• Title/Summary/Keyword: particle inversion

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Particle Based Discrete Element Modeling of Hydraulic Stimulation of Geothermal Reservoirs, Induced Seismicity and Fault Zone Deformation (수리자극에 의한 지열저류층에서의 유도지진과 단층대의 변형에 관한 입자기반 개별요소법 모델링 연구)

  • Yoon, Jeoung Seok;Hakimhashemi, Amir;Zang, Arno;Zimmermann, Gunter
    • Tunnel and Underground Space
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    • v.23 no.6
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    • pp.493-505
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    • 2013
  • This numerical study investigates seismicity and fault slip induced by fluid injection in deep geothermal reservoir with pre-existing fractures and fault. Particle Flow Code 2D is used with additionally implemented hydro-mechanical coupled fluid flow algorithm and acoustic emission moment tensor inversion algorithm. The output of the model includes spatio-temporal evolution of induced seismicity (hypocenter locations and magnitudes) and fault deformation (failure and slip) in relation to fluid pressure distribution. The model is applied to a case of fluid injection with constant rates changing in three steps using different fluid characters, i.e. the viscosity, and different injection locations. In fractured reservoir, spatio-temporal distribution of the induced seismicity differs significantly depending on the viscosity of the fracturing fluid. In a fractured reservoir, injection of low viscosity fluid results in larger volume of induced seismicity cloud as the fluid can migrate easily to the reservoir and cause large number and magnitude of induced seismicity in the post-shut-in period. In a faulted reservoir, fault deformation (co-seismic failure and aseismic slip) can occur by a small perturbation of fracturing fluid (<0.1 MPa) can be induced when the injection location is set close to the fault. The presented numerical model technique can practically be used in geothermal industry to predict the induced seismicity pattern and magnitude distribution resulting from hydraulic stimulation of geothermal reservoirs prior to actual injection operation.

Preparation of $PES-TiO_2$ Hybrid Membranes and Evaluation of Membrane Properties ($PES-TiO_2$ 복합막의 제조 및 막 특성 평가)

  • Youm, Kyung-Ho;Lee, Mi-Sheon
    • Membrane Journal
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    • v.17 no.3
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    • pp.219-232
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    • 2007
  • The polyethersulfone(PES)-titanium oxide($TiO_2$) hybrid membranes were prepared by immersion precipitation phase inversion method. The casting solution for the preparation of $PES-TiO_2$ hybrid membrane was provided by adding $TiO_2$ nano particles into the basis polymer solution of 14 wt% and 20 wt% PES/N-methyl-2-pyrrolidone(NMP). The $TiO_2$ loading [wt% ($TiO_2/NMP$)] in eating solution was varied from 0 to 60 wt%. Membrane performance and morphological change of the resulting $PES-TiO_2$ hybrid membranes were discussed in aspect of $TiO_2$ loading, by viscosity, coagulation value and light transmittance of the casting solution, measurement of tensile strength, pore size and contact angle, surface and cross sectional SEM images of the hybrid membrane, and ultrafiltration experiments using the hybrid membrane. According as increase of $TiO_2$ loading in the casting solution, viscosity is increased and coagulation value becomes lower, therefore the thermodynamic instability of the casting solution is increased. It is found that when $TiO_2$ loading is increased, 1) precipitation rate becomes faster while instantaneous demixing is maintained, 2) pure water flux, membrane pore size and compaction stability of the resulting membranes are increased, 3) tensile strength and contact angle are decreased. Dead-end ultrafiltration of bovine serum albumin(BSA) solution using the hybrid membrane shows that membrane performance(flux of BSA solution) enhanced up to 7 times compared with the results obtained using the pure PES membrane(not containing $TiO_2$ particle), due to the increase of hydrophilicity.

Recycling of Suspended Particulates by Atmospheric Boundary Depth and Coastal Circulation (대기경계층과 연안순환에 의한 부유입자의 재순환)

  • Choe, Hyo
    • Journal of Environmental Science International
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    • v.13 no.8
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    • pp.721-731
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    • 2004
  • The dispersion of suspended particulates in the coastal complex terrain of mountain-inland basin (city)-sea, considering their recycling was investigated using three-dimensional non-hydrostatic numerical model and lagrangian particle model (or random walk model). Convective boundary layer under synoptic scale westerly wind is developed with a thickness of about I km over the ground in the west of the mountain, while a thickness of thermal internal boundary layer (TIBL) is only confined to less than 200m along the eastern slope of the mountain, below an easterly sea breeze circulation. At the mid of the eastern slop of the mountain, westerly wind confronts easterly sea breeze, which goes to the height of 1700 m above sea level and is finally eastward return flow toward the sea. At this time, particulates floated from the ground surface of the city to the top of TIBL go along the eastern slope of the mountain in the passage of sea breeze, being away the TIBL and reach near the top of the mountain. Then those particulates disperse eastward below the height of sea-breeze circulation and widely spread out over the coastal sea. Total suspended particulate concentration near the ground surface of the city is very low. On the other hand, nighttime radiative cooling produces a shallow nocturnal surface inversion layer (NSIL) of 200 m thickness over the inland surface, but relatively thin thickness less than 100m is found near the mountain surface. As synoptic scale westerly wind should be intensified under the association of mountain wind along the eastern slope of mountain to inland plain and further combine with land-breeze from inland plain toward sea, resulting in strong wind as internal gravity waves with a hydraulic jump motion bounding up to about 1km upper level in the atmosphere in the west of the city and becoming a eastward return flow. Simultaneously, wind near the eastern coastal side of the city was moderate. Since the downward strong wind penetrated into the city, the particulate matters floated near the top of the mountain in the day also moved down along the eastern slope of the mountain, reaching the. downtown and merging in the ground surface inside the NSIL with a maximum ground level concentration of total suspended particulates (TSP) at 0300 LST. Some of them were bounded up from the ground surface to the 1km upper level and the others were forward to the coastal sea surface, showing their dispersions from the coastal NSIL toward the propagation area of internal gravity waves. On the next day at 0600 LST and 0900 LST, the dispersed particulates into the coastal sea could return to the coastal inland area under the influence of sea breeze and the recycled particulates combine with emitted ones from the ground surface, resulting in relatively high TSP concentration. Later, they float again up to the thermal internal boundary layer, following sea breeze circulation.

Nanoemulsions: a Novel Vehicle for Cosmetics (나노에멀젼: 화장품을 위한 새로운 제형)

  • Cho, Wan-Goo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.37 no.1
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    • pp.1-21
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    • 2011
  • This review describes several kinds of emulsification methods for nanoemulsions and the application of nanoemulsions. Nanoemulsion droplet sizes fall typically in the range of 20 ~200 nm and show narrow size distributions. Although most of the publications on either oil-in-water (O/W) or water-in-oil (W/O) nanoemulsions have reported their formation by dispersion or high-energy emulsification methods, an increased interest is observed in the study of nano-emulsion formation by condensation or low-energy emulsification methods based on the phase transitions that take place during the emulsification process. Phase behaviour studies have shown that the size of the droplets is governed by the surfactant phase structure (bicontinuous microemulsion or lamellar) at the inversion point induced by either temperature or composition. Studies on nanoemulsion formation by the phase inversion temperature (PIT) method have shown a relation between minimum droplet size and complete solubilization of the oil in a microemulsion bicontinuous phase independently of whether the initial phase equilibrium is single or multiphase. Due to their small droplet size nanoemulsions possess stability against sedimentation or creaming with Ostwald ripening forming the main mechanism of nanoemulsion breakdown. An application of nanoemulsions is the preparation of nanoparticles using a polymerizable monomer as the disperse phase where nanoemulsion droplets act as nanoreactors, cosmetics and controlled drug delivery. In this review, we mainly focus on the cosmetics.

Preparation and Characterization of Ethosome Containing Hydrophobic Flavonoid Luteolin (소수성 플라보노이드인 루테올린을 함유한 Ethosome의 제조 및 특성조사)

  • Lee, Sang Min;Choi, Moon Jae;Lee, Young Moo;Jin, Byung Suk
    • Applied Chemistry for Engineering
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    • v.21 no.1
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    • pp.40-45
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    • 2010
  • Entrapment of hydrophobic flavonoid luteolin into ethosome was carried out for improving its stability and making practical application in the field of drug and cosmetics. The formation of liquid crystalline phase and its thermal properties were investigated by polarized optical microscopy and DSC. The phase inversion from W/O to W/O/W was detected by conductivity change with the addition of PBS buffer solution into the ethanol-dissolved lecithin mixture. The particle size change of ethosome with constituent composition was examined, which showed that the incorporation of luteolin into lecithin up to 10% had little effect on the size of ethosome. Enhancement of stability of luteolin by entrapment into ethosome was verified through DPPH test. The stabilization efficacy of ethosome was improved further by the addition of tocopherol.

VERTICAL PROPERTIES OF THE GLOBAL HAZE ON TITAN DEDUCED FROM METHANE BAND SPECTROSCOPY BETWEEN 7100 AND 9200Å

  • Sim, Chae-Kyung;Kim, Sang-Joon;Kim, Joo-Hyeon;Seo, Haing-Ja;Jung, Ae-Ran;Kim, Ji-Hyun
    • Journal of The Korean Astronomical Society
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    • v.41 no.3
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    • pp.65-76
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    • 2008
  • We have investigated the optical properties of the global haze on Titan from spectra recorded between 7100 and $9200{\AA}$, where $CH_4$ absorption bands of various intensities occur. The Titan spectra were obtained on Feb. 23, 2005 (UT), near the times of the Cassini T3 flyby and Huygens probe, using an optical echelle spectrograph (BOES) on the 1.8-m telescope at Bohyunsan Observatory in Korea. In order to derive the optical properties of the haze as a function of altitude, we developed an inversion radiative-transfer program using an atmospheric model of Titan and laboratory $CH_4$ absorption coefficients available from the literature. The derived extinction coefficients of the haze increase toward the surface, and the coefficients at shorter wavelengths are greater than those at longer wavelengths for the 30 - 120 km altitude range, indicating that the Titanian haze becomes optically thin toward the longer wavelength range. Total optical depths of the haze are estimated to be 1.4 and 1.2 for the 7270 - $7360{\AA}$ and 8940 - $9150{\AA}$ ranges, respectively. Based on the Huygens/DISR data set, Tomasko et al. (2005) reported total optical depths of 2.5 - 3.5 at $8290{\AA}$, depending on the assumed fractal aggregate particle model. The total optical depths based on our results are smaller than those of Tomasko et al., but they partially overlap with their results if we consider a large uncertainty from possible variations of the $CH_4$ mixing ratio over Titan's disk. We also derived the single scattering albedo of the haze particles as a function of altitude: it is less than 0.5 at altitudes higher than ${\sim}150\;km$, and approaches 1.0 toward the surface. This behavior suggests that, at altitudes above ${\sim}150\;km$, the average particle radius is smaller than the wavelengths, whereas near the surface, it becomes comparable or greater.

Synergistic Interaction in W/O and W/S Emulsions Stabilized by a Mixture of Powders and Surfactant (분체와 유화제의 상호 관계성에 기인한 저점도 W/O 및 W/S 에멀젼의 안정성 연구)

  • In, So Hyun;Cho, Hwanil;Kang, Nae Gyu;Han, Jong Sup;Park, Sun Gyoo;Lee, Cheon Koo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.42 no.1
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    • pp.15-28
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    • 2016
  • Water-in-oil emulsions including water-in-ester oil and water-in-silicone oil (W/O+S) have various advantages such as blocking moisture evaporation and forming air permeable membrane. However, their applications have been limited due to the poor stability under low viscosity condition. In this study, we investigated the effect of synergistic interaction between nonionic surfactant, micro-size particles and cationic surfactant on the stability of W/O+S formulation. The stability of W/O+S emulsions was changed as a function of cationic surfactant concentration where it increased at lower concentration and then started to decrease above a critical point. Finally, emulsion phase inversion occurred at a high concentration. The results suggest that W/O+S emulsions of low viscosity ranging from 2000 to 5000 cps can be stabilized under the conditions where a nonionic surfactant, micro-size particles and a cationic surfactant are used in the range of 1.0 ~ 4.0 wt%, 2.5 wt% and 0.1 ~ 0.5 wt%, respectively.

Evaluation of Near Subsurface 2D Vs Distribution Map using SPT-Uphole Tomography Method (SPT-업홀 토모그래피 기법을 이용한 지반의 2차원 전단파 속도 분포의 도출)

  • Bang, Eun-Seok;Kim, Jong-Tae;Kim, Dong-Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.3C
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    • pp.143-155
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    • 2006
  • SPT-Uphole tomography method was introduced for the evaluation of near subsurface shear wave velocity (Vs) distribution map. In SPT-Uphole method, SPT (Standard Penetration Test) which is common in geotechnical site investigation was used as a source and several surface geophones in line were used as receivers. Vs distribution map which is the triangular shape around the boring point can be developed by tomography inversion. To obtain the exact travel time information of shear wave component, a procedure using the magnitude summation of vertical and horizontal components was used based on the evaluation of particle motion at the surface. It was verified that proposed method could give reliable Vs distribution map through the numerical study using the FEM (Finite Element Method) model. Finally, SPT-Uphole tomography method was performed at the weathered soil site where several boring data with SPT-N values are available, and the feasibility of proposed method was verified in the field.

Effect of Oil in Water Nanoemulsion Containing a Mixture of Lactic Acid and Gluconolactone for Skin Barrier Improvement (유산 및 글루코노락톤 혼합물을 함유하는 수중유형 나노에멀젼의 피부장벽개선 효과)

  • Ji-Hye Hong;Young Duck Choi;Gye Won Lee;Young Ho Cho
    • Journal of Life Science
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    • v.33 no.11
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    • pp.905-914
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    • 2023
  • To evaluate the effectiveness of the skin barrier improvement of lactic acid (LA) and gluconolactone (GL), the expression of filaggrin, loricrin, hyaluronic acid (HA), hyaluronan syhthase-2 (HAS2), and aquaporine-3 (AQP3) in keratinocytes, and the moisture content and transepidermal water loss (TEWL) by clinical trials were evaluated. The expression levels of filaggrin and locricrin, which are the main factors affecting the proper functioning of skin barrier function, and HA, HAS2, and AQP3, which are skin moisturizing-related proteins measured by quantitative real-time polymerase chain reaction (qRT-PCR) and western blotting. The results showed that the expression levels of the factors that decreased by H2O2 treatment were significantly increased by LA, GL, and a mixture of LA and GL at the mRNA and protein levels (p<0.05). The nanoemulsion containing a mixture of LA and GL was prepared using the emulsion inversion method, and the average particle size was 299.9 ± 0.287 nm. After measuring the TEWL of nanoemulsion using Vapometer, it was found that TEWL significantly decreased by 15.53% and 26.73% after two weeks and four weeks of product use, respectively, compared to TEWL before product use (p<0.001). Similarly, the skin moisture content of the nanoemulsion significantly increased by 15.40% and 26.59% after two weeks and four weeks of product use, respectively, compared to skin moisture content before product use (p<0.001). Therefore, the skin barrier function and moisturizing effect of a mixture of LA and GL are shown by increasing the moisture content and decreasing the TEWL by increasing the expression of filaggrin, loricrin, HA, HAS2, and AQP3. This suggests the possibility for the development of functional cosmetic ingredients in the future.