• Title/Summary/Keyword: pcbs

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Distribution of Organochlorines and PCB Congeners In Korean Human Tissues

  • Park, Mee-Jung;Lee, Sang-Ki;Yang, Ja-Yeol;Kim, Ki-Wook;Lee, Su-Yeon;Lee, Won-Tae;Chung, Kyu-Hyuck;Yun, Yeo-Pyo;Yoo, Young-Chan
    • Archives of Pharmacal Research
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    • v.28 no.7
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    • pp.829-838
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    • 2005
  • In order to investigate the residual amounts of organochlorines and polychlorinated biphenyls (PCBs) in Korean human tissues (blood, adipose tissue, liver, kidney cortex, and lung), the samples were collected from the autopsied cadavers of 40 men and 40 women (from teens to seventies of age). ${\alpha}-BHC,\;{\beta}-BHC,\;{\gamma}-BHC,\;{\delta}-BHC$, p,p'-DDT, p,p'-DDD, p,p'-DDE, endrin, dieldein, aldrin, and 7 marker PCBs (28, 52, 101, 118, 138, 153, and 180) were determined in human tissues. The levels of organochlorines and PCB congeners indicated that they have been widely distributed in Korean human body. Positive correlations in terms of age were observed for the following cases: p,p'-DDE, p,p'-DDT, ${\Sigma}-DDT$, PCB 118, PCB 138, PCB 153, and ${\Sigma}-PCB$ in the adipose tissue, and p,p'-DDE in the lung. Concentration of these compounds showed a significant age-related increase. Accumulation of these compounds in aged people revealed that these compounds were more slowly eliminated in our environment and risk assessment was necessary for further proper action. Significant differences in the levels of PCBs between genders were found for PCB 118 in the adipose tissue and PCB 138 in the liver. Positive correlation coefficients between tissues were detected with p,p'-DDE and ${\beta}-BHC$.

A Confirmation of the Minimum Moving Time to the Stop-Motion in the (sLa-Camera-pLa)Type ((sLa-Camera-pLa)타입에서 Stop-Motion 방식의 최소 구동 시간 입증)

  • Kim, Soon Ho;Kim, Chi Su
    • KIPS Transactions on Software and Data Engineering
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    • v.6 no.5
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    • pp.223-228
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    • 2017
  • SMT is an device that picks up electronic components and does precise placing onto PCBs. In order to do this, it stops in front of a camera installed in the middle to go over vision inspection. And after that it is move for placing. There are 16 different types of routes in this process. This paper compared to the moving time of three methods in the (sLa-Camera-pLa)type. The first method is stopping in front of the camera for vision inspection and placing components onto PCBs(stop-motion). The second method is moving in front of the camera for vision inspection without stopping(fly1-motion). The third method is inspecting the components when the speed of the X axis, the Y axis is the best and is placing components onto PCBs(fly2-motion). This paper shows the moving time of three methods is same. Therefore we proved that the stop-motion method can be placing in the fastest time without changing structure of the device in the (sLa-Camera-pLa)type.

Recovery of Metals from Printed Circuit Board Scraps by Shape Sorting Method (형상분리법에 의한 폐 PCBs로부터 유가금속의 회수연구)

  • Lee, Jae-Chun;Lee, Min-Yong;Shigehisa Endoh;Shin, Hee-Young
    • Resources Recycling
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    • v.5 no.3
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    • pp.37-43
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    • 1996
  • The recovery of metals from printed circuit board(PCBs) scraps was investigated by utilizing a shape sorting method.After all electronic parts mounted on the board were removed. PCBs were pulverized to particles smaller than 1 mm by aswing hammer type impact mill in order to liberate metal components. Metals were separated from nonmetalliccomponents by an inclined vibrating plate (IVP). The metal separation efficiency was measured as a function of vihrationintensity and inclined angle. The maximum efficiency was obtained when IVP was operated at the vibration intensity(Kv)of 1.40 and the inclined angle of 10". The grade of the metal components was recovered from PCBs exceeding 90% byusing IVP.0% by using IVP.

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Analysis of Commercial Recycling Technology and Research Trend of Printed Circuit Boards in Korea (국내 인쇄회로기판의 재활용 상용화 기술 및 연구동향 분석)

  • An, HyeLan;Kang, Leeseung;Lee, Chan-Gi
    • Resources Recycling
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    • v.26 no.4
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    • pp.9-18
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    • 2017
  • Recently, the amount of electronic scrap is rapidly increasing due to the rapid growth of the electronics industry. Among the components of electronic scrap, the printed circuit board(PCB) is an important recycling target which includes common metals, precious metals, and rare metals such as gold, silver, copper, tin, nickel and so on. In Korea, however, PCB recycling technologies are mainly commercialized by some major companies, and other process quantities are not accurately counted. According to present situation, several urban mining companies, research institutes, and universities are conducting research on recovery of valuable metals from PCBs and/or reusing them as raw materials that is different from existing commercialization process developed by major companies. In this study, we analyzed not only current status of collection/disposal process and recycling of waste PCBs in Korea but also the trend of recycling technologies in order to help resource circulation from waste PCBs become more active.

Effects of Pahs and Pcbs and Their Toxic Metabolites on Inhibition of Gjic and Cell Proliferation in Rat Liver Epithelial Wb-F344 Cells

  • Miroslav, Machala;Jan, Vondracek;Katerina, Chramostova;Lenka, Sindlerova;Pavel, Krcmar;Martina, Pliskova;Katerina, Pencikova;Brad, Upham
    • Environmental Mutagens and Carcinogens
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    • v.23 no.2
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    • pp.56-62
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    • 2003
  • The liver progenitor cells could form a potential target cell population fore both tumor-initiating and -promoting chemicals. Induction of drug-metabolizing and antioxidant enzymes, including AhR-dependent CYP1A1, NQO-1 and AKR1C9, was detected in the rat liver epithelial WB-F344 "stem-like" cells. Additionally, WB-F344 cells express a functional, wild-type form of p53 protein, a biomarker of genotoxic events, and connexin 43, a basic structural unit of gap junctions forming an important type of intercellular communication. In this cellular model, two complementary assays have been established for detection of the modes of action associated with tumor promotion: inhibition of gap junctional intercellular communication (GJIC) and proliferative activity in confluent cells. We found that the PAHs and PCBs, which are AhR agonists, released WB-F344 cells from contact inhibition, increasing both DNA synthesis and cell numbers. Genotoxic effects of some PAHs that lead to apoptosis and cell cycle delay might interfere with the proliferative activity of PAHs. Contrary to that, the nongenotoxic low-molecular-weight PAHs and non-dioxin-like PCB congeners, abundant in the environment, did not significantly affect cell cycle and cell proliferation; however both groups of compounds inhibited GJIC in WB-F344 cells. The release from contact inhibiton by a mechanism that possibly involves the AhR activation, inhibition of GJIC and genotoxic events induced by environmental contaminants are three important modes of action that could play an important role in carcinogenic effects of toxic compounds. The relative potencies to inhibit GJIC, to induce AhR-mediated activity, and to release cells from contact inhibition were determined for a large series of PAHs and PCBs and their metabolites. In vitro bioassays based on detection of events on cellular level (deregulation of GJIC and/or proliferation) or determination of receptor-mediated activities in both ?$stem-like^{\circ}{\times}$ and hepatocyte-like liver cellular models are valuable tools for detection of modes of action of polyaromatic hydrocarbons. They may serve, together with concentration data, as a first step in their risk assessment.

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Analytical Method for Aperiodic EBG Island in Power Distribution Network of High-Speed Packages and PCBs (비주기 전자기 밴드갭이 국소 배치된 고속 패키지/PCB 전원분배망 해석 방안)

  • Myunghoi Kim
    • Journal of Advanced Navigation Technology
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    • v.28 no.1
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    • pp.129-135
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    • 2024
  • In this paper, an analytical approach for the design and analysis of an aperiodic electromagnetic bandgap (EBG)-based power distribution network (PDN) in high-speed integrated-circuit (IC) packages and printed circuit boards (PCBs) is proposed. Aperiodic EBG is an effective method to solve the noise problem of high-speed IC packages and PCBs. However, its analysis becomes challenging due to increased computation time. To overcome the problem, the proposed analytical method entails deriving impedance parameters for EBG island and the overall PDN, which includes locally placed EBG structures. To validate the proposed method, a test vehicle is fabricated, demonstrating good agreement with the measurements. Significantly, the proposed analytical method reduces computation time by 99.7 %compared to the full-wave simulation method.

Treatment of Highly Concentrated PCB Containing Insulating Oil by Countercurrent Oxidation Process (역류산화공정을 이용한 고농도 PCBs 함유 절연유의 처리)

  • Lee, Chang Soon;Kim, Daeik;Ryoo, Keon Sang
    • Journal of the Korean Chemical Society
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    • v.61 no.4
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    • pp.143-150
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    • 2017
  • Countercurrent oxidation process (COP) was developed and evaluated for treatment of highly concentrated PCB containing insulating oil. The PCB content in insulating oil taken from Haksanmetal company was found to be 1,512 ppm. The COP utilizes a self-sustained flame which propagates itself in a direction counter to the oxygen flow. The flame removes PCBs adsorbed in activated carbon and, at the same time, regenerates activated carbon. The flame temperature was determined from both mass loss of activated carbon and the relative ratio of CO and $CO_2$ exhausted during COP, and showed that its temperature lied in the range of $650-850^{\circ}C$. Removal efficiency of PCBs was achieved above 99.99% for 5% of insulating oil loaded activated carbon with 1 COP in weight ratio. Also, the same removal efficiency was acquired for 60% of insulating oil loaded activated carbon with three consecutive COP. In addition, specific surface area of activated carbon during COP was recovered to almost similar value of virgin activated carbon. It proved that the COP was much effective in removing high concentration of PCBs in insulating oil easily and affordably.

Characteristics of organic pollutants in discharged industrial waste in Korea - Focuse on metallic and plastic manufacturing processes and wastewater treatment plants - (국내 사업장 폐기물 중 유기오염물질의 배출특성 연구 - 금속과 플라스틱 제조공정 및 폐수처리시설 중심으로 -)

  • Yeon, Jin-Mo;Kang, Young-Yeul;Kim, Woo-Il;Shin, Sun-Kyoung;Jeong, Seong-Kyeong;Cho, Yoon-A;Kim, Na;Kim, Min-Sun
    • Analytical Science and Technology
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    • v.25 no.6
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    • pp.421-428
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    • 2012
  • In this study, PCDD/PCDFs, PAHs and PCBs in wastes from metal, plastic and wastewater treatment facilities were analyzed. The concentrations of PCDD/PCDFs ranged from 7.37~432.20 ng-TEQ/kg in fly ash, 0.51~855.01 ng-TEQ/kg in incinerated ash and 0.37~385.81 ng-TEQ/kg in dust. Dioxin content was lower, compared to data in foreign countries. PAHs concentration was in the range of 0.0075~2.9225 mg/kg for process sludge and 0.0035~1.6716 mg/kg for wastewater sludge, which satisfied all of the two standards (Nap, Ant, B(a)F:4/0.8, Phen, B(a)A:5/1, Flt:10/2.5, B(a)P:4.5/0.9) of the Marine Environment Management Act. PAHs concentration in process sludge and wastewater sludge were slightly lower than those abroad. According to the analysis of seven types of PCBs (in comparison with the first standard, 0.15 mg/kg), concentration was found in the range of 0.0~0.65 mg/kg, while PCB-52, PCB-101, PCB-138, PCB-153 and PCB-180 isomers were detected in excessive value in some machine oil and hydraulic fluid.

The Analysis of Dioxin-like PCBs in Fishes and Shellfishes using Accelerated Solvent Extraction (ASE) System and Multilayer Column Chromatography (가속용매추출장치(ASE) 및 다층크로마토그래피를 이용한 어패류 중의 dioxin-like PCBs의 분석)

  • Oh, Keum-Soon;Park, Seong-Soo;Chung, So-Young;Sho, You-Sub;Kim, Jung-Soo;Jang, Seoung-Chul;Lee, Jong-Ok;Kim, Hee-Yun;Woo, Gun-Jo;Suh, Jung-Hyuck
    • Korean Journal of Food Science and Technology
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    • v.39 no.2
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    • pp.122-127
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    • 2007
  • In this study, an analytical method was optimized for detecting dioxin-like PCBs in fish and shellfish. Here, homogenized samples were extracted using an accelerated solvent extraction (ASE) system with 33 mL cell size. Multilayer column chromatography, which consisted of acidic, basic and neutral silica gels, was used for the clean up of the extracts. The instrumental analysis was executed by HRGC/HRMS to a resolution of 10,000 using 4 window multiple ion detection (MID) mode. For the results, the average recoveries ranged from 94.1 to 104.1% (${\pm}8.4$) and the limit of detection was approximately 0.1 pg/g at S/N ratio >3. Finally, the detected concentrations of dioxin-like PCBs for fish and shellfish were in the range of 0.030-1.836 pg TEQ/g.

Selective Leaching Process of Precious Metals (Au, Ag, etc.) from Waste Printed Circuit Boards (PCBs) (廢 PCBs부터 귀금속(Au, Ag 등)의 선택적 침출공정)

  • 오치정;이성오;국남표;김주환;김명준
    • Resources Recycling
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    • v.10 no.5
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    • pp.29-35
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    • 2001
  • This study was carried out to recover gold, silver and valuable metals from the printed circuit boards (PCBs) of waste computers. PCBs samples were crushed under 1 mm by a shredder and separated into 30% conducting and loft nonconducting materials by an electrostatic separator. The conducting materials contained valuable metals which were then used as feed materials for magnetic separation. 42% of magnetic materials from the conducting materials was removed by magnetic separation as nonvaluable materials and the others, 58% of non magnetic materials, was used as leaching samples containing 0.227 mg/g Au and 0.697 mg/g Ag. Using the materials of leaching from magnetic separation, more than 95% of copper, iron, zinc, nickel and aluminium was dissolved in 2.0M sulfuric acid solution, added with 0.2M hydrogen peroxide at $85^{\circ}C$. Au and Ag were not extracted in this solution. On the other hand, more than 95% of gold and 100% of silver were leached by the selective leaching with a mixed solvent (0.2M($NH_4$)$_2$$S_2$$O_3$,0.02M $CuSO_4$,0.4M $NH_4$OH). Finally, the residues were reacted with a NaCl solution to leach Pb whereas sulfuric acid was used to leach Sn. Recoveries reached 95% and 98% in solution, respectively.

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