2006

TPOs based on polypropylene has been dominating materials in hard automotive parts such as in bumper fascia, instrumental panel and door trim panel owing to their variety of advantages compared to engineering plastics and steels for years. Recently as environmental regulations related to recycle have been strengthened, the use of TPOs in soft automotive parts such as instrument panel skin and door trim skin is being required much more.. Therefore, in this study, we' d like to give an overview of soft TPOs and introduce soft TPO materials requirement and preferable materials composition by vacuum thermoforming and powder slush molding, respectively.

• Proceedings of the KIEE Conference
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• 대한전기학회 1999년도 하계학술대회 논문집 C
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• pp.1224-1226
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• 1999

When electrical engineers get started with the design of main electrical system of a complex petrochemical plant along with chemical and mechanical engineers, they are usually confronted with lack of power system data. This paper presents a procedure how to perform power system stability analysis for the purpose of design studies within the limited system data given and to verify the given data to get reliable convergence in dynamic simulation as well as to apply the stability analysis result on practical system design. The power system stability analysis on the Cadereyta petrochemical plant in Mexico is provided as a study case.

• Journal of the Korea Safety Management & Science
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• 제9권1호
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• pp.51-63
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• 2007

It is noted that the disaster such as fire, explosion, collapse has been rapidly increased caused by strength deterioration of steel structures at petrochemical plant during fire. In this regard, it is stressed out that the legal requirement for fire proofing for steel structures at petrochemical plant should be carefully reviewed since the current legal requirement such as Industrial Safety & Health Law, Architectural Law has a conflict and different way of approach. In addition, it is our point of view that the present law should be revised to consolidate into single law including engineering design criteria to reflect unreasonable legal requirement. It is further our point of view that the performance certificate for fire proofing like UL-1709, basis of maintenance should be appropriately and reasonably provided in line with global practice.

• Journal of Information Processing Systems
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• 제20권3호
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• pp.399-408
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• 2024

The moisture content of crude oil notably affects various aspects of oil production, storage, transportation, and exploration. However, accurately measuring this moisture content is challenging because of numerous influencing factors, leading to a lack of precision in existing detection methods. This inadequacy hinders the progress of China's petroleum industry. To overcome these challenges, this paper proposes a conductivity-based method for measuring crude oil moisture content. By employing an embedded system, we designed a sensor comprising five electrodes. Additionally, we developed signal excitation and signal processing circuits. Moreover, a software program was designed to analyze and compute the output signal using fast Fourier transform operations. This facilitated the identification of flow patterns, computation of relevant flow rates, and establishment of correlation rates based on frequency spectral characteristics. Based on experimental results, we established a functional relationship between measurement parameters and crude oil moisture content. This study enhanced the precision of moisture content measurement, thereby addressing existing limitations and fostering the advancement of China's petroleum industry.

• Journal of Preventive Medicine and Public Health
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• 제33권2호
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• pp.174-183
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• 2000

Objectives : To evaluate the effect of low-level exposure of air pollutants on the respiratory tract of the children living near the petrochemical estate in Ulsan. Methods : The study design was cross-sectional, and the study subjects consisted of 150 children(76 boys, 74 girls) living near the petrochemical estate and 100 children(53 boys, 47 girls) living in a suburban area. We investigated respiratory health using self-administered questionnaires(ATS-DLD-78) , radiological examination, and pulmonary function test such as FVC and FEV1. Results : There were higher prevalence rates of respiratory symptoms in the children living near the petrochemical estate than the children living in a suburban area. And the results of FVC and FEV1 of 11-years old children living near the petrochemical estate were lower than those of the children living in a suburban area. Conclusions : Chronic exposure of low-level air pollutants would affect respiratory health of the children. Therefore, further a longitudinal study of respiratory health will be needed for children living near the petrochemical estate in Ulsan.

• Applied Chemistry for Engineering
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• 제33권5호
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• pp.538-544
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• 2022

One of the most exciting areas for the development of alternative fuels is the production of biodiesel. To reduce the cost of biodiesel production, in situ trans-esterification has been introduced to simplify the production process by enabling extraction and trans-esterification to occur at a single stage in the presence of a catalyst. In this study, we investigated the feasibility of using non-corrosive and environmentally receptive flying jet plasma as an alternative catalytic route for in situ tran-sesterification of castor bean seeds (CBS). Upon optimizing the reaction conditions, it is elucidated that applying a low ratio of methanol to seeds (≤6:1) has resulted in hindering the in situ trans-esterification and leading to insignificant conversion. The yield of esters has increased from 80.5% to 91.7% as the molar ratio rose from 9:1 to 12:1. Excess alcohol beyond the ratio of 15:1 was shown to have a negative impact on the yield of the produced esters, attributed to an increase in the biodiesel portion prone to dissolving in the co-product (glycerol). An increase in the reaction bulk temperature from 40 to 55 ℃ led to a higher ester content by 50%. Further increases in the bulk temperature beyond 55 ℃ did not affect yields. Regarding the reaction period, the results have shown that 3 h of reaction is adequate for a higher biodiesel yield. The quality of the biodiesel obtained has demonstrated that all physicochemical properties meet the ASTM D6751 specifications.