• Title/Summary/Keyword: pceC

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Effects of $O_2$ Plasma Treatment on the Electrical Properties of Organic Photovoltaic Cell (유기 광기전 소자의 전기적 특성에 미치는 산소 플라즈마 처리의 영향)

  • Oh, Dong-Hoon;Lee, Young-Sang;Park, Hee-Doo;Shin, Jong-Yeol;Kim, Tae-Wan;Hong, Jin-Woong
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1463-1464
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    • 2011
  • An indium thin oxide(ITO) is used as a substrate material for organic light-emitting diodes(OLEDs) and organic photovoltaic cells. This study examined the effects of an $O_2$ plasma treatment on the electrical properties of an organic photovoltaic cell. The four probe method and Atomic force microscope(AFM) revealed the lowest surface resistance at the plasma treatment intensity of 250 [W] and the lowest average surface roughness of 2.0 [nm] at 250 [W]. The lowest average resistance of 17 [${\Omega}$/sq] was also observed at 250 [W] 40 [sec]. The $O_2$ plasma treatment device and a basic device in a structure of CuPc/C60/BCP/Al on ITO glass were fabricated by thermal evaporation, respectively. When the $O_2$ plasma treatment was used to the ITO, The experimental results revealed that the power conversion efficiency(PCE) indicated 65 [%] higher in the PCE than that without the plasma treatment.

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Property of CdTe/CdS Solar Cells on Gamma-irradiation (방사선에 대한 CdTe/CdS 태양전지 특성 검토)

  • Kim, Ji-Yoo;Kim, Hwa-Jung;Park, Hae-Jun;Ha, Jang-Ho
    • Journal of Radiation Industry
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    • v.8 no.1
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    • pp.17-22
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    • 2014
  • In this study, we prepared CdTe/CdS solar cells using a thermal vacuum evaporation method. In particular, $CdCl_2$ treatment was attempted using this same method at $400^{\circ}C$ for 30 min. The prepared CdTe/CdS solar cells were investigated using Fouier transform infrared spectrometry (FTIR), field emission scanning electron microscopy (FE-SEM), and a solar simulator system including light absorption properties, morphological properties, and power conversion efficiency (PCE). In addition, we investigated the gamma-irradiation treatment at dose rates of 0 Gy, 500 Gy, 1 kGy, 10 kGy, and 30 kGy. The characteristics of gamma-irradiation treatment were studied based on the same method described above. In particular, it showed increased values as 0.826% higher than the non-irradiation of 0.448% from PCE analysis.

Micropower energy harvesting using high-efficiency indoor organic photovoltaics for self-powered sensor systems

  • Biswas, Swarup;Lee, Yongju;Kim, Hyeok
    • Journal of Sensor Science and Technology
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    • v.30 no.6
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    • pp.364-368
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    • 2021
  • We developed a highly efficient organic photovoltaic (OPV) cell with a poly[4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b;4,5-b']dithiophene-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene-)-2-carboxylate-2-6-diyl)]:[6,6]-phenyl-C71-butyric acid methyl ester active layer for harvesting lower-intensity indoor light energy to power various self-powered sensor systems that require power in the microwatt range. In order to achieve higher power conversion efficiency (PCE), we first optimized the thickness of the active layer of the OPV cell through optical simulations. Next, we fabricated an OPV cell with optimized active layer thickness. The device exhibited a PCE of 12.23%, open circuit voltage of 0.66 V, short-circuit current density of 97.7 ㎂/cm2, and fill factor of 60.53%. Furthermore, the device showed a maximum power density of 45 ㎼/cm2, which is suitable for powering a low-power (microwatt range) sensor system.

Improved Solubility and Characterization of Photovoltaic Properties D/A Copolymers based on Rigid Structure of Phenothiazine-Quinoxaline (Rigid한 Phenothiazine-Quinoxaline D/A 공액 고분자 구조의 용해성 향상 연구 및 유기박막태양전지로의 특성 분석)

  • Seong, Ki-Ho;Yun, Dae-Hee;Park, Yong-Sung
    • Clean Technology
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    • v.20 no.4
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    • pp.415-424
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    • 2014
  • In this study, two kinds of polymer (PPQX-2hdPTZ (P1), POPQX-2hdPTZ (P2)) were synthesised by Suzuki coupling reaction based on phenothiazine derivative as electron-donor and quinoxaline derivative as electron-acceptor. Microwave synthesis workstation was used to shorten the polymerization time and increase the degree of polymerization. The physical, thermal stability, optical and electrochemical properties of the synthesized polymer were confirmed. The thermal stability of two polymers was outstanding as the initial decomposition temperature was $323-328^{\circ}C$. And additional substituted alkoxy chain on P2 showed higher degree of polymerization. An analysis of electrochemical properties, all polymer had similar HOMO energy level values. Device was fabricated by ITO/PEDOT:PSS/active layer/$BaF_2$/Al structure and photovoltaic properties were confirmed. Each device has a different film thickness and the resulting change in PCE was confirmed. As a result the thinner thickness of the film showed a high efficiency ($PCE_{max}:P1=1.0%$, P2 = 1.1%).

Fabrication and Characterization of Organic Solar Cells with Gold Nanoparticles in PEDOT:PSS Hole Transport Layer (PEDOT:PSS 정공 수송층에 금 나노입자를 첨가한 유기태양전지의 제작 및 특성 연구)

  • Kim, Seung Ho;Choi, Jae Young;Chang, Ho Jung
    • Journal of the Microelectronics and Packaging Society
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    • v.20 no.2
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    • pp.39-46
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    • 2013
  • In this paper, organic solar cells(OSCs) based on bulk-heterojunction structures were fabricated by spin coating method using polymer P3HT and fullerene PCBM as a photoactive layer. The fabricated OSCs had a simple glass/ITO/PEDOT:PSS/P3HT:PCBM/Al structures. The photoactive layer of mixed P3HT:PCBM was formed with 1:1 weight ratio. The hole transport layer(HTL) was used conducting polymer PEDOT:PSS concentration with gold nanoparticles. The annealing temperature and concentration of nanoparticles in HTL were verified to improve the OSC characterization. The percentage of gold nanoparticles in HTL were 0.5 wt% and 1.0 wt%, and the surface morphology, electrical properties and absorption intensities were investigated. The devices were 0.5 wt%, and the highest 3.1% of the powder conversion efficiency(PCE), 10.2 $mA/cm^2$ of the maximum short circuit current density($J_{SC}$), 0.535V of the open circuit voltage($V_{OC}$) and 55.8% of the fill factor(F.F) could be obtained when the nanoparticle concertration was 0.5 wt%. The annealing temperature of HTL was $110^{\circ}C$, $130^{\circ}C$, $150^{\circ}C$ in vacuum oven and measured the absorption intensities, surface morphology, crystallinity and electrical properties were investigated. The best property was obtained in HTL annealed at $130^{\circ}C$ for gold nanoparticles of 0.5 wt%, showing that $J_{SC}$, $V_{OC}$, F.F and PCE were about 12.0 $mA/cm^2$, 0.525V, 64.2% and 4.0%, respectively.

Study on the Development of Super-High-Early-Strength Mortar Using the Hardening catalyst and High early strength cement (조강시멘트를 사용한 초조강 모르타르 개발에 관한 연구)

  • Cho, In-Sung;Hur, Yeon-Ok;Min, Tae-Beom;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.11a
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    • pp.217-219
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    • 2012
  • In this study, the experiment was conducted in the level of mortar as one of the basic studies on pre-cast concrete which acceleration curing is not done. This study has the purpose to develop the strength of mortar into 20MPa within 6 hours in the condition of room temperature using admixtures which can accelerate C3S hydration reaction. In this experiment, W/C was fixed into 20%, PCE which can stimulate C3S was used as an accelerating admixture. From the results of this experiment, maximum content of accelerating admixture was 1%. Also, as more than 20MPa was measured through 6-hour compressive strength, it can be known that strength can be developed without steam-curing.

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Analysis of Thermal Annealing Effect on the Power Conversion Efficiency of Heterojunction Organic Photovoltaics (Annealing 온도에 따른 bulk heterojunction 유기태양전지의 특성분석)

  • Kim, Y.H.;Kim, M.S.;Park, S.K.;Kang, J.W.;Han, J.I.
    • Proceedings of the KIEE Conference
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    • 2008.10a
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    • pp.177-178
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    • 2008
  • 열처리 조건이 이종접합 유기태양전제(heterojunction organic photovoltaics)의 power conversion efficiency(PCE)에 미치는 영향에 대해 살펴보았다. 본 연구에서는 열처리 온도와 열처리 시간을 변수로 다양한 조건하에서 유기태양전지를 제작하고 AM1.5G 조건에서의 효율 변화를 관찰하였다. 열처리 온도는 $90^{\circ}C$에서 $170^{\circ}C$까지 변화시키며 태양전지의 특성변주를 측정하였으며, 유리 기판 상에 제작된 태양전지의 경우에 $150^{\circ}C$의 열처리 온도에서 가장 우수한 효율을 나타내었다.

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New Generation Multijunction Solar Cells for Achieving High Efficiencies

  • Lee, Sunhwa;Park, Jinjoo;Kim, Youngkuk;Kim, Sangho;Iftiquar, S.M.;Yi, Junsin
    • Current Photovoltaic Research
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    • v.6 no.2
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    • pp.31-38
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    • 2018
  • Multijunction solar cells present a practical solution towards a better photovoltaic conversion for a wider spectral range. In this review, we compare different types of multi-ijunction solar cell. First, we introduce thin film multijunction solar cell include to the thin film silicon, III-V material and chalcopyrite material. Until now the maximum reported power conversion efficiencies (PCE) of solar cells having different component sub-cells are 14.0% (thin film silicon), 46% (III-V material), 4.4% (chalcopyrite material) respectively. We then discuss the development of multijunction solar cell in which c-Si is used as bottom sub-cell while III-V material, thin film silicon, chalcopyrite material or perovskite material is used as top sub-cells.

Interfacially Controlled Hybrid Thin-film Solar Cells Using a Solution-processed Fullerene Derivative

  • Nam, Sang-Gil;Song, Myeong-Gwan;Kim, Dong-Ho;Kim, Chang-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.190.2-190.2
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    • 2014
  • We report the origin of the improvement of the power conversion efficiency (PCE) of hybrid thin-film solar cells when a soluble C60 derivative, [6,6]-phenyl-$C_{61}$-butyric acid methyl ester (PCBM), is introduced as a hole-blocking layer. The PCBM layer could establish better interfacial contact by decreasing the reverse ark-saturation current density, resulting in a decrease in the probability of carrier recombination. The power conversion efficiency of this optimized device reached a maximum value of 8.34% and is the highest yet reported for hybrid thin-film solar cells.

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Properties of a Hexane-Degrading Consortium (Hexane 분해 혼합균의 특성)

  • Lee Eun-Hee;Kim Jaisoo;Cho Kyung-Suk
    • Microbiology and Biotechnology Letters
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    • v.33 no.3
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    • pp.215-221
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    • 2005
  • It was characterized the hexane biodegradation and mineralization using a hexane-degrading consortium, and analyzed its bacterial community structure by 16S rDNA PCR-DGGE (denaturing gradient gel electrophoresis). The specific growth rate (${\mu}_{max}$) of the hexane-degrading consortium was 0.2 $h^{-1}$ in mineral salt medium supplemented with hexane as a sole carbon source. The maximum degradation rate ($V_{max}$) and saturation constant ($K_{s}$) of hexane of the consortium are 460 ${\mu}mol{\cdot}g-DCW^{-1}{\cdot}h^{-1}$ and 25.87 mM, respectively. In addition, this consortium could mineralize $49.1{\%}$ of $^{14}C$-hexane to $^{14}CO_2$, and $43.6{\%}$ of $^{14}C$-hexane) was used for the growth of biomass. The clones isolated from the DGGE bands were closely related to the bacteria which were capable of degrading pollutants such as oil, biphenyl, PCE, and waste gases. The hexane-degrading consortium obtained in this study can be applied for the biological treatment of hexane.