• Title/Summary/Keyword: particle size control

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Dispersion stability of ultra-fine $BaTiO_3$ suspensions in aqueous medium

  • Chun, M.P.;Chung, Y.B.;Ma, Y.J.;Cho, J.H.;Kim, B.I.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.6
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    • pp.239-243
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    • 2005
  • The effect of pH and particle size on the dispersion stability of ultra-fine $BaTiO_3$ suspensions in aqueous medium have been investigated by means of zeta potential, sediment experiments, and powder properties (particle analysis, specific surface area) etc. Zeta potential as a function of pH for two particles of different size increases from -75 to +10 mV with decreasing pH from 8.5 to 1.4. The curve of zeta potential for small particle (150 nm) has slow slope than that of large particle (900nm), giving IEP (isoelectric point) value of pH=1.6 for small particle and pH=1.9 for large particle respectively, which means that it is more difficult to control zeta potential with pH fur small particle than large particle. The dispersion stability of $BaTiO_3$ particles in aqueous medium was found to be strongly related with the agglomeration of colloidal suspensions with time through the sedimentation behaviors of colloidal particles with time and pH value.

Effects of Particle Size and Binder Phase Addition on Formability of Li-Si Alloy Powder for Thermal Battery Anode (열전지 음극재용 Li-Si 원료의 성형성에 미치는 입자크기와 바인더첨가 효과)

  • Ryu, Sung-Soo;Kim, Hui-Sik;Kim, Seongwon;Kim, Hyung-Tae;Cheong, Hae-Won;Lee, Sung-Min
    • Journal of Powder Materials
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    • v.21 no.5
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    • pp.331-337
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    • 2014
  • The effects of particle size of Li-Si alloy and LiCl-KCl addition as a binder phase for raw material of anode were investigated on the formability of the thermal battery anode. The formability was evaluated with respect to filling density, tap density, compaction density, spring-back and compressive strength. With increasing particle size of Li-Si alloy powder, densities increased while spring-back and compressive strength decreased. Since the small spring-back is beneficial to avoiding breakage of pressed compacts, larger particles might be more suitable for anode forming. The increasing amount of LiCl-KCl binder phase contributed to reducing spring-back, improving the formability of anode powder too. The control of particle size also seems to be helpful to get double pressed pellets, which consisted of two layer of anode and electrolyte.

Characteristics of the Ceramic Filter with the Control of Particle Size and Graphite Additive for the Hazardous Particle and Gas Removal (입도와 흑연 첨가제에 따른 유해 입자 및 가스 동시제거용 세라믹필터 특성평가)

  • Cho, Eul-Hun;Lee, Kun-Jae
    • Journal of Powder Materials
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    • v.21 no.6
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    • pp.454-459
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    • 2014
  • In this study, the porous ceramic filter was developed to be able to remove both dust and hazardous gas contained in fuel gas at high temperature. The porous ceramic filters were fabricated and used as a catalyst support. And the effects have been investigated such as the mean particle size, organic content and addition of foaming agent on the porosity, compressive strength and pressure drop of ceramic filters. With the increase of mean powder size and the organic content for the cordierite filter, the porosity was increased, but the compressive strength and pressure drop were decreased. From the results of the research, the optimum condition for the fabrication of ceramic filters could be acquired and they had the porosity of 58%, the compressive strength of 13.4 MPa and the pressure drop of 250 Pa. It was expected that this ceramic filter was able to be applied to the glass melting furnace, combustor, and dust/toxic gas removal filter.

Effect of Wood Particle Size on Physical and Mechanical Composites by Nonwoven Web Process

  • Chae, Shoo Geun;Eom, Young Geun
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.2 s.130
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    • pp.40-55
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    • 2005
  • This study was carried out to discuss the feasibility of wood and plastic wastes as the raw materials for wood particle-plastic composites. For this purpose, composites were manufactured from coarse and fine wood particles and polypropylene fibers by nonwoven web process. And the effect of wood particle size on the performance of the composites were analyzed according to ASTM D 1037-93. In the physical properties of composites, water absorption decreased with the increase of target density and polypropylene fiber content. And the composites with fine wood particles appeared to have slightly lower water absorption than those with coarse wood particles. Thickness swelling did not vary significantly with the increase of target density but increased with the increase of wood particle content. And the composites with fine wood particles were significantly lower in thickness swelling than those with coarse wood particles. In the mechanical properties of composites, dry and wet MOR showed the increasing tendency with the increase of polypropylene fiber content and target density. Dry and wet MOE showed the increasing tendency with the increase of target density but only wet MOE exhibited the increasing tendency with the increase of polypropylene fiber content. Composites with fine wood particles appeared to be generally higher in wet MOR and MOE than those with coarse wood particles. In conclusion, composites with fine wood particles showed generally higher performance than those with coarse ones. Also, composites were significantly superior to control particleboards in the performance, especially in water absorption and thickness swelling.

Electromagnetic Wave Absorption of Sheet Type EM Wave Absorber by Control of Ferrite Particle Size (Sheet형 전파흡수체에 있어 Ferrite 입자 크기의 제어에 따른 전파흡수체의 특성)

  • Kim, Dong-Il;Ok, Seung-Min;Kim, Su-Jung;Park, Woo-Keun;Song, Jae-Man
    • Journal of Navigation and Port Research
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    • v.27 no.1
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    • pp.71-74
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    • 2003
  • Electromagnetic wave absorbers with sheet type have been fabricated and their absorption properties are measured. The absorbtion properties of the fabricated ferrite absorbers were improved with decreasing the particle size in the frequency range of 2.4~3.2 GHz.

Effect of Pt Particle Size on the Durability of PEMFC (연료전지 촉매의 입자크기가 내구성에 미치는 영향)

  • Min, Kyoung-Won;Kim, Hyun-Jong;Han, M.K.;U, Yu-Tae;Kim, Mok-Soon;Chu, Young-Hwan
    • Journal of the Korean Electrochemical Society
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    • v.11 no.4
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    • pp.313-318
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    • 2008
  • The influence of the particle size of platinum(Pt) on the stability and activity was studied. The particle size of platinum was controlled in the range of $3.5{\sim}9\;nm$ by heat treatment of commercial Pt/C and confirmed by XRD and TEM. An accelerated degradation test was performed to evaluate the stability of platinum catalysts. Oxygen reduction reaction was monitored for the measurement of activity. As increasing the Pt particle size, the stability of Pt/C electrode was enhanced and the activity was reduced. It was confirmed that the stability of Pt/C electrode was in inverse proportion to the activity. PtCo/C alloy catalyst was used to improve the activity and stability of large-sized platinum particle. The maximum power density of commercial Pt/C was $507.6\;mV/cm^2$ and PtCo/C alloy catalyst was $585.8\;mV/cm^2$. The decrement of electrochemical surface area showed Pt/C(60%) and PtCo/C alloy catalyst(24%). It was possible to enhance both of stability and activity of catalyst by the combination of particle size control and alloying.

The Characteristics of Exhausted Soot Particles from a Common-Rail Direct Injection Diesel Engine by TIRE-LII (커먼레일 직접분사식 디젤엔진에서 시분해 레이저 유도 백열법을 이용한 매연입자의 배출 특성)

  • Kim, Gyu-Bo;Han, Hwi-Young;Chang, Young-June;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.5
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    • pp.78-85
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    • 2007
  • Recently, diesel vehicles have been increased and their emission standards have been getting strict. The emission of diesel vehicles contains numerous dangerous compounds, especially particulate matters cause a serious environmental pollutant and affect to human health seriously. Thousands of studies have already reported that particulate matters are associated with respiratory and cardiovascular diseases, and death. Due to these, it is necessary to measure the soot concentration and soot particle size in laboratory flames or practical engines to recognize the soot formation, and develop the control strategies for soot emission. In this study, the characteristics of exhausted soot particle size and volume fraction from 2.0L CRDI diesel engine have been investigated as varying engine speed and load. Laser induced incandescence has been used to measure soot concentration. Time-resolved laser induced incandescence has been used to determine soot particle size in the engine. The soot volume fraction is increased as increasing engine load but soot volume fraction is decreased as increasing engine speed. The primary particle size is distributed about $35nm{\sim}60nm$ at each experimental conditions.

Continuous Combined Process for Homogeneous Dispersion of Ceramic Particle and Aluminum Materials (세라믹 입자/알루미늄 소재의 연속복합 균일분산)

  • 이동건;이승후;강충길
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2001.04a
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    • pp.381-384
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    • 2001
  • The combined stirring method to uniform distribution of particle is consisted of two strring force both electro-magnetic stirring generated from induction heating and mechanical stirring with graphite stirrer. PMMC billets were fabricated with the volume fractions ranged from 0% to 20% and particle sizes ranged from 14$\mu\textrm{m}$ to 25$\mu\textrm{m}$. It is important to control the size of primary ${\alpha}$-AI solid particles because it could become the cause of the particle pushing or capture phenomena from the fact that secondary dendrite arm spacing size depends on the cooling rate during the solidification in hypoeutectic AI-Si alloy.

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Prediction of Packing Density of Milled Powder Based on Packing Simulation and Particle Shape Analysis

  • Amano, Yuto;Itoh, Takashi;Terao, Hoshiaki;Kanetake, Naoyuki
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1254-1255
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    • 2006
  • For precise property control of sintered products, it is important to understand accurately the packing density of the powder. We developed a packing simulation program that could make a packed bed of spherical particles having particle size distribution. In addition, the influence of the particle shape of the actual powder on the packing density was quantitatively analyzed. The predicted packing densities corresponded well to the actual data.

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Size Characteristics of Micro-bubbles According to Applied Voltage and Electrode materials (전해부상에서 전압과 극판 재질에 따른 미세기포의 크기 특성)

  • Park, Yong-hyo;Han, Moo-young
    • Journal of Korean Society of Water and Wastewater
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    • v.16 no.6
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    • pp.663-669
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    • 2002
  • Electro-flotation (EF) has shown advantages, such as a high removal efficiency and easy control of bubble generation, over dissolved air flotation. However, the fundamental characteristics of the process have not been investigated in detail. According to recent modeling results from trajectory analysis, the size of the bubble is one of the most important factors that affect the efficiency of collision between bubble and particle. In this paper, the size characteristics of bubbles generated from EF under various conditions are measured using a new method for bubble size measurement, the Particle Counter Method (PCM). The size of the generated bubbles was found to be constant with respect to applied voltage but to vary with the electrode materials. These results and their implications are discussed.