• Title/Summary/Keyword: penetration mechanism

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Composite TiN-Al2O3 Syntheses and Hydrogen Permeability Characteristics Evaluation (복합 TiN-Al2O3 합성과 수소투과도 특성 평가)

  • CHO, KYOUNG-WON;LEE, YOUNG-HWAN;HAN, JEONG-HEUM;YU, JE-SEON;HONG, TAE-WHAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.2
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    • pp.177-183
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    • 2020
  • To utilize hydrogen energy, high-yield, high-purity hydrogen needs to be produced; therefore, hydrogen separation membrane studies are being conducted. The membrane reactor that fabricates hydrogen needs to have high hydrogen permeability, selective permeability, heatresistant and a stable mechanical membrane. Dense membranes of Pd and Pd alloys are usually used, but these have drawbacks associated with high cost and durability. Therefore, many researchers have studied replacing Pd and Pd alloys. Dense TiN membrane is highly selective and can separate high-purity hydrogen. The porous alumina has a high permeation rate but low selectivity; therefore, separating high-purity hydrogen is difficult. To overcome this drawback, the two materials are combined as composite reclamations to produce a separation membrane with a high penetration rate and high selectivity. Accordingly, TiN-alumina was manufactured using a high-energy ball mill. The TiN-alumina membrane was characterized by X-ray diffraction analysis, scanning electron microscopy, and energy dispersive spectroscopy. The hydrogen permeability of the TiN-alumina membrane was estimated by a Sievert-type hydrogen permeation membrane apparatus. Due to the change in the diffusion mechanism, the transmittance value was lower than that of the general TiN ceramic separator.

Applications and Prospects of Calcium Carbonate Forming Bacteria in Construction Materials (건축공학분야에서 탄산칼슘형성세균의 응용과 전망)

  • Park, Sung-Jin;Ghim, Sa-Youl
    • Microbiology and Biotechnology Letters
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    • v.40 no.3
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    • pp.169-179
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    • 2012
  • Microbiological calcium carbonate precipitation (MCCP) is being applied for the aesthetic restoration of cement buildings destroyed by biochemical processes and to block water penetration into the cement's inner structure. After determining the advantages of this technique, many related studies in the area of architecture concerning the application of microorganisms to improve construction material have been reported in both America and Europe. The techniques compatibility with cement material is especially interesting because of the needed screening of various calcium carbonate forming-bacteria and the required development of their application methods. The purpose of this review is to describe the mechanism of MCCP and related researches with eco-friendly construction materials. Mainly, we describe the methodological studies focused on biodeposition on the surface of building materials and the research trends concerning the addition of microorganisms to improve the durability of cement structures. Additionally, the concepts and technical aspects focused on the development of self-healing smart concrete, with the use of multi-functional bacteria, have been considered.

Effect of Temperature/Humidity Treatment Conditions on Interfacial Adhesion of Electroless-plated Ni on Polyimide (고온다습처리 조건이 무전해 니켈 도금 박막과 폴리이미드 사이의 계면 접착력에 미치는 영향)

  • Min, Kyoung-Jin;Jeong, Myeong-Hyeok;Lee, Kyu-Hwan;Jeong, Yong-Soo;Park, Young-Bae
    • Korean Journal of Metals and Materials
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    • v.47 no.10
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    • pp.675-680
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    • 2009
  • Effects of $85^{\circ}C/85%$ Temperature/Humidity (T/H) treatment conditions on the peel strength of an electroless-plated Ni/polyimide system were investigated from a $180^{\circ}$ peel test. Peel strength between electroless-plated Ni and polyimide monotonically decreased from $37.4{\pm}5.6g/mm$ to $22.0{\pm}2.7g/mm$ for variation of T/H treatment time from 0 to 1000 hrs. The interfacial bonding mechanism between Ni and polyimide appears to be closely related to Ni-O bonding at the Ni/polyimide interface. The decrease in peel strength due to T/H treatment appears to be related to polyimide degradation due to moisture penetration through the interface and the bulk polyimide itself.

A Study on the Development of Higher Education Internationalization Advocating One Belt One Road (일대일로를 옹호하는 고등 교육 국제화 발전 연구)

  • Wang, Guanen
    • Journal of the International Relations & Interdisciplinary Education
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    • v.1 no.1
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    • pp.80-94
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    • 2021
  • The "Belt and Road" economic development strategy provides new ideas for the transformation of my country's higher education. Under the guidance of the new development concept and relying on a good competitive platform, my country's higher education will have more possibilities for internationalization. The analysis of the connotation of the development concept of my country's higher education internationalization is mainly reflected in the development and tolerance of my country's higher education, and the innovation and sharing of development concepts. With this as the direction, my country's higher education institutions can combine the school's own school-running philosophy to formulate new teaching standards that are in line with international rules. Do a good job in the penetration of our country's excellent traditional culture, and handle the relationship between cultures of various countries. Actively learn from international advanced teaching concepts to build a scientific and perfect talent training mechanism.

Properties of Pinus densiflora Timber Wood by High Temperature Linseed Oil Treatment (고온아마인유처리에 의한 소나무재의 특성)

  • Lee, Dong-heub;Lee, Myung-Jae;Oh, Hyung-Min;Son, Dong-won
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.2
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    • pp.50-57
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    • 2004
  • This study attempted to evaluate the water repellency and drying effectiveness of linseed oil treated-solid wood at high temperature by immersion. The moisture content of green wood (Pinus densiflora) sample (above 90%) was reduced about 10% after 6 hours treatment at 150℃. When the treated samples were cut into cross section along the length, it was observed that the linseed oil penetrated into up to 20% of the sample cross section area in all locations. However, a strength loss of the specimen was not detected. The pre-drilling before linseed oil treatment was effective in reducing the defects such as checks and splits, and improved the linseed oil penetration into all samples from the surfaces. The result of water absorption test of treated-wood showed that the water repellent efficacy of treated-wood was greater than that of the control. The anti-fungal activity of treated samples using five sap stains and thee decay fungi was not detected in broad-spectrum toxic mechanism. However, decay test using white rot fungi (Tyromyces palustris) and brown rot fungi (Trametes versicolor) showed that the treated sample has a decay resistance to these two fungi.

High-velocity ballistics of twisted bilayer graphene under stochastic disorder

  • Gupta, K.K.;Mukhopadhyay, T.;Roy, L.;Dey, S.
    • Advances in nano research
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    • v.12 no.5
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    • pp.529-547
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    • 2022
  • Graphene is one of the strongest, stiffest, and lightest nanoscale materials known to date, making it a potentially viable and attractive candidate for developing lightweight structural composites to prevent high-velocity ballistic impact, as commonly encountered in defense and space sectors. In-plane twist in bilayer graphene has recently revealed unprecedented electronic properties like superconductivity, which has now started attracting the attention for other multi-physical properties of such twisted structures. For example, the latest studies show that twisting can enhance the strength and stiffness of graphene by many folds, which in turn creates a strong rationale for their prospective exploitation in high-velocity impact. The present article investigates the ballistic performance of twisted bilayer graphene (tBLG) nanostructures. We have employed molecular dynamics (MD) simulations, augmented further by coupling gaussian process-based machine learning, for the nanoscale characterization of various tBLG structures with varying relative rotation angle (RRA). Spherical diamond impactors (with a diameter of 25Å) are enforced with high initial velocity (Vi) in the range of 1 km/s to 6.5 km/s to observe the ballistic performance of tBLG nanostructures. The specific penetration energy (Ep*) of the impacted nanostructures and residual velocity (Vr) of the impactor are considered as the quantities of interest, wherein the effect of stochastic system parameters is computationally captured based on an efficient Gaussian process regression (GPR) based Monte Carlo simulation approach. A data-driven sensitivity analysis is carried out to quantify the relative importance of different critical system parameters. As an integral part of this study, we have deterministically investigated the resonant behaviour of graphene nanostructures, wherein the high-velocity impact is used as the initial actuation mechanism. The comprehensive dynamic investigation of bilayer graphene under the ballistic impact, as presented in this paper including the effect of twisting and random disorder for their prospective exploitation, would lead to the development of improved impact-resistant lightweight materials.

Development of an Empirical Equation for Estimating Lond Transfer Curve for Micropile in Weathered Soils (풍화지반에 근입된 마이크로파일의 하중전이곡선 추정을 위한 경험식 개발)

  • Park, Seong-Wan;Cho, Kook-Hwan;Roh, Kang-Koo
    • Journal of the Korean Geotechnical Society
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    • v.23 no.1
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    • pp.5-11
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    • 2007
  • Micropiles have been used for underpinning or rehabilitation of existing foundations, and direct structural support system as well. However, relatively few studies have been done on the load-transfer mechanism of micropile systems in Korea. In addition to that, only the limited information is available for estimating the side friction values on micropiles installed in weathered soils. In this study, a full-scale test on an instrumented micropile is performed in order to establish the load-transfer curves based on a hyperbolic function. Then, an empirically derived equation that correlates the load-transfer curve of micropiles with the N values from field standard penetration tests is proposed. The results from all procedures are presented in this paper. Finally, back analysis using a finite difference method and the published field data are adopted for examination of a developed skin friction equation of micropile in weathered soils respectively.

Transport Coefficients and Effect of Corrosion Resistance for SFRC (강섬유 보강 콘크리트의 수송계수 및 부식저항효과)

  • Kim, Byoung-Il
    • Journal of the Korea Concrete Institute
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    • v.22 no.6
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    • pp.867-873
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    • 2010
  • This study investigated the corrosion properties of reinforced concrete with the addition of steel fibers. The transport properties of steel fiber-reinforced concrete such as permeable void, absorption by capillary action, water permeability and chloride diffusion were first measured to evaluate the relationship with the corrosion of steel rebar. Test results showed a slight increase on the compressive strength with the addition of steel fibers as well as considerable improvement of penetration resistance to mass transport of harmful materials into concrete. The addition of steel fibers in reinforced concrete accelerated the initiation of steel corrosion contrary to the expected results based on the measured transport properties. The NaCl ponding surface showed the spalling failure due to the corrosion expansion of steel fibers and the cut-surface around the steel rebar showed the localized steel fiber's corrosion. The wet-dry cycling with high chloride ions as well as high temperature seems to induce the increase of salt crystallization on the pores continually and the increased pressure with the steel fiber's corrosion on the pores caused the spalling failure on the exposed surface. The microcracking on the surface therefore accelerated the movement of water, chloride ions and oxygen into the embedded steel rebar. The mechanism affecting corrosion of embedded steel reinforcement with steel fibers in this study are not yet fully understood and require further study comprising of accurate experimental design to isolate the effect of steel fiber's potential mechanism on the corrosion process.

Cellular Protective Effects and Mechanisms of Kaempferol and Nicotiflorin Isolated from Annona muricata against 1O2-induced Damage (그라비올라로부터 분리된 Kaempferol 및 Nicotiflorin의 1O2으로 유도된 세포손상에 대한 보호 효과와 그 메커니즘)

  • Park, So Hyun;Shin, Hyuk Soo;Lee, Nan Hee;Hong, In Kee;Park, Soo Nam
    • Applied Chemistry for Engineering
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    • v.29 no.1
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    • pp.49-55
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    • 2018
  • In this study, we investigated the cellular protective effects and mechanisms of nicotiflorin and its aglycone kaempferol isolated from Annona muricata. The protective effect of these components against $^1O_2$-induced cell damage was also studied by using L-ascorbic acid and (+)-${\alpha}$-tocopherol as controls. Kaempferol exhibited the most potent protective effect, followed by (+)-${\alpha}$-tocopherol and nicotiflorin. L-Ascorbic acid did not exhibit any cellular protective effects. To elucidate the mechanism underlying protective effects, the quenching rate constant of the singlet oxygen, free radical-scavenging activity, ROS-scavenging activity, and uptake ratio of the erythrocyte membrane were measured. The results showed that the cell membrane penetration is a key factor determining the cellular protective effect of kaempferol and its glycoside nicotiflorin. The result from L-ascorbic acid demonstrated that the cellular protective effect of a compound depends on its ability to penetrate the cell membrane and is independent of its antioxidant capacity. In addition, it is suggested that cellular protective effects of kaempferol and (+)-${\alpha}$-tocopherol depend not only on the cell permeability, but also on free radical- and ROS-scavenging activities. These results indicate that the cell permeability and free radical- and ROS- scavenging activities of antioxidants are major factors affecting the protection of cell membranes against the oxidative damage induced by photosensitization reaction.

Effects of Geometry of Reactor Pressure Vessel Upper Head Control Rod Drive Mechanism Penetration Nozzles on J-Groove Weld Residual Stress (원자로 상부헤드 제어봉구동장치 관통노즐 형상이 J-Groove 용접잔류응력에 미치는 영향)

  • Kim, Ju-Hee;Kim, Yun-Jae;Lee, Sung-Ho;Hur, Nam-Young;Bae, Hong-Yeol;Oh, Chang-Young;Kim, Ji-Soo;Park, Heung-Bae;Lee, Seung-Geon;Kim, Jong-Sung;Huh, Nam-Su
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.10
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    • pp.1337-1345
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    • 2011
  • In pressurized water reactors (PWRs), the reactor pressure vessel (RPV) upper head contains numerous control rod drive mechanism (CRDM) nozzles. In the last 10 years, the incidences of cracking in alloy 600 CRDM nozzles and their associated welds has increased significantly. Several axial and circumferential cracks have been found in CRDM nozzles in European PWRs and U.S. nuclear power plants. These cracks are caused by primary water stress corrosion cracking (PWSCC) and have been shown to be driven by welding residual stresses and operational stresses in the weld region. Therefore, detailed finite-element (FE) simulations for the Korea Nuclear Reactor Pressure Vessel have been conducted in order to predict the magnitudes of the weld residual stresses in the tube materials. In particular, the weld residual stress results are compared in terms for nozzle location, geometry factor$r_o$/t, geometry of fillet, and adjacent nozzle.