• Applied Chemistry for Engineering
• /
• v.23 no.1
• /
• pp.59-64
• /
• 2012

Polystyrene latex spheres (PLS) were prepared as artificial dusts by the emulsion polymerization with potassium persulfate (KPS) and sodium dodecyl sulfonate (SDS) as an initiator and a stabilizer, respectively. The reaction temperature and the concentration of the initiator and stabilizer were chosen as variables to control the PLS particle size. As temperature increased, the particle size decreased considerably. Furthermore, the PLS particle size and their size distributions can be controlled minutely by adjusting the concentrations of KPS and SDS. It is confirmed that the PLS prepared in this work is monodispersed with the coefficient of variance less than 7% and are in the range of 0.1~0.5 ${\mu}m$, which are good for using as artificial dusts.

• Journal of The Geomorphological Association of Korea
• /
• v.26 no.4
• /
• pp.1-20
• /
• 2019

In order to establish appropriate policy to control sediment-associated problems, it is necessary to identify the physical characteristics of the reservoir sediments in particulate form in the Yeongsan River. Two time-integrated suspended sediment samplers were installed at Seungchon and Juksan weir on the upper and middle Yeongsan River in July 2012. Reservoir sediment samples were obtained at monthly intervals until October 2014. During the monitoring period, a total of 38 sediment samples were obtained and analyzed. Seasonal trends of suspended sedimentation rates and grain size distributions were examined based on variations in precipitation and discharge fluctuations. Moreover, stream flow characteristics, which has a great influence on the physical characteristics of the river sediment, was analyzed using flow duration curve for the period 2003-2019 at Naju gauging station. Sedimentation rates during summer, when heavy rainfall was concentrated due to the monsoonal front and typhoon, were very high, indicating the positive relationship between sediment concentration and discharge. Particle size analysis of the collected sediment showed that coarse silt and very fine sand-sized sediment dominated most of the Seungchon weir sediment. On the other hand, medium silt-sized sediment dominated the downstream Juksan weir except for a few summer samples. These results implied that the physical characteristics of the suspended sediment are determined not only due to flow fluctuations, but also with regard to the antecedent rainfall conditions, hillslope-channel connectivity, and the supply of materials from various contributing regions. This information about flow characteristics and temporal variations in reservoir sediment can be used for safe management of the weir and discussing the issues on the dismantling of the weirs.

• Proceedings of the Korea Association of Crystal Growth Conference
• /
• 1998.09a
• /
• pp.103-111
• /
• 1998

Au fine particle dispersed TiO2 film was prepared on silica glass substrate by sol-gel dip and firing process. The films were fabricated from the system of titanium tetraisoproxie-EtOh-HCl_H2O-hydrogen tetrachloroaurate(III) tetrahydrate. The conditions for the formation of the clear solution and dissolving high concentration of Au compound were examined. And a photoreduction process was adopted to control the size of gold metal particles. Phase evolution of matrix TiO2 and variation of Au particle with UV irradiation were investigated by XRDA, SEM, TEM and UV-visible spectrophotometer. And the effect of CPCl(Cetylpyridinium chloride monohydrate) as a dispersion agent was evaluated.

• Applied Chemistry for Engineering
• /
• v.16 no.1
• /
• pp.45-51
• /
• 2005

$K^+-{\beta}^{{\prime}{\prime}}-Al_2O_3$ in the $K_2O-Li_2O-Al_2O_3$ ternary system was synthesized using aluminum nitrate solution as a starting material. For the synthesis of pure $K^+-{\beta}^{{\prime}{\prime}}-Al_2O_3$, raw materials with chemical composition of $0.84K_2O{\cdot}0.082Li_2O{\cdot}5.2Al_2O_3$ were mixed in solution state. The effects of dispersant and solution-pH were investigated in minimizing the particle size and on the synthesis of pure $K^+-{\beta}^{{\prime}{\prime}}-Al_2O_3$. Ethanol was used for a dispersant, and $NH_4OH$ solution and nitric acid were added for pH adjustment. The solution pH was increased from 1.0 to 7.5 by 0.5 increments. Each sample was calcined at $1200^{\circ}C$ for 2 h and characterized with X-ray diffraction and particle size analyzer. The pH of solution significantly effected both particle size and phase formation, while the addition of ethanol only effected particle size. The synthesis of pure $K^+-{\beta}^{{\prime}{\prime}}-Al_2O_3$ was favored by addition of nitric acid (for pH control).

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.18 no.1
• /
• pp.506-512
• /
• 2017

The purpose of this study was to improve release rate and bioavailability of nateglinide formulation. Polymorphism selection and particle size control were performed to enhance formulation dissolution rate, and a pH modifier was included in the formulation to overcome pH-dependent solubility of nateglinide. The enhanced dissolution rate was characterized by using a dissolution test. The results showed that H-type raw material had a higher dissolution rate than that of B-type raw material. There was 6.2% difference in dissolution between the two materials at 60 min. With regard to particle size, raw material with a $1.13{\mu}m$ particle size showed a 20% faster release rate than that of raw material with a $2.28{\mu}m$ particle size. Furthermore, fumaric acid was included in formulation as a pH modifier. That addition produced a greater than 50% improvement in dissolution rate. In conclusion, dissolution rate of nateglinide can be enhanced by optimizing its polymorphism and particle size; moreover, a synergistic effect on the enhancement of dissolution rate is obtained by including fumaric acid, a pH modifier, in the formulation.

• Journal of the Korean Wood Science and Technology
• /
• v.47 no.3
• /
• pp.299-310
• /
• 2019

This study was carried out to investigate the effect of heat-treatment and particle size on the crystalline properties of the wood cellulose. The color of wood flours was changed from light yellow in control sample to dark yellow or deep brown by heat treatment at $100^{\circ}C$ to $200^{\circ}C$. Relative crystallinity of the heat treated wood cellulose decreased with decreasing particle size from wood chips to 200 mesh, and there was little change in the crystal width. As the temperature was increased, relative crystallinity of the wood increased and crystal width was not changed. As a result of the FT-IR analysis, it was confirmed that the peaks were gradually decreased at -OH elongation as the heat-treated temperature was increased. The lignin C-H bending of $1425cm^{-1}$ and the hemicellulose C-H bending of $1370cm^{-1}$ did not change with the increase of the heat treatment temperature. In addition, it was revealed that C-C stretching of carbohydrate near $1031cm^{-1}$ decreased with increasing heat treatment temperature. Consequently, it is suggested that particle size and heat treatment affected the crystalline properties of wood cellulose.

• Applied Chemistry for Engineering
• /
• v.25 no.6
• /
• pp.564-569
• /
• 2014

Zirconia nanoparticles were synthesized by hydrothermal process, and experimental parameters such as reaction temperature, reaction time, kind and concentration of precipitator, kind of precursor were varied. Particle sizes and crystalline phases of each synthesized nanoparticles were analyzed with X-ray diffraction and FE-scanning electron microscope (SEM). The particle size and crystallization of zirconia increased with increasing concentration of precipitator. The growth rate of particle sizes when NaOH as a precipitator was used also increased more than that of KOH. Therefore, the use of KOH rather than NaOH was more effective in the control of particle sizes. An amorphous zirconia nanoparticle was found in 4 h of hydrothermal reaction, but the monoclinic zirconia nanoparticle was found in 8 h and over of hydrothermal reaction, and the width of nanoparticles was slightly slimmed and the length of nanoparticles was slightly extended with increasing reaction time. The smallest particle size was produced at the same synthesis condition when zirconium chloride among the precursors such as zirconium (IV) acetate, zirconium nitrate and zirconium chloride was used.

• Journal of Korean Society of Water and Wastewater
• /
• v.19 no.2
• /
• pp.117-124
• /
• 2005

Appropriate removal of pollutants from combined sewer overflows(CSOs) and stormwater runoff is of primary concern to watershed managers trying to meet water quality standards even under a wet weather condition. Harmful substances associated with particles besides TSS and BOD are subjected to removal prior to discharge into the natural waters. Effectiveness of five major hydrodynamic separation technologies, Vortechs, Downstream Defender including Storm King for CSOs control, CDS, Stormceptor, and IHS, were evaluated in this study. There is not sufficient information for accurate evaluation of the removal efficiency for the pollutants from the stormwater runoff and CSOs. Based upon limited engineering data, however, all technologies were found to be effective in separation of heavy particles and floating solids. Technologies utilizing screens seem to have advantage in the treatment capacity than the other technologies relied fully on hydrodynamic behavior. The IHS system seems to have a strong potential in application for control of CSOs because of unique hydrodynamic behavior as well as a flexibility in opening size of the screens. Size of the particulate matter in the CSOs and stormwater runoff is found to be the most important parameter in selection of the type of the hydrodynamic separators. There exists an upper limit in the solids removal efficiency of a hydrodynamic separator, which is strongly dependent upon the particle size distribution of the CSOs and stormwater runoff.

• Resources Recycling
• /
• v.5 no.3
• /
• pp.65-72
• /
• 1996

Colloidal calcium wrbonate(diametcr 0.02-0 09 m~wja s developed to maintain the mamenl of pnriide formatio~>w ~lhoutsurlace trealment. The control factors of particle size and optimum condiliuna for compound fam*tition has not bccn studiedyet. This shldy war aimed at developing a method fur compounding colloidal calcium carbonfcte to cnl~hol cubic calciumcarbonate, and then compounding the b-o types oI precipitated calcium wrbonatc under optimum wndilrans Calc~umhydroxide was calcinated at 1, lWC far two hours, md then hydrated for 30 minutes at t i i O rprn and ambiznt temperahlle.Two-liter suspension was subjected to the contact with carbon dioxide at l5"C, 600 ipxn and C0= injection in the rate of 1 Umin Two types of dcium carbonate(cuhic calcium carbonatc(0 24.9 pm) md collnidd calcium mhnnate (0.02-0 09 pm))were compounded by "wing the concentrations of calcium oxide and ihe suspension were compounded. It was found that theoptimum concentrations of each suspensions were 5 wt % and 2.5 \I*.% respectively. ' h c key control factor af thc parlicle slzcdislribution was the concenkation al the suspension. The size of compounded particles was measured by a Zcla S k r 'fieaverage particle size of the cubic calcium carbonate aas 223.4 nm(0.223 pm), and that of thc colloidal a~lciumc arbonate was93.6 nm (0.093 km). Ihe particle sizc was evenly cantlolled on a stdblc basis in an H, O reaction system.asis in an H, O reaction system.

• Applied Chemistry for Engineering
• /
• v.20 no.2
• /
• pp.201-207
• /
• 2009

The hydrogenation reaction of methyl dodecanoate for the synthesis of 1-dodecanol has been carried out in the presence of a copper chromite catalyst. The catalysts were synthesized by ceramic method, co-precipitation, and improved co-precipitation method and the particles were characterized by SEM and XRD. Also, the products of the reaction were assigned by GC, GC/MSD and NMR. The particles synthesized by each method showed (1) a spherical shape with the size of 3.2 to $7.0{\mu}m$, (2) an agglomerated spherical shape with the size of 50 to 500 nm and (3) a spherical shape with smaller particle size, respectively. Especially, in order to control the size of particles, the particles were synthesized in various dispersant solutions as Span 80, polyacrylate, and polyethyleneglycols (PEGs). The particles synthesized in PEG (Mw = 4000) solution showed the smallest particle size of 30 to 50 nm and the regularity of the particle size distribution. Our experimental results elucidated that the activity of catalyst for hydrogenation increases with decreasing the size of catalyst particle. The highest yield of dodecanol in the hydrogenation reaction was 95.5% when copper chromite synthesized in the PEG solution was used as a catalyst in the optimized reaction condition.